Your wastewater treatment plant ought to compensate you nicely
for taking charge of the grease trap waste. No doubt they would
be happy to pawn their grease skimmings off on you as well.

FFAs.......Theoretical limit or physical limit?

I don't believe Aleks lays a claim to any exact high point of
FFAs which can be converted when following the procedure outlined
in his ambient pressure method. At ambient pressure the primary
limiting factors are reaction time and diluted catalyst.

To establish a physical limit a series of tests would have to be
conducted. Even then, the results would be dependant upon time
limit. Some would have no problem with letting the reaction
extend for a lengthy period. Others would be more inclined
towards the McDonalds' drive thru method.

Todd Swearingen

----- Original Message -----
From: movember <[EMAIL PROTECTED]>
To: <biofuels-biz@yahoogroups.com>
Sent: Tuesday, August 20, 2002 10:14 PM
Subject: [biofuels-biz] Re: hi ffa feed stocks


> The high-ffa feedstock is from industrial food waste and grease
> traps. It doesn't smell very nice either!
>
> Out of interest, what is the upper limit of FFA that would be
suited
> to standard pressure, ~60 degrees C, Aleks-style two-stage
processing?
>
>
>
> --- In [EMAIL PROTECTED], "Appal Energy" <[EMAIL PROTECTED]> wrote:
> > Yes. HTP is required to obtain high esterification conversion
on
> > such material. I would suggest that you seek out your nearest
> > college's chemistry department head and/or chemical
engineering
> > department to determine exactly what ballpark you will be in
> > relative to pressure and temp.  They may also be willing to
> > assist you with the sampling
> >
> > 85% FFA feedstock is not derived from your run of the mill
fish
> > and chips outlet. It sounds more as if it's soap stock that
has
> > been removed during oil processing.
> >
> > Todd Swearingen
> >
> > ----- Original Message -----
> > From: movember <[EMAIL PROTECTED]>
> > To: <[EMAIL PROTECTED]>
> > Sent: Monday, August 19, 2002 9:03 PM
> > Subject: [biofuels-biz] Re: hi ffa feed stocks
> >
> >
> > > I am able to source large quantities of the high ffa
feedstock
> > (FFA
> > > 85%), however initial miniature tests (1 litre batches
using
> > Aleks'
> > > two stage Acid/Base method) have proved unsuccessful.
> > >
> > > Would the same process, under high Temperature/Pressure, be
> > > sufficient to convert feedstocks of this type? If this may
be
> > the
> > > case, then what mini-batch experiments could be done to
test
> > the
> > > feedstock?
> > >
> > > Much apreciated.
> > >
> > >
> > > --- In [EMAIL PROTECTED], "Appal Energy" <[EMAIL PROTECTED]>
wrote:
> > > > It's a bit difficult to say that acid/base catalysis
"falls
> > > > down," whether it be the ambient procedure as presented
by
> > Aleks
> > > > Kac or a HTP industrial procedure.
> > > >
> > > > Most of what industry achieves under high pressure and
> > > > temperature can be achieved at STP by conducting the
reaction
> > > > over prolonged periods, at moderate temperature and in
> > several
> > > > stages when necessary.
> > > >
> > > > To date we have experienced repeated success with STP
> > > > esterification, simply by prolonging the esterification
> > period to
> > > > 36-48 hours, generating a complete transesterification
> > reaction
> > > > on 3.5% FFA feedstock with but 1.5 grams of KOH per liter
of
> > oil
> > > > over a 36 hour period.
> > > >
> > > > Whether a repeat cycle is used on the esterification side
or
> > not,
> > > > it is necessary to separate the feedstock from any layers
> > that
> > > > formed during the esterification prior to conducting the
> > repeat
> > > > cycle or the base stage.
> > > >
> > > > Todd Swearingen
> > > >
> > > > ----- Original Message -----
> > > > From: goat industries <[EMAIL PROTECTED]>
> > > > To: <[EMAIL PROTECTED]>
> > > > Sent: Monday, August 19, 2002 4:19 PM
> > > > Subject: [biofuels-biz] hi ffa feed stocks
> > > >
> > > >
> > > > > Check out work done by Canakci and Van Gerpen. I'm
trying
> > out
> > > > their ideas,
> > > > > but finding it difficult to get good results. Also, an
acid
> > > > value of 1mg
> > > > > KOH/g = 0.5 % FFA. They identiified water formation in
the
> > acid
> > > > stage as the
> > > > > inhibiting part of the reaction, which is where Alek's
> > > > 'foolproof' method
> > > > > falls down (apparently).
> > > > >
> > > > >
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