Frank Key wrote:

> Roger wrote:
>
> >  Another question... Why don't the ions "plate out" on the particles
> > > anyway, specially, as Frank says, the particles carry a neutral charge?
> > > Silver ions do have a strong tendency to reduce back to the metal. Roger
>
> For an ion to become a metallic particle (atom) is must take on an electron.
> Unless an electron is supplied to make the atom "whole" again, it remains an
> ion. Ions remain dispersed in the water due mutual repulsion caused by their
> "ionic charge" so would normally remain dispersed unless coerced into some
> other behavior.

The silver particles are surrounded by OH radicals according to you.  An OH
radical has an extra electron and makes the particle slightly negative.  Thus it
should attract an Ag + ion, and the OH should be able to supply an electron so 
it
can plate out on the particle.  I see no natural repulsion between an Ag+ ion 
and
a negative silver particle.

Marshall


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