Assuming you have no important settings in LibreOffice I would suggest
removing the previous configuration:
1. Close all LibreOffice programs (if open)
2. Open a terminal
3. Run rm .config/libreoffice -r
Can you open it after doing this?
** Changed in: libreoffice (Ubuntu)
Status: New => Incomplete
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https://bugs.launchpad.net/bugs/1174374
Title:
libreoffice-calc crashes/hangs desktop on Ubuntu 12.10 and 13.04 when
opening a .xlsx file
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