Was there any discussion on how these nanoparticles
were produced?  I suppose it's not something the
average person could make?

-Ken Bagwell


--- Marshall Dudley <[email protected]> wrote:

> Ode Coyote wrote:
> 
> >  "Scientists studied the absorption spectra of the
> different preparations
> > to pinpoint their shapes. "Spherical nanoparticles
> absorbed in the blue
> > region of the spectrum, for example," Yacaman
> said."
> >
> > ##  So, "color" isn't 'entirely' about size, but
> is something much more
> > complex especially when shapes of impure crystals
> can vary in a fractal
> > pattern according to the nucleating particle
> center that the crystal grows
> > upon.
> 
> Yes, this is known, and covered in some of the
> references I have posted in the
> past.  Basically a silver particle is like a small
> antenna, and will have a
> resonant frequency.  Light at the resonant frequency
> will be absorbed, and as
> the particle increases in size, then the resonant
> frequency decreases (resonant
> frequency will be 4 times the length of time it
> takes for electricity to travel
> from one margin of the crystal to another, just like
> with a 1/4 wavelength
> antenna), moving the absorption band from uv, to
> violet, blue, green, yellow,
> orange, red, and infrared as the crystal grows
> larger.  The apparent color is
> of course the complement of the absorbed color.
> 
> Now if you make an antenna  in the shape of a
> snowflake, you will have a myriad
> of resonances, some low frequency across the whole
> flake, but others within the
> center, arms and areas at the end of the arms, each
> having their own
> resonances, and these will all be much higher
> resonances than the one across
> the whole thing. Exactly the same thing happens with
> silver crystals, except
> the frequencies are not in the radio range, but the
> light ranges.  The physics
> is actually quite well understood, although
> computing all the resonances for an
> irregular shape becomes difficult if not impossible.
> 
> Marshall
> 
> 
> 
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