At 9:16 AM 12/3/4, Jones Beene wrote:
[snip]
>Let me direct your attention to "Thallium online"
>http://www.rxlist.com/cgi/generic/thallium.htm
>
>You will see that over 95% of the gammas in this situation
>would have a mean energy between 68-80 KeV but are coming
>from the transitory mercury isotope as the Tl life is so
>short. After an extended run, and with such a small amount
>used, and with a starting half-life of only 70+ hours, there
>is almost no Tl left to measure at the end of the run.


OK, I see you were referring to the Hg gammas at 80 keV.  Yes, these too
have a good penetraing power and are readily discriminated from tritium
betas. They too can be counted by ordinary geiger counters. Also, a 70 hour
half-life is plenty good for a tracer for water drops.  A test of whether a
cell is vulnerable to water drop entrainment shouldn't take more than an
hour.

BTW, I see the referenced medical web site uses "KeV".  The prefix "k"
(small k) is the standard prefix for kilo-, even though "M" is the standard
prefix for mega-.


[snip]
>...Anyway if lots of tritium was being
>produced, a fair amount of the bremsstrahlung gamma photons
>of about 3-6 keV would be seen.

These gamms have almost no pentrating power in water.  This is why organic
solvents are used for liquid scintillation counting.  The water is kept to
a few percent in the counting vials.

>
>This "should be" easily discriminated from the Tl emission,
>but not necessarily so - depending on the detector used and
>how the results were interpreted. That is why I asked the
>question.

I think it would be nearly impossible to confuse tritium with either 201Tl
or 201Hg.  You don't even need a multi channel analyser.

I think the important thing here is not to lose sight of the fact that
Cirillo's and various other boil-off enthalpy data may be suspect due to
the problem which P.J van Noorden so kindly pointed out.  This is an
important fact to consider when designing future boil-off experiments.

Regards,

Horace Heffner          


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