Hi Marc-André,

Sikandar is 100% right. The main problem is that all currently
implemented methods have a tabulated (step-wise constant) potential as
outcome.

We are working on implementing the simplex algorithm, which can use
arbitrary functional forms of the potential, but I can not guarantee
that it will be finished soon.

Cheers,

Christoph

2011/9/2 Sikandar Mashayak <[email protected]>:
> Hi
> Marc-André
>
> One way to determine LJ potential energy terms is to first obtain CG
> potential using IBI or IMC method and then fit 12-6 LJ functional form to
> it. Of course, the quality of fit would depend upon whether the CG potential
> has the LJ type shape or not.
>
> --
> sikandar
>
> On Fri, Sep 2, 2011 at 12:35 PM, Marc-André Dubois <[email protected]>
> wrote:
>>
>> Hi guys,
>>               Is there a way to obtain The Lennard-Jones potential energy
>> terms for the interaction between 2 CG beads from the radial distribution
>> function? Thank you,
>>
>> Marc-André
>>
>> Le 2011-09-01 à 12:21, Marc-André Dubois a écrit :
>>
>> > Victor,
>> >           I appreciate your answer. Basically, one goal of this
>> > investigation is to reproduce some of the amphiphilic behavior of a 
>> > molecule
>> > that we have synthesize here in the lab. We would like to simulate the
>> > transition from a aqueous environment to an apolar one and the conformation
>> > change of our molecule to better understand the mechanism of these types of
>> > molecules. The first idea was to use MARTINI to do this, so we tried using
>> > this tool, and we get some results but we would like to construct a more
>> > accurate coarse grained representation of the studied molecule.
>> >
>> > I will se the literature that you have propose. Thanks for your help,
>> >
>> > Marc-André
>> >
>> >
>> > Le 2011-09-01 à 12:02, Victor Ruehle a écrit :
>> >
>> >> Dear Marcc-André,
>> >>
>> >> are you now just asking about the technical aspect, or about the
>> >> method itself? If the latter, there is no clear answer to your
>> >> problem. There are various methods available. The first question you
>> >> should ask yourself is what kind of properties you want to reproduce
>> >> in with your coarse-grained model.
>> >>
>> >> Most methods implemented in VOTCA are structure based approaches (or
>> >> closely related to it) and therefore will most probably do wrong on
>> >> thermodynamics. You can e.g. check the VOTCA references
>> >> (http://www.votca.org/citations), there are also lot's of references
>> >> given in the papers for more details on the method or links to other
>> >> methods. That's still an incomplete list, but might be a good point to
>> >> start with.
>> >>
>> >> If you want to act on the rdfs, I would start with IBI (see section in
>> >> the manual). Otherwise, also force-matching or a hybrid approach might
>> >> be worth a try. It's not yet officially supported in VOTCA, but
>> >> depending on your system, it might be worth to have a look at what the
>> >> MARTINI force field people did.
>> >>
>> >> Don't hesitate to ask any further questions, but providing some more
>> >> details might help...
>> >>
>> >> Best,
>> >> Victor
>> >>
>> >> 2011/9/1 Marc-André Dubois <[email protected]>:
>> >>> Hi all,
>> >>>          I tried to follow the tutorials that you provide on your
>> >>> website. Coarse-grained models are not actually the biggest concern of my
>> >>> group, so I have to start from the basis. As I actually understand the
>> >>> thing, I have to:
>> >>>
>> >>> 1. constructs an atomistic representation of the system, which will
>> >>> give to you data to construct the coarse grained representation.
>> >>> 2. runs a molecular dynamic at the atomistic scale
>> >>> 3. obtains the radial distribution function for each of your CG beads
>> >>>
>> >>> From step 1 to step 3, I think that everything works fine. From these
>> >>> steps, how it is possible to find the actual interaction potentials of 
>> >>> the
>> >>> CG beads to constructs a forcefield that GROMACS will understand? I am 
>> >>> sorry
>> >>> that this question would seems trivial, but as I previously said, I am 
>> >>> not
>> >>> familiar with these kind of experiments. Thank you,
>> >>>
>> >>> Marc-André Dubois
>> >>>
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-- 
Dr. Christoph Junghans
Votca Core Developer

Web: http://www.votca.org

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