>Hi all,
>I would like to try some experiments on hydrogen.
>First : What is the best way to make it out of water ? What electrodes
>should I use, so they don't go in solution ?
>What electrolite should I use ?
>Is there a link where I can find some information for beginners on this item
>?
>
>By the way : I have been driving over 100.000 km on BD now, without any
>problems at all. Just great!
>
>Met vriendelijke groeten,
>Pieter Koole
>Netherlands

Dag Pieter

"Caveman Chemistry" previously had a nice description and slide show 
of producing Chlorine, Hydrogen, and Lye from table salt, using PET 
bottles, flashlight batteries, glue and stuff. "Wire electrodes would 
be corroded by the lye and chlorine. We could use gold or platinum 
wire, but the poor man's inert electrode is carbon. The easiest place 
to get carbon electrodes is from a flashlight battery. It is 
imperative that you use ordinary flashlight batteries, not alkaline 
batteries, since alkaline batteries put the zinc in the center and 
the carbon on the outside. Ordinary flashlight batteries have a 
carbon rod down the middle and a zinc can on the outside."

Now that site has changed, and I can't find this section there anymore.
http://cavemanchemistry.com/cavebook/index.html
Caveman Chemistry

Only these:
http://www.cavemanchemistry.com/cavebook/chchloralkali2.html

http://www.cavemanchemistry.com/cavebook/chchloralkali.html

Here's the previous text though, below, without the slide show, hope 
it makes sense.

regards

Keith



Here are the supplies we need: A 2-liter soft drink bottle, 2 smaller 
soft drink bottles (about 500 mL each), 2 ordinary size D flashlight 
batteries, and some waterproof glue which will stick to PET plastic.

Wire electrodes would be corroded by the lye and chlorine. We could 
use gold or platinum wire, but the poor man's inert electrode is 
carbon. The easiest place to get carbon electrodes is from a 
flashlight battery. It is imperative that you use ordinary flashlight 
batteries, not alkaline batteries, since alkaline batteries put the 
zinc in the center and the carbon on the outside. Ordinary flashlight 
batteries have a carbon rod down the middle and a zinc can on the 
outside.

You should wear glasses and gloves for this part. Peel away the paper 
wrapper to expose the zinc can underneath.

Use pliers to peel away the zinc can, exposing the electrolyte paste 
within. Loosen up this paste until the carbon rod is free and then 
remove the carbon rod with pliers.

The electrolyte paste is not all that harmful, but it can be messy. 
Do not eat this paste, rub it all over your body, feed it to stray 
animals, rub it in your eyes, or any of the 1,268 other stupid things 
that could be done with it. Just throw it in the trash and wash your 
hands after handling it.

Just to cover all the bases, the same is not true for alkaline 
batteries. Their electrolyte paste is alkaline and it is caustic. You 
should definitely wash your hands soon after contact with this paste. 
But you won't get that contact in this project, since alkaline cells 
don't have carbon rods.

You need two carbon rods. Here they are, inert and electrically conductive.

You will cut the top off the 2 liter bottle and the bottoms off the 
two smaller bottles. The size of the smaller bottles doesn't matter 
as long as they fit inside the 2 liter bottle.

Take a pocket knife and cut two holes in the bottom of the 2 liter 
bottle. The holes should be just big enough to insert the carbon 
rods. The rods are about as big in diameter as a pencil, so if you 
start with a small hole, you can use a pencil to open up a smooth, 
round hole of the right size. Then insert the carbon rods, making a 
tight fit with the bottle.

You now need some kind of glue to seal the rods in place. I have used 
Plumbers Goop, which makes an excellent seal. Here I am using an 
epoxy that is specifically for plastic. The important consideration 
is that the glue must make a good waterproof seal with the PET 
plastic from which the bottle is made.

Once the carbon rods are sealed, push the two small plastic bottles 
into the large one. One carbon rod should protrude into each of the 
two small bottles. Take the caps off the small bottles and fill the 
large bottle to the brim with saturated salt water. Just keep adding 
salt until no more will dissolve. Screw the caps onto the small 
bottles and then pour water out of the large one until it is about 
half full. Amazingly, the small bottles will stay full of water.

I am powering the cell with 4 D cells in series (6 Volts total). The 
negative end goes to one carbon rod (the cathode) and the positive 
end goes to the other carbon rod (the anode). Bubbles will start to 
collect on the carbon rods and soon gas will collect at the top of 
each bottle. Hydrogen will be produced at the cathode and chlorine 
will be produced at the anode. The water will start out pH neutral 
but will become more and more alkaline as sodium hydroxide is 
produced.

Here is a close-up of the cathode with hydrogen bubbling up from it.



>----- Original Message -----
>From: "Bruce Crowder" <[EMAIL PROTECTED]>
>To: <biofuel@yahoogroups.com>
>Sent: Saturday, September 20, 2003 7:57 PM
>Subject: [biofuel] Re: Hydrogen Economy
>
>
> > Hi,
> >
> > I'm an engineer at a company that designs fuel reformers to convert
> > hydrocarbons into hydrogen, mostly for fuel cell applications but
> > also for other applications.  I'm not necessarily advocating this as
> > a solution to our dependence on fossil fuels, but there are a couple
> > factors that many people fail to consider when discussing these
> > options.  First, fuel cell systems that run on hydrogen are much
> > more efficient than internal combustion engines.  For example, a
> > fuel cell car that runs on hydrogen reformed from gasoline will get
> > about 50% more miles per gallon than a typical automobile.  Same
> > fuel goes into the tank but less is used for the same amount of
> > work.  Secondly, the current administration is having very little
> > impact on the development of this technology. The $1.2 billion that
> > Bush promised for fuel cell development is a tiny fraction of what
> > would be required to spur industry to refocus efforts towards a new
> > technology.  In the end, the technology that makes the most economic
> > sense and earns the highest level of confidence from the public will
> > win.
> >
> > I've got my money on biodiesel as the fuel of the future.
> >
> > -Bruce
> >
> > --- In biofuel@yahoogroups.com, Hakan Falk <[EMAIL PROTECTED]> wrote:
> > >
> > > I would agree with you, if it was higher R/P values for natural
> > gas. With the
> > > current 7 years for US, the demands of independence of import
> > becomes an
> > > even a more impossible dream. I do not have to describe the
> > current US
> > > situation on NG again. Hydrogen from NG achieve nothing and the
> > best
> > > bet is coal/nuclear at the end. It is already feverish activities
> > in US to
> > > build
> > > a lot more nuclear power stations.
> > >
> > > Hydrogen production at home? That will make Osama bin Laden happy.
> > >
> > > Hakan
> > >
> > >
> > > At 06:27 PM 9/20/2003, you wrote:
> > > > >Initially Hydrogen will come from US coal reserves and then
> > > > >central production with huge Nuclear Power Stations. To
> > > > >diversify from this, to consumer level is at best a naive dream
> > > > >and probably a deliberate attempt of scam.
> > > >
> > > >To some extent I think it will also come from natural gas
> > reformed at
> > > >the level of the home (and let us remember that H2 is presently
> > > >usually made from Natural Gas... about 90% I think).  And, as Ken
> > > >points out, from simple electrolysis using electricity delivered
> > to
> > > >the home.
> > > >
> > > >If they must have their H2 economy, I'd like to see H2 made from
> > other
> > > >sources, such as methane made from biomass, if they want to
> > establish
> > > >a sustainable economy of H2, but what do I know.
> > > >
> > > > >To hook up your car for consumer production of one of the
> > > > >most difficult gases to handle, cannot be a realistic dream.
> > > > >Osama bin Laden would be happy to know that the Americans
> > > > >will blow up themselves at the end.
> > > > >
> > > > >Maybe they are now building arguments for Bush to take the
> > > > >taxpayers money and pay for the upgrade of the grid.
> > > > >
> > > > >Hakan
> > > > >
> > > > >At 08:42 AM 9/20/2003, you wrote:
> > > > >>Hi
> > > > >>
> > > > >>Here's my two cents worth on the hydrogen economy.
> > > > >>Electrolysis of water is what will happen and the car
> > > > >>companies are promoting plugging into your home at
> > > > >>night to charge up for the morning commute.
> > > > >>
> > > > >>How much extra capacity will power companies need to
> > > > >>install to charge up all these hydrogen cars? Let's
> > > > >>say your car averages 20-horsepower (~15kW) for an
> > > > >>hour a day = 54MJoules/day.  I read somewhere that an
> > > > >>average house uses 0.75kW and if this means 24 hours
> > > > >>per day, 65MJoules/day.  It would interesting if
> > > > >>anyone has an "average" electric bill for comparison.
> > > > >>
> > > > >>
> > > > >>A lot of energy will be needed to charge up all those
> > > > >>millions of hydrogen cars and where will it come from?
> > > > >>
> > > > >>Best regards,
> > > > >>
> > > > >>Ken
> >
> >
> >
> >
> > Biofuel at Journey to Forever:
> > http://journeytoforever.org/biofuel.html
> >
> > Biofuels list archives:
> > http://archive.nnytech.net/
> >
> > Please do NOT send Unsubscribe messages to the list address.
> > To unsubscribe, send an email to:
> > [EMAIL PROTECTED]
> >
> > Your use of Yahoo! Groups is subject to http://docs.yahoo.com/info/terms/
> >
> >
>
>
>
>Biofuel at Journey to Forever:
>http://journeytoforever.org/biofuel.html
>
>Biofuels list archives:
>http://archive.nnytech.net/
>
>Please do NOT send Unsubscribe messages to the list address.
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