Ode Coyote wrote:

>  When using too much current, electrode ends close to the bottom, no
> stirring and lit from the bottom.. I have seen white particles at one
> electrode appearing to strean towards the other electrode, golden particles
> at the other appearing to go the other way and nothing in between.
>
>  Under one electrode a white dusty looking deposit forms that fairly hard
> to remove. That electrode develops a white coating that can go to a tan
> color if the process goes long enough. [Presumably silver hydroxide and/or
> silver trapped on hydrogen bubbles]

I believe that will be primarily silver oxide, and maybe some silver hydroxide
if the ionic content got too high.

>
>
> The other electrode accumulates a black deposit with a black spot
> underneath. [Presumably silver oxides]

I believe that to be finely divided silver metal. If you can rub it and it
turns to silver, that should indicate it is silver metal.

>
>
>  In between the spots will be metallic silver plateout like a mirror if you
> let it go for a long time. The mirror is virtually impossible to remove.
>
> While perusing chemical experiment sites etc, I have run across statements
> such as "silver hydroxide is more soluable than silver hydroxide"

I have seen this as well, and even emailed them for clarification, but got no
response.

>
>  Many things get mis stated on websites and even in scientific papers.
> One reference to silver hydroxide being black begs confirmation from
> elsewhere.
>  They may have 'meant' to say silver oxide.

I am not sure silver hydroxide can even be in a solid form, I think it is too
unstable to dry without forming silver oxide.  But I still can't find any good
references.

Marshall

>
>
> Ode
>
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