I have the same problem with Ubuntu 13.04. 
If you look into the .xsession-errors(.old) file it will tell you:
==========================================

PolicyKit daemon disconnected from the bus.
We are no longer a registered authentication agent.
** Message: Got disconnected from the system message bus....

(deja-dup-monitor:2793): GVFS-RemoteVolumeMonitor-WARNING **: Owner of
the volume monitor org.gtk.Private.UDisks2VolumeMonitor disconnected
from the bus; removing drives/volumes/mounts

(update-notifier:2716): GVFS-RemoteVolumeMonitor-WARNING **: Owner of
the volume monitor org.gtk.Private.UDisks2VolumeMonitor disconnected
from the bus; removing drives/volumes/mounts

(nautilus:2393): GVFS-RemoteVolumeMonitor-WARNING **: Owner of the
volume monitor org.gtk.Private.UDisks2VolumeMonitor disconnected from
the bus; removing drives/volumes/mounts

(gnome-setting-daemon:3421): libupower-glib-WARNING **: Couldn't connect
to system bus: Failed to connect to socket
/var/run/dbus/system_bus_socket: File or directory not found

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https://bugs.launchpad.net/bugs/1157780

Title:
  "stop networking" crashes window manager

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