Yes, you guys have it nailed.
The higher the solute content of a solution the lower the freezing
point. So when you freeze sea water to a certain temperature ice
crystals will form, further concentrating the unfrozen brine and
further lowering the temperature at which that brine will freeze. One
must freeze sea water to -50C at which point 99.7% of the water has
frozen, and 99.7% of the sodium and 95.5% of the chloride have
precipitated.

In the Popsicle a high proportion of the water of the sugary solution
has frozen and concentrated the sugar and flavour to a syrup which is
still liquid, but is found throughout the ice-lattice, held there by
capillary action I suspect.

Concerning CS, at some point the solution becomes so concentrated that
the silver ions will precipitate out as a salt... silver
hydroxide/oxide I guess. I wonder if that can be resuspended into an
ionic CS again. If one heats silver oxide above 150C the oxide
decomposes... to what metallic silver? Could one make a fine metallic
silver powder this way? Mind you, it would take a lot of CS to make a
gram of silver powder.

Cheers
Ivan.

> -----Original Message-----
> From: Dean Miller [mailto:[email protected]]
> Sent: Monday, 16 December 2002 8:41 a.m.
> To: [email protected]
> Subject: Re: CS>Frozen CS
>
>
> Hi Marshall,
>
> On Sun, 15 Dec 2002 11:39:48 -0500, Marshall Dudley
> <[email protected]> wrote:
>
> >You can freeze sea water and get virtually pure water in
> the ice. All the
> >dissolved salts in sea water are ionic.  I see no reason
> well water should be
> >different.
>
> I agree, freezing salt water will produce mostly pure water
> ice.  But
> ... have you ever had a Popsicle?  :)   Ivan can probably
> tell us what
> conditions are necessary to freeze substances along with the ice.
>
> If I can find the time, I'll try freezing some CS and then melt and
> test it's ppm rating (now to find a glass ice cube tray).
>
> -- Dean -- from (almost) Des Moines -- KB0ZDF


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