Acquire::http::Proxy "http://123.456.7.8.sg:8080";; is not a command. It is a line to add to /etc/apt/apt.conf (for instance at the end of it). And I do not know what is the ".sg" for but it should not be there.

The lines in .bashrc will only have an influence on what you do in a terminal. If you want to use a graphical front-end to APT (and not apt-get or aptitude), I believe it will not have any influence.

The configuration through Synaptic's preferences should have worked...

There is something I am not sure about: has APT ever been able to access the repository from your system and with the same network interface? If it used to work, configuring a proxy does not look necessary (unless the proxy was added since then).

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