Will,

XPRESS extracts precursor intensities from MS1 scans and your mzXML file
contains only MS/MS scans.  So that's why XPRESS is failing because it's
expecting to parse MS1 scans which aren't present in this file.

Jimmy

On Fri, Apr 7, 2023 at 8:57 AM Will Comstock <[email protected]> wrote:

> Hi all,
>
> I'm trying to use tSIM-ddMS2 to identify specific peptides in my sample,
> but I also want SILAC quantification of those peptides using XPRESS. I've
> made sure the MS1 isolation window is wide enough to see both Light and
> Heavy peptide peaks for everything in my inclusion list (30 daltons, so my
> heavy peptides which are +8 or +10 are detected). However, when I search
> with Comet and XPRESS, there is no quantitative ratio provided, just -1.0.
> XPRESS appears to be looking in the wrong place for the light and heavy
> peptides, but I am not sure why or how to redirect it to the right parts of
> my MS1 spectra. If I look at the precursor scans manually via QualBrowser,
> both peaks are definitely being detected.
>
> Has anyone here tried using XPRESS to do SILAC quantitation in targeted
> runs before?
>
>
> Here is a folder with my data, search parameters, and database just in
> case.
>
> https://drive.google.com/drive/folders/1142YHaxB1RC6HMcfuy_MdEN8T-sSLDSl?usp=sharing
>
> Thanks!
> -Will
>
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