At 11:34 PM 6/22/2011, Finlay MacNab wrote:
If the relative humidity sensor measures capacitance then the dielectric constant of steam and the dielectric constant of steam plus water would be very different and yield very different readings.

A quick google search for capacitance measurement of steam quality yields several papers and a multitude of patents on the subject so it would seem that a measurement of steam quality from capacitance values is possible. A quick literature search for the dielectric constant of steam results in an avalanche of data about the dielectric constant of steam at various temperatures and pressures. There is even data at 100.1C and 1 atm.

Then again I am just a lowly chemist so what do I know?

About as much as anyone else outside their specialty. Maybe a little more.

Saying that a Google search leads to this or that without providing the actual search, and without showing what results you looked at, is less than helpful.

I did this search: http://www.google.com/search?q=capacitance+measurement+of+steam+quality&ie=utf-8&oe=utf-8&aq=t&rls=org.mozilla:en-US:official&client=firefox-a

I found papers, for example, on the measurement of steam quality using capacitance. The RH meters in question are not designed to use that approach. If they were, they would surely advertise it! (This is a valuable application.) You want to measure steam quality, see

http://www.thermochem.com/Geo_On-line_Steam_Quality_Measurement_Equipment

The equipment described is far more complex than these RH meters. I've suggested here a simple possibility for steam quality measurement or at least estimation, involving light passing through a glass tube containing the steam flow. I see this from Thermochem: "New – Laser-Based Steam Quality Meter is under Development and soon to be Commercial." It's pretty easy to guess what they are doing and, in fact, I've been involved in the design of equipment that does something like this with smoke particles in air (in wind tunnels).

They are simply observing the water droplets, directly, with lasers. My own suggestion was much simpler, it would detect dry steam but would not catch really large water droplets as much. My guess is that with some experimental work to calibrate it, it could set an upper bound on entrained water.

But for the gross measurements being done, seeing that steam is transparent, visibly, and with the tests suggested used by experienced steam engineers, should be enough. Has anyone thought of inviting an actual steam engineer to the demonstrations? That is *not*, apparently, Galanatini, a chemist from every piece of evidence I've seen. His company, touted as evidence of his expertise, does mostly chemistry with some environmental analysis, the kind that will use an RH meter. So he'd have a meter, but nothing there indicates steam quality measurement experience.

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