PPM concentration can only be determined by and AA or spectrophotometer (which 
I have).
Your PWT readings and calculations do not take into account the loses due to 
the formation of silver oxide on the cathode.
 
If you check the conductuvuty with your PWT just after making a batch and then 
about every 12 hours you will be surprised how much it will change.
 
Thermal stirring does not do as good a job of distributig the silver ions being 
formed as does the mechanical stirring.  The measure the effectiveness of your 
method go about half way through your process and note the current then turn 
off the supply for 10 seconds and note the new reading.
 
I am trying to write a small booklet with pictures, data plots, and diagrams 
for the newbies. 
 
"Ole Bob"