On 15/07/11 10:24, Tom Van Baak (lab/iPad) wrote:
A primary frequency standard is one that faithfully implements the definition 
of the SI second. Thus primary standards are based on Cs. But not all Cs-based 
clocks are primary. CSAC, for example, is not a primary standard. Rubidium, 
hydrogen, quartz, or pendulum clocks are not primary.

There is an over-focus om the atom being used rather than the physical apparatus being used. Certain physical apparatuses (physical packages) has severe biases frequency so regardless of which atom used, you will have repeatability issues (build two devices, and they will tick differently).

However, for various reasons has different atoms (and isotopes) been chosen for various physical packages due to various reasons. For instance, rubidium has two isotopes which makes it feasable to create an optical pumping due to how the D1 and D2 lines of the isotopes is located.

Rubidium was investigated in beam configurations just as cesium.

In fact, Cesium wasn't even the most stable one when chosen. It was chosen for its lower frequency was deemed more practical to implement. Still, the early beam devices had severe systematic biases in their frequency and much work has gone into prediciting them, reducing them and compensating them.

The definition spells out zero magnetic field, zero temperature (zero 
velocity), and zero altitude on the earth's rotating geoid. There are many 
other practical physics details that need to be addressed. For a good example 
of what it takes to make a Cs clock a primary standard see:

http://tf.nist.gov/general/pdf/1497.pdf
http://tf.nist.gov/general/pdf/1846.pdf

So strictly speaking no Cs clock actually runs at exactly 9192.631770 MHz since 
you need a certain amount of magnetic field to isolate the hyperfine 
transition, you can't run at absolute zero, no labs are actually at sea level, 
and atoms are not simple toys, etc.

A lot of work is required to identify, predict, and quantify a host of factors. Again, 
please read or glance at those papers to appreciate the work that national metrology labs 
do to "make copies of the SI second" for their country.

The 9192631770 cycles per second thing is the easy poster statement, the unattainable goal so to speak. The real world is quite complex.

Today I would say that "digital cesium", i.e. the locking of C-field from the side-band Rabi responses is among the key technologies which needs to be in a cesium to compete for systematic error removals.

Cheers,
Magnus

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