Jones Beene wrote.
>
> Is it time for Fred to lecture the assembled experts on:
>
> Voltage-Threshold vs. Voltage-Gradient; and assorted other intermediary
> subjects which make water
> electrolysis anything but "known" (Gibbs free energy,
> Helmholtz layers and so on)?
>
 
May I suggest that you reread pages 25 through 40. Jones  
 
http://www2.ijs.si/~kkocevar/skripta.pdf
 
1] H. K. Christenson. Confinement effects on freezing and melting. J. Phys.: Condensed

matter, 13:R95–R133, 2001.

[2] S. Arcidiacono and D. Poulikakos. Oscillatory behaviour of nanodroplets.

Phys. Rev. E., 70:011505, 2004.

[3] S. Cuenot et al. Surface tension effects on the mechanical properties of nanomaterials.

Phys. Rev. B., 69:165410, 2004.

[4] Y. Sumino et al. Self-running droplet:emergence of regular motion from nonequilibrium

noise. Phys. Rev. Lett., 94:068301, 2005.

And:

http://electrochem.cwru.edu/ed/encycl/art-c03-elchem-cap.htm

And:

http://www.physics.rutgers.edu/~wchen/Madey_page/Full_Publications/PDF/madey_SSR_1987_T.pdf

And whatever else suits your fancy.  :-)

Fred

 
 
 

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