Hi Trem,

1. ANY HVAC system will make both NO and NO3 due to the nitrogen
adsorbed in the DW. Stephen Quintro distills under Argon, transports
under Argon and brews under Argon. That is a mess. I have an Argon tank
but its not worth the effort.

2. It easiest method for the detection of NO3 is through pH. If the pH
is 6 or above then no worry, but when it gets down to around 3 or 4 then
one should check for NO3.

3. The "correction factor" for use of a PWT is generally due to the
formation of a weak acid. On the wide anode, narrow cathode sample that
I had Stephen check, the conductance was 12 and the PPM was 10. The pH
was 6.58.

As stated I have measured 1 ppm of NO3 in 37 v CS.

I can't answer your question as to the electro-chemistry  involved, but
a correction  factor to 1.6 or more for a PWT would cause me to wonder
about the NO3 value. In the hundreds of samples that I have checked
there have been less than a dozen the pH over 6. I generally do not
check LVDC for NO3 as the limits have been very low.

This I do know; with equal sized anode and cathode the ratio of Cond. to
PPM is large maybe 1.8 to 2, and pH's 5 or less.
With a ratio of anode to cathode of 8 to 1, the Cond. to PPM can be
about 1.2. and the pH's are over 6.
I find that  conductivity changes during the first 24 hours. What I
monitor during the test brews is not always the same after a few hours.
Why?  I do not know. I will try to find out.

In talking to Stephen we both agree that there are some factors in
making CS that we are not even aware of!

There is one area that I have just touched on and that is the energy
required to make CS. If you have Wplot32.exe you can put plot on the
tube and look at the top bar there is an option "transformations". With
this one can integrate the area under the current curve and get a value
dimensions of  MA- TIME. By adjusting the units and multiplying by
voltage on can get an energy equivalent to make the CS. The voltage
multiplier is not required for a constant voltage study. To do this for
your system will require a little more math as there is an additional
integral required for the change in voltage.

But the  MA-TIME comparison is wild. I will try and put something
together for you s I have the data but have not done the analysis.
Sufice it to say  when I did a casual look I could not rationalize what
I saw.

"Ole Bob"




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