Dear Tom

Given that biochar seems to be a good addition to manure and compost, what 
about purposely adding it to food scraps intended for animal feed, for the 
medicinal benefit that ingested charcoal may provide?

1: Is there any known detrimental effect to animals consuming charcoal?
2: Is there any reason to believe that animals would find charcoal fines in 
their food as unpalatable?
3: Would chickens perhaps seek out charcoal particles as a "grit substitute?"

If nothing else, at least manure from animals fed charcoal would produce 
"pre-biocharred manure." :-)

Best wishes,

Kevin


  ----- Original Message ----- 
  From: Tom Miles 
  To: 'Discussion of biomass cooking stoves' 
  Sent: Monday, October 31, 2011 6:17 PM
  Subject: Re: [Stoves] [biochar-production] Re: Stoves Digest, Vol 14,Issue 17


  Frank,

   

  I can understand that carbon in different forms degrades at different rates. 
And dry AD systems are interesting. 

   

  When I add char to household food scraps it makes what appears to be a better 
quality of compost. I am also aware that In the developing world these same 
scraps might be used as feed. Maybe Paul, Art, or others have had experience 
with adding TLUD char to compost from food waste, litter, or manure.   

   

  Thanks

   

  Tom

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Frank Shields
  Sent: Monday, October 31, 2011 1:45 PM
  To: 'Discussion of biomass cooking stoves'
  Subject: Re: [Stoves] [biochar-production] Re: Stoves Digest, Vol 14, Issue 17

   

  Tom,

   

  The C/N ratio is almost useless in when preparing compost formulations 
contrary to what most people think.  The carbon is determined on a Total Carbon 
and so is nitrogen. What we really need is available C and N and the 
availability changes during the composting process. If you add wood chips to a 
compost they will be there in a large part when the compost is finished - so 
should not be counted. Oils  and other lipids will biodegrade quickly lowering 
the pH. Then it's the slow release of carbon to available form as the process 
continues. With nitrogen becoming available as ammonia the pH goes up. It can 
out-gas and be lost so availability of nitrogen should also be a continuous 
process. All this occurs with in  vegetative material  that has wood chips 
added only for porosity.

   

  So a measure of total N and total C at the beginning has little use and is 
only a guideline.  Real way is to measure the Total N and C at the beginning 
and again at the end to determine the C removed as CO2 IMO.  But to answer your 
question you might as well test for Total N and total C to get a C/N ratio with 
the char along with the wood chips. 

   

  As for food scraps; They are the hardest to compost unless well mixed in with 
a lot of other materials. That because they are readily available C and N and 
react fast and that causes smells and fluctuation in pH, hugh oxygen demands 
making anaerobic conditions etc. New interest is AD dry systems then aerobic 
composting remaining material that have been partial stabilized.  

   

  Frank

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Tom Miles
  Sent: Monday, October 31, 2011 1:01 PM
  To: 'Discussion of biomass cooking stoves'
  Subject: Re: [Stoves] [biochar-production] Re: Stoves Digest, Vol 14, Issue 17

   

  Frank

   

  If I am taking char from a TLUD and adding it to cooking scraps for compost 
do I ignore the carbon in the char when calculating the Carbon to Nitrogen 
ratio? 

   

  Thanks


  Tom

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Frank Shields
  Sent: Monday, October 31, 2011 12:05 PM
  To: 'Discussion of biomass cooking stoves'
  Subject: Re: [Stoves] [biochar-production] Re: Stoves Digest, Vol 14, Issue 17

   

  Dear Tom,

   

  For compost the purpose is to 'stabilize' the carbon to a point the 
environment can replenish oxygen and nutrients at a rate plants and biota is 
not effected.  When in an ag situation we have growers ready to supplement 
nutrients (nitrogen) at the ready when plants or lab tests indicate needed. 
Stabilized values I like to see is < 4 mg CO2-C / g organic matter / day.  This 
dry weight.  But many people use 8 mg CO2-C as a stabilized value. 

   

  I think biochar is not even in the picture for nitrogen up-take or oxygen 
depletion in an ag soil because they will be so low. Perhaps over time in a non 
ag environment the carbon may deplete the nitrogen  - put more likely just hold 
the nitrogen from being leached for later use. 

   

  Frank 

   

   

   

   

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Tom Miles
  Sent: Friday, October 28, 2011 11:50 AM
  To: 'Discussion of biomass cooking stoves'
  Subject: Re: [Stoves] [biochar-production] Re: Stoves Digest, Vol 14, Issue 17

   

  Crispin, Frank,

   

  Apart from fraud, it is nice to have a general indication of how much of the 
fuel will convert to a gas before burning and how much would, in theory, remain 
as char. IN practice you oxidize part of he "fixed" carbon as well. 

   

  In carbonization the volatile carbon is a useful indicator of the extent of 
carbonization. We look for volatile carbon to be less than 20% for most 
applications. That does not mean that all biochar needs to be less than 20% 
volatile carbon. Other measures of labile carbon would be helpful. 

   

  For biochar applications it would be useful to know how much of the carbon is 
likely to be consumed by organisms and will thereby have a demand on nitrogen 
or other nutrients. I have assumes that is the volatile fraction. How much char 
C do you include in calculating a C:N ration for composting, for example?  If 
you intend to deliver a char to a uses that will supply it's own N how much to 
you have to add? How much char from stoves can you estimate will have a demand 
on plant nutrients if used as biochar? 

   

  Tom

   

  From: [email protected] 
[mailto:[email protected]] On Behalf Of Crispin 
Pemberton-Pigott
  Sent: Friday, October 28, 2011 1:09 PM
  To: 'Discussion of biomass cooking stoves'
  Subject: Re: [Stoves] [biochar-production] Re: Stoves Digest, Vol 14, Issue 17

   

  Dear Frank

   

  My main disagreement is the term Fixed Carbon and that it means the total 
weigh DAF where it should be a measure of carbon in that fraction. I will need 
to get over that. 

   

  I assure you that Fixed Carbon does not have a clear and scientific meaning. 
I have given up hope with analyses that use the term. That means, it is 
'helpful' but not an exact measure of anything.

   

  It really is taken to mean the carbon that happens not to disappear when the 
sample is treated in a certain way. Treat it in another way and the 'fixed' 
portion changes so it is an inherent property of the protocol times the fuel, 
not a property of the fuel alone.

   

  The coal industry is so large that they feel they can get away with internal 
definitions and that makes huge problems for stovers because we never really 
know what we are being handed to burn. With biomass that has historically been 
the 'chemistry' of the fuel contents. But the principal users of 'fixed carbon' 
are the coal consumers like power stations. To give the DAF value of anything 
is misleading because we need to know what % it is of the fuel, not of part of 
the fuel.

   

  There are many tricks played by people promoting processed fuels that involve 
switching the fuel energy content numbers during the conversation. For example, 
people will report the 'as received' heat content as the fuel's heating value 
(which is true) and then point out that their 'Processing' increases this to a 
much higher 'DAF value' showing a '60% increase in energy per kg' even though 
it takes energy to remove the water and calculate out the ash.  Plain fraud. 
Whenever someone reports the energy content you have to not only ask on what 
basis the figure was derived, but also investigate the protocol to see if it 
really is what it claims to be. Many people believe that there is free energy 
to be harvested in this manner.

   

  Regards

  Crispin

   



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