Sorry none available. 

Chris 

-----Original Message-----
From: [email protected]
[mailto:[email protected]] On Behalf Of Forest Wilson
Sent: Wednesday, April 22, 2009 8:22 AM
To: [email protected]
Subject: Re: antifreeze combustibility?

Tonight please repeat the experiment using glycerin, then ethyl glycol. 
Forest Wilson 

-----Original Message-----
From: "Chris Cahill" <[email protected]>

Date: Wed, 22 Apr 2009 08:08:08 
To: <[email protected]>
Subject: RE: antifreeze combustibility?


So I did some fire testing last night with PG.  I used a spray bottle to see
what would happen with pure and 50/50 mix.

Pure sprayed into a fire definitely causes a flash of extra burning.  This
makes sense in the atomization and low flashpoint.  

Now when mixed 50/50 the same effect did not occur.  There may be a
contribution to the fire but it's very, very small at best.  Really it
appeared the spray was putting out the fire.  Steam was being created as one
would expect by spraying water on a fire.

How realistic, I don't know.  The drop size I was using was much smaller
than a typical head.  The rate of application was much smaller but so was my
fire.  I won't suggest a scaling effect but it's possible.  Did this lead to
fire in pure that wouldn't ordinarily be there?  Maybe, probably depends on
the size of the fire and the drop size in real circumstances.  The other
interesting thing with pure is I got some residual drops to flash.  When I
threw the plastic bottle in the fire that had some residual in it it flashed
as if I put gasoline on the fire.  Slightly delayed though while achieving
the flash point.  What this tells me is the possibility on a very large AF
system with pure one might have a problem if the pure warms up enough before
the application of the water.  Bottom line is I wouldn't use pure in any
circumstance. 

Mix I'm not so worried about. I used 50/50 because that's typical around
here considering our slightly cool weather.  

On the slush thing below the freeze point that's apparently the difference
between the freeze point and burst point.  Both numbers are reported on some
information sheets.  The number we typically use (NFPA 13) are freeze points
where in the lab is the first evidence of ice crystal formation.  The burst
point is much colder (-50ish) where a full solid is formed and will break
things.  What's nice about this is the "safety factor or tolerance" in
mixing might not be so critical.  There is a little play.  I think it's the
equivalent to the difference between flashpoint and fire point with
combustible liquids.         

Chris Cahill, P.E.
Fire Protection Engineer
Sentry Fire Protection, Inc.
 
763-658-4483
763-658-4921 fax
 
Email: [email protected]
 
Mail: P.O. Box 69
        Waverly, MN 55390
 
Location: 4439 Hwy 12 SW
              Waverly, MN 55390
-----Original Message-----
From: [email protected]
[mailto:[email protected]] On Behalf Of George Church
Sent: Tuesday, April 21, 2009 3:19 PM
To: [email protected]
Subject: RE: antifreeze combustibility?

And to think you could have just set it outside 2 months ago and made it
solid :)

Seriously, I think Noble Co would have your answers. They make a lot of
premix, concentrate, both flavors, and the special Hastings style for big
heads in cold places.

glc

-----Original Message-----
From: [email protected]
[mailto:[email protected]] On Behalf Of Chris Cahill
Sent: Tuesday, April 21, 2009 3:46 PM
To: [email protected]
Subject: RE: antifreeze combustibility?

I took some 50/50 and added dry ice to bring it down to -37.  Definitely
slushy not frozen though it should have been.  It would come out of a
sprinkler head but not terribly effective.  Think milk shake from McDonalds
after about 20 minutes at room temperature.   

Chris Cahill, P.E.
Fire Protection Engineer
Sentry Fire Protection, Inc.
 
763-658-4483
763-658-4921 fax
 
Email: [email protected]
 
Mail: P.O. Box 69
        Waverly, MN 55390
 
Location: 4439 Hwy 12 SW
              Waverly, MN 55390

-----Original Message-----
From: [email protected]
[mailto:[email protected]] On Behalf Of Matthew J.
Willis
Sent: Tuesday, April 21, 2009 2:35 PM
To: [email protected]
Subject: RE: antifreeze combustibility?

How about the "thickening" of the solution?

R/
Matt

 
Matthew J. Willis
Norred Fire Systems L.L.C.
318-387-1134 Voice
318-387-1163 Facsimile
[email protected]
-----Original Message-----
From: [email protected]
[mailto:[email protected]] On Behalf Of Ford, Charles
Sent: Tuesday, April 21, 2009 2:20 PM
To: [email protected]
Subject: RE: antifreeze combustibility?

Todd and others, I've heard of contractors using 100% anti-freeze on small
systems 'cause " the guys
aren't good at math and what harm is it?" I pointed out that freeze point
rises beyond 40-50%. The
flammability issue didn't occur to me.

C. Burton Ford
Designer- NICET Certified: Fire Alarm,
Special Hazards, Sprinkler Design
&Sprinkler Inspections
NFPA CFPS
Cintas Fire Protection-D-47
Warminster, PA 18974
Phone 267-487-1000
Fax 267-487-1010
-----Original Message-----
From: [email protected]
[mailto:[email protected]] On
Behalf Of Todd Williams
Sent: Tuesday, April 21, 2009 3:12 PM
To: [email protected]
Subject: RE: antifreeze combustibility?

This all begs a lot more questions:

1. Has this scenario be reproduced in a lab or other controlled
environment? Full scale testing?
2. How does concentration impact reaction?
3. Was the antifreeze a pre-mix solution or mixed by the contractor?
4. Does the antifreeze and water separate over time?
5. If this is an issue, why hasn't NFPA been more proactive?
6. Glycerine vs. Propylene Glycol?
7. Does is react to flame or only a heat source?




At 03:02 PM 4/21/2009, you wrote:
>Members,
>
>A settlement was reached in this matter. The public information that is
>available is as follows;
>
>The area in question was a covered deck protected with sprinklers
>utilizing antifreeze. At some point the deck was enclosed and heaters
>added. Apparently the antifreeze and ordinary temperature sprinklers
>remained. Heater operation resulted in sprinkler operation wherein a
>"fireball" was described.
>
>John Drucker
>
>
>-----Original Message-----
>From: [email protected]
>[mailto:[email protected]] On Behalf Of
>[email protected]
>Sent: Tuesday, April 21, 2009 2:39 PM
>To: [email protected]
>Subject: RE: antifreeze combustibility?
>
>It seems curious that there was an antifreeze system close to a unit
>heater.  If you have an antifreeze system it would seem you don't need
>the heater and vice-versa.  Hopefully the additional details to follow
>will answer that question also.
>
>
>
>An incident related to antifreeze occurred at the WindanSea, Highlands,
>
> >NJ where a sprinkler system containing antifreeze discharged in
> >proximity to a unit heater. The atomized liquid was ignited by the unit
>
> >heater and occupants burned from the fire that resulted.
>
>John Hoffman P.E. | Fire Protection Engineer | Facility Engineering
>Services, KCP, LLC - Burns & McDonnell Engineering | National Nuclear
>Security Administration's Kansas City Plant | Operated by Honeywell FM&T
>| 2000 E. 95th St | Kansas City, MO  64131 | ph 816-997-7213
>
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Todd G. Williams, PE
Fire Protection Design/Consulting
Stonington, Connecticut
www.fpdc.com
860.535.2080
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