The `quantum` module has a way to represent operators in various ways.
It is not necessarily the best way to do it in sympy, but if you want
to extend the dirac matrices it is probably the most straightforward
one.

Otherwise `diffgeom` has another approach to the same problem of
expressing a geometric entity as matrix in a basis.

In both cases it seems inappropriate to me to use the assumptions
subsystem for this. This is not an assumption about the geometrical
object itself, rather about the way you represent it. Doing it
explicitly seems more natural.

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