Powering the Future: China’s Superionic Hydride Ion Conductor Breakthrough

By CHINESE ACADEMY OF SCIENCES APRIL 24, 2023

Chinese scientists have developed the first superionic hydride ion
conductor capable of operating at ambient conditions. By targeting the
structure and morphology of trihydrides in rare earth elements and using a
mechanical ball milling method, the researchers were able to suppress the
electronic conductivity of lanthanum trihydride, transforming it into a
superionic conductor with record-high conductivities. This breakthrough has
potential applications in advanced clean energy storage and electrochemical
conversion technologies. The team intends to further explore the physics
behind the phenomenon and expand their method to other hydride materials.
Credit: Chinese Academy of Sciences

*Chinese scientists have created the first ambient-temperature superionic
hydride ion conductor, enabling advancements in clean energy storage and
electrochemical conversion technologies.*

Chinese scientists have developed the first superionic hydride ion
conductor at ambient conditions, according to the Dalian Institute of
Chemical Physics under the *Chinese Academy of Sciences*
<https://scitechdaily.com/tag/chinese-academy-of-sciences/>.

With strong reducibility and high redox potential, the hydride ion (H-) is
a reactive hydrogen species and an energy carrier. Materials that conduct
pure H- at ambient conditions will be enablers of advanced clean energy
storage and electrochemical conversion technologies.

Several H- conductors have already been developed in recent years, but none
of the materials could achieve superionic conduction at ambient conditions.

The research team targeted the structure and morphology of trihydrides —
hydrides containing three atoms of hydrogen per molecule — of certain rare
earth elements (REHx), including Lanthanum (La), according to a research
paper published in the journal Nature.

They innovatively adopted the mechanical ball milling method and deformed
lanthanum trihydride (LaHx) through impact and shear force, according to
the paper.

By creating nanosized grains and defects in the LaHx lattice, the
electronic conductivity of LaHx can be suppressed by more than five orders
of magnitude. This transforms LaHx into a superionic conductor with record
high conductivities at the ambient temperatures — minus 40
degrees Celsius to 80 degrees Celsius.

The researchers plan to explore the physics underneath the phenomenon and
extend the method developed in the study to other hydride materials to
broaden the material scope for pure H- conductors.

For more on this breakthrough, see *A New Era of Superionic Hydride
Conduction at Room Temperature*
<https://scitechdaily.com/charging-ahead-a-new-era-of-superionic-hydride-conduction-at-room-temperature/>
.

KR IRS 27423

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