Good catch, I will try to redo the RAW conversion to include my MS1 scans.
Thanks Jimmy!

-Will

On Fri, Apr 7, 2023 at 12:50 PM Jimmy Eng <[email protected]> wrote:

> Will,
>
> XPRESS extracts precursor intensities from MS1 scans and your mzXML file
> contains only MS/MS scans.  So that's why XPRESS is failing because it's
> expecting to parse MS1 scans which aren't present in this file.
>
> Jimmy
>
> On Fri, Apr 7, 2023 at 8:57 AM Will Comstock <[email protected]> wrote:
>
>> Hi all,
>>
>> I'm trying to use tSIM-ddMS2 to identify specific peptides in my sample,
>> but I also want SILAC quantification of those peptides using XPRESS. I've
>> made sure the MS1 isolation window is wide enough to see both Light and
>> Heavy peptide peaks for everything in my inclusion list (30 daltons, so my
>> heavy peptides which are +8 or +10 are detected). However, when I search
>> with Comet and XPRESS, there is no quantitative ratio provided, just -1.0.
>> XPRESS appears to be looking in the wrong place for the light and heavy
>> peptides, but I am not sure why or how to redirect it to the right parts of
>> my MS1 spectra. If I look at the precursor scans manually via QualBrowser,
>> both peaks are definitely being detected.
>>
>> Has anyone here tried using XPRESS to do SILAC quantitation in targeted
>> runs before?
>>
>>
>> Here is a folder with my data, search parameters, and database just in
>> case.
>>
>> https://drive.google.com/drive/folders/1142YHaxB1RC6HMcfuy_MdEN8T-sSLDSl?usp=sharing
>>
>> Thanks!
>> -Will
>>
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