On Tue, Dec 1, 2015 at 3:33 PM, <[email protected]> wrote:

Furthermore a specific arrangement of atoms in a molecule or lattice may
> well create an asymmetric field.


If what is needed is a field that is not spherical, that is also an
interesting idea.  Perhaps hydrogen and deuterium accomplish this, e.g., as
in this photo, which shows charge density diagrams with 0, 1, and 2
hydrogen atoms in the middle of a palladium lattice:

http://i.imgur.com/3uKjFpi.png

The electron charge density for electrons orbiting the hydrogen atoms at
the center of the images are suggested by the Tsyganov and others to be
forced into a p-orbital, although I don't know how likely this is.  This
image is from p. 103 of this issue of JMCNS:
http://www.iscmns.org/CMNS/JCMNS-Vol17.pdf.

In this case, the electron orbitals pass by the sides of the palladium
atoms, creating a non-uniform charge distribution.

Eric

Reply via email to