At 02:15 PM 10/5/2003 +0530, you wrote:
>Dear Ole Bob, Jason, Tony, Marshall, Trem, Everybody
>
>Thanks for all the helpful points, and I'm still something of a novice
>on the CS aspect of ceramic water purifiers.  But I have a comment and
>question on the need for stirring:  my understanding is that sometimes
>stirring is not needed, since the flask is kept at about 200oF.
>Wouldn't this bring about a kind of thermal stirring, dispersing the
>ions?

 ####Thermal stirring comes from a temperature 'differential'. The
'process' of Either heating or cooling will induce a thermal current.  Just
having a high or low temperature that stays constant won't.
 If the water is over about 120 deg F, excessive energetic motion
[Brownian?] will cause the particles to collide and grow larger from the
impacts.
 Stirring is not 'needed' but does help to overcome the effects of high
current densities and , in 'effect', lowers a low current density as well.
..something about the hydration of ions in a solution..blah blah blah.  [
archives..a long subject]

>
>Also, checking back in the literature, isn't it true that for CS that's
>generated with DC the only accurate procedure in the lab comes from a
>spectral analysis?  And how does the Hanna PWT do when measuring the
>very small particle sizes?

 #####Hanna meters do not measure particles...period. [ONLY ions..and
indirectly at that]
 None of the meters do anything but measure conductivity.

  Much of what I've seen on list concerns the
>way particles get bigger with additional ppm, but doesn't the frequent
>polarity reversal keep the particle size down?
###  Probably not.
 My idea is that the more particles and or ions that are packed in a space,
the more likely they will collide and pack together especialy during and
soon after production when everything is still a bit unstable.
 [The elements have not yet 'decided' what they will form and how.  Various
procedures help them make up their minds, so to speak]

  So in this method of
>making concentrated CS  I could have a huge percentage of small
>particles, of a size that will not be indicated by the Hanna PWT.  To
>imagine that I'm getting only 2.4 ppm, for this 9:1 solution, with
>bright orange color, pearly irredecence and strong TE, seems just
>utterly absurd.
####  If you are getting a green CS with a dense TE, you have many many
huge particles...about as big as they can get and still be called
colloidal...and very few conductive ions left in the dissolved state that a
meter will register on.
 A meter isn't a good way to measure PPM to start with and we use a 'fudge
factor' to compensate within  a "range" of PPM between about 18 to 24PPM.
But that fudge factor is not a constant.  The higher the concentration, the
higher the fudge factor..and no one knows 'how' high.
 If the CS is low PPM...  3-10 PPM? with no visible TE.  The reading will
be more direct.
 But it's still counting apples to see how many banannas you have.

Ode
>
>Is it true that for DC generated CS the Hanna device would indicate only
>about 10% of true ppm? 
##  Usually it's 90% of true PPM...but that depends on your CS.  The
greater the TE, the more 'off' it will be.

 So if my 9:1 dilute is indicating 2.4 ppm it's
>really 24ppm.  And my undiluted CS would be more like 240ppm?  From what
>I'm seeing this kind of concentrated CS is a very different animal by
>comparison to the 10 to 20 ppm CS.
##  You bet!

  I would be highly appreciative if
>someone could suggest a different kind of regime for testing ppm, ionic,
>particulate or whatever, CS of this very particular variety.  This
>regime would be especially necessary to small cities, where the lab
>resources may be a bit limited.
##  I think you are condemmed to a wild guess.
  I think that even the 'average' lab is only making a educated guess.

Ode


>As usual you guys are an indespensible lifeline.
>Reid
>
>Ole Bob said:
>Hi Reid,
>
>When I introduced polarity switching about 5 years ago I did a study on
>swithing times but always with a 50% duty cycle. I started with 12 x 12
>sec
>and advanced to 120 x 120 sec. I  found that the 60 x 60 was the best
>comprise. I did sell about a dozen EZCS2 units with motorized stirring.
>
>When I fist present ed the idae of polarity switching there was
>resistance to
>it with some saying that I was blowing the oxides or something back into
>the
>CS, it has become universally used.
>
>"Ole Bob"
>
>
>
>
>
>
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