There usually (always?) is something like "Restore defaults" in the BIOS/UEFI configuration. Search for it.

Trisquel's documentation suggests "the USB installer provided by pendrivelinux.com" to create the live USB: https://trisquel.info/en/wiki/how-create-liveusb

I wrote a manual to configure the BIOS/UEFI to boot the live system... but it is in French (do you read French?): https://trisquel.info/fr/wiki/d%C3%A9marrer-un-syst%C3%A8me-live-installable

Notice that it is practically impossible to provide step by step instructions to configure the BIOS/UEFI because there are many different BIOS/UEFI configuration interfaces.

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