Maybe you’re seeing this? This Tandem option is on by default:


http://www.thegpm.org/tandem/api/pqa.html







*From:* [email protected] [mailto:
[email protected]] *On Behalf Of *GATTACA
*Sent:* Tuesday, May 14, 2013 11:42 AM
*To:* [email protected]
*Subject:* [spctools-discuss] X!Tandem/TPP adding modifications not
specified



This is a weird one: X!Tandem/TPP seems to be inserting n-terminal
acetylation modifications to searches without being told to do so.

Since updating our pipeline to TPP 4.6.2 we are occasionally seeing
n-terminal acetylation (+42@[) in our results.

For instance, the input.xml file contains:
<note type="input" label="residue, modification mass">57@C</note>
<note type="input" label="residue, potential modification mass">
15.994915@M,80@S,80@T,80@Y</note>


Looking at the output of Tandem2XML I see that it detects the modifications
shown above, but it also detects +42@[
<terminal_modification terminus="n" massdiff="42.0106" mass="43.0184"
protein_terminus="N" variable="Y" symbol="^" /><!--X! Tandem n-terminal AA
variable modification-->


We never specified the n-terminal modification. The raw X!Tandem XML output
does *NOT* indicate that this modification was provided. So where is it
coming from?

It appears to occur randomly. It has been observed in different samples
from different labs.
When it does happen, the file sizes for the search results are
significantly inflated (ie: file sizes are > 40MB when usually are in the
range of 8-10MB).

I've looked at the default_input.xml files used by X!Tandem and the +42@[
isn't given there.

Any suggestions?

Thanks

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