url: http://escribe.com/health/thesilverlist/m60189.html
CS>Sludge on LVDC Electrodes
From: Marv Hacker (view other messages by this author)
Date: Fri, 13 Jun 2003 20:10:18

  > To: Mike Monett

  > Mike,

  > I have some photos of CS electrode coated with sludge, using LVDC.
  > I    tried   sending   them   to   your   last   reported  address
  > ([email protected]), but  the email was bounced. How  may I
  > get the info to you?

  Marv, Congratulations!  You  did  it  on  the  first  attempt.  I am
  sooooooo envious. It took me many tries to accomplish what you did.

  I hope you don't mind if I uploaded your pictures to help others see
  what you have accomplished.

  Here is a picture of your beautiful Gray Gunk:

  http://www3.sympatico.ca/add.automation/misc/2ece54fc.jpg

  And a picture of your setup:

  http://www3.sympatico.ca/add.automation/misc/2ece54f5.jpg

  What has  happened is you let the brew run for a very long  time. At
  very low  current density, this creates a small amount of  gray goop
  on the  cathode.  I believe Ole Bob mentioned this  is  silver atoms
  captured by hydrogen bubbles.

  When you reach this point, some of the current is wasted  making the
  goop. But  you  can reach very high ion concentration,  as  shown by
  your Hanna  PWT  measurement of 60 ppm. Congratulations  -  you have
  joined an elite crowd. Not many people have made 60  ppm, especially
  on their first try. As you can see, no stirring is needed.

  If you ran at much higher current density, such as the 1.4 mA/sq. in
  that I  used  to  use, the system would  have  collapsed  into black
  sludge long before this and you would have to throw it away.

  The cs  doesn't need to be this strong to be very effective.  60 ppm
  is far  too  strong to drink and may give you a  tummyache.  But you
  might pour it in a separate container and keep it covered with saran
  wrap to  prevent evaporation. It may start turning yellow  in  a few
  days. Please let us know what happens to it.

  Put about 1 inch in a glass and add three shakes of salt. You should
  get an  instant  response - the dispersion  should  be  strong milky
  white. You might even have to add more salt.

  Can I make some suggestions?

  Your system  is fine the way you designed it, and  would  work well.
  But you could improve it with the following:

  1. Double  the length of 12 ga wire to form a "W". This  doubles the
  wetted area  and makes it easier to get the proper  value  of series
  resistor. The 12 ga wire is strong enough to hold shape pretty well.

  2. Move  the  electrodes closer together - say to  about  0.75 inch.
  This reduces  the initial resistance which also makes  it  easier to
  get the proper resistor value. The strength of 12 ga helps  keep the
  proper spacing, but you won't have to wipe the electrodes  very much
  at these low currents.

  The close  spacing helps by reducing the ratio  between  the initial
  voltage and  final  voltage, which helps keep  the  current constant
  during the run. Here is an example on my system:

  --------------------------------------------------------------------

  Wed Jun  04,  2003,  01:00:57  pm  started  run  on  9V,  33k series
  resistor.

  Wed Jun 04, 2003, 01:01:35 pm 1.715V 196uA
  Wed Jun 04, 2003, 04:22:41 pm 1.155V 213uA
  Wed Jun 04, 2003, 05:06:06 pm 1.045V 216uA
  Wed Jun 04, 2003, 05:51:35 pm 0.9927 218uA
  Wed Jun 04, 2003, 06:12:32 pm 0.9626 218uA
  Wed Jun 04, 2003, 07:40:11 pm 0.8565 221uA
  Wed Jun 04, 2003, 08:10:43 pm 0.8491 221uA
  Wed Jun 04, 2003, 08:34:13 pm 0.8348 222uA
  Wed Jun 04, 2003, 08:42:21 pm 0.8040 222uA

  7.75 * 3600 * 220e-6 = 6.138 Coulombs

  --------------------------------------------------------------------

  However, the  purity  of your dw also affects the  initial  value. I
  look for medium quality dw which seems to work well.

  3. Put  a mark on the outside of the glass to show  the  fill point.
  Ideally, it should be above the middle loop of the "W", but you have
  to leave  enough  room  so the water doesn't  hit  the  top  when it
  sloshes while moving.

  You can add a mark very easily. Clean the outside of the  glass with
  isopropyl alcohol.  Take  an ordinary indelible marker  and  rest it
  against something  high  enough. Bring the glass up to  the  tip and
  rotate it.  You should get a smooth black circle  around  the glass.
  Cover it  with transparent Scotch tape, and never put  the  glass in
  the dishwasher.

  Pour some  water in the glass and measure the quantity  to  the fill
  point. This will help in making Coulomb calculations later.

  4. To  keep the top screws from rusting due to  the  humidity inside
  the jar,  coat them with acrylic nail polish. Any color  will  do. I
  prefer screaming  purple  so  it  is  easy  to  tell  when  they are
  completely covered.

  5. When  you settle on the value for the series resistor,  you might
  be able to mount it directly on the 9V battery clip, and  thread the
  alligator leads through two small holes in the fiber material.

  Cover it  with hot glue to seal it against moisture.  Make  sure you
  cut the alligator leads to different length to reduce the chance the
  ends will make contact and drain the battery.

  Congratulations, Marv. You did a fine job!
 
Best Regards,

Mike Monett


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