Dan Nave wrote:

> If my math is right, here is a rule of thumb that you can
> use for approximating the maximum concentration of CS when
> you make it...
>
> "The maximum concentration for 1 cup of CS made at 1
> milliamp for one hour would be approximately 17ppm."

I had computed about 20 ppm per hour for 20 mA into a gallon.  That works
out to be almost exactly the same.

>
>
> Reasoning:
>
> Each Coulomb of electricity will deposit .001118 grams of
> silver into solution.  A Coulomb is 1 ampersecond.
>
> For example, 1 cup of water is 227 grams.  Run it for 1 hour
> at 1 milliamp.
>
> Find the number of seconds:
> 1 hour = 60 seconds/minute x 60 minutes = 3600 seconds
>
> Find the number of Coulombs:
> .001 amps x 3600 seconds = 3.6 ampseconds = 3.6 Coulombs
>
> Find the amount of silver released:
> 3.6 columns x .001118 grams/coulomb = .00402 grams of silver
> released into solution
>
> Find the ratio or water to silver:
> 227 grams of water / .00402 grams of silver = 56467 / 1
>
> Find the parts per million:
> 1,000,000 / 56467 = 17ppm
>
> So, the rule of thumb would be:
>
> "The maximum concentration for 1 cup of CS made at 1
> milliamp for one hour would be 17ppm."
>
> This assumes that the current is at 1 ma from start to
> finish of the hour.  (If it took 1 hour for the current to
> go from zero to 1 ma then the concentration would be
> approximately half (8.5ppm) for that hour, assuming that the
> current increase is reasonably linear at this stage.)
>
> These values are approximate and indicate the *maximum*
> concentration you can get.  Your effective CS concentration
> will be somewhat less.

That is the big question.  When I ran this over the weekend, I ended up
with a good bit of black fluffy stuff that fell off the wires.  I am sure
that some current was wasted on making this, but how much is anyones guess.

Marshall

>
>
> Using this value you can quickly get a rough estimate of
> your (max) CS concentration by figuring out the number of
> cups in your jar, the run time in hours, and the current in
> milliamps.
>
> Dan
>
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