Dear Rebecca

Firstly, I am concerned about the "Cristobalite Link" below, in that it seems 
to overlap "silica", "cristobalite", and other forms of quartz. See: 
http://www.quartzpage.de/gen_mod.html showing how various forms of quartz exist 
at various temperatures.
Note that "cristobalite" is one specific crystalline phase of quartz.

Secondly, what is important is the "respirable" dust that is actually respired. 

It is well known that respiring "silica dust" can cause "Silicosis". It is well 
known that "Small Particulate Matter emissions" from virtually any poor stove 
can cause serious health problems. Hence, the effort to design "stove systems" 
that minimize "Small Particulate Matter Emissions" into the living space, where 
they can potentially be respired.

Rice Hull Ash, even at 90% silica in the ash pit, is not a problem, in that it 
is in the ash pit, where it is not respired. On the other hand, an "apparently 
superior fuel" that only had say 25% silica content in the ash pit would be 
vastly more hazardous, if it vented 10 or 100 times as much ash into the living 
space, in respirable form.

This is where competent and meaningful stove design and testing comes into 
play. 

As has been said many times, "It is not so much the fuel, but the stove system 
design, that is good or bad."

Best wishes,

Kevin


  ----- Original Message ----- 
  From: Rebecca A. Vermeer 
  To: Paul Olivier ; [email protected] 
  Cc: Jon Anderson 
  Sent: Friday, June 14, 2013 3:44 AM
  Subject: [Stoves] Fw: : Re: Insulation and stove life


  Hello Paul,
  Larry just told me that the silica content of rice hull ash is over 90%.  At 
the ETHOS 2013 Conference, I saw a TURBO stove developed in the Philippines 
which used rice hull for fuel.  Given your comment below regarding cristobalite 
“which is a nasty carcinogen” and severely hazardous to human health (see link 
below), would you recommend the use of  rice hull as a household fuel for 
cookstoves? 

  Rebecca Vermeer

  CRISTOBALITE LINK:
  http://nj.gov/health/eoh/rtkweb/documents/fs/1657.pdf
  From: Paul Olivier 
  Sent: Wednesday, June 12, 2013 12:01 AM
  To: Discussion of biomass cooking stoves 
  Subject: Re: [Stoves] : Re: Insulation and stove life

  Paal,


  One thing I look for on my burner is that all burner holes support a flame 
throughout the process. If channeling occurs during the process or if char is 
being burned as the process comes to a close, then one can see burner holes 
that do not support a flame. This means that CO2 is being discharged from the 
burner holes, and of course CO2 does not burn. When CO2 is formed, this 
represents a big inefficiency, since combustion takes place far below the pot. 
When this happens the sides of the reactor can easily turn red hot and melt. I 
do not know how it is possible to spot the presence of CO2 if the top of the 
reactor stays open and does not have a lid with burner holes.


  If one turns up the fan a bit too high resulting in channeling, it can happen 
that only a few holes (among a total of 80 in my case) do not support a flame. 
If I turn the fan down a bit and shake the reactor, this problem is immediately 
corrected. Also the effect of the presence of CO2 can be spotted by the cook in 
another way. The distribution of heat to the pan is not even.


  Also many of the positive characteristics of biochar are lost when biochar is 
combusted and is reduced to ash. The combustion of biomass and biochar takes 
place when channeling occurs, and the combustion of biochar takes place if the 
fan is not turned off at the end of the process. Rice hull ash and rice hill 
biochar are not at all the same thing when it comes to growing plants. Also 
rice hull ash can easily contain cristobalite, which is a nasty carcinogen. 
Under ordinary conditions, no farmer should be handling this stuff.


  Thanks.

  Paul




  On Wed, Jun 12, 2013 at 1:06 PM, Paal Wendelbo <[email protected]> wrote:

    Ron

    By end of flame the color of the char is red to yellow, that indicate a 
temperature of 700 to 800 ˚C and when there is no smoke, complete combustion 
has taken place. Is that not good for biochar?

    Regards Paal W


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  -- 
  Paul A. Olivier PhD
  26/5 Phu Dong Thien Vuong
  Dalat
  Vietnam

  Louisiana telephone: 1-337-447-4124 (rings Vietnam)
  Mobile: 090-694-1573 (in Vietnam)
  Skype address: Xpolivier
  http://www.esrla.com/ 


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