Hi Jianqiao, although I am not 100% certain, I do not recall any SpectraST
feature where it will try to match a spectrum to a library entry outside
the normal tolerance window, but corrected for an alternate charge state.



This is an interesting idea for a feature, I hadn’t thought about this
before. It might be successful in matching some additional spectra, at
least for 2+ and 3+, which often look similar. But not yet possible.



Maybe Henry can correct me or provide additional thoughts.



Regards,

Eric





*From:* [email protected] [mailto:
[email protected]] *On Behalf Of *Jianqiao Shen
*Sent:* Sunday, June 25, 2017 1:45 PM
*To:* spctools-discuss
*Subject:* [spctools-discuss] SpectraST question about different charge
states of candidate library spectra and query spectra



Hi,



I am using SpectraST to build a spectral library. I know that the precursor
m/z of candidate library spectrum should be in tolerance of query spectrum.
My question is whether SpectraST can match the candidate library spectrum
with the query spectrum if their precursor have different charge states.



For example, we have spectrum A in library and its corresponding peptide
sequence is XXXXX with mass 1000, and the charge of precursor is 2 so the
precursor m/z is 500. We also have the query spectrum B and its peptide
sequence is XXXXX with mass 1000 as well but the charge of precursor is 3
so the precursor m/z is 333. Can SpectraST match the candidate library
spectrum A with query spectrum B regardless of their different charge?



Thank you!

Jianqiao Shen



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