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http://news.bbc.co.uk/hi/english/sci/tech/newsid_622000/622018.stm

Friday, 28 January, 2000,
              15:50 GMT

              Scientists break emerald myths


              The research is reported in
              Science magazine



              A careful analysis of some of
              the world's most magnificent
              emeralds has shown the gem
              stones have secret histories.

              Three of the stones belonging
              to the collection of the Nizam
              of Hyderabad, an ancient
              Indian family, actually came
              from Colombia in the 16th
              Century and not, as legend
              tells, from Alexander the
              Great many years earlier.

              For more than 4000 years, the
              deep green of a flawless
              emerald has been treasured
              around the world as a symbol
              of eternal spring and
              immortality. The gemstone
              has been prized by the
              Egyptians, Romans - Emperor
              Nero surveyed the gladiators
              through an emerald monocle -
              the Moguls of India, the
              Aztecs, and the crowned
              heads of Europe, among
              others.

              But the history of many of the
              world's best gems is often
              shrouded in myth and
              difficult to trace. This led a
              team of researchers from
              France and Colombia to use
              the latest analytical
              techniques to determine the
              origin of nine famous stones
              that span a period from the
              Roman occupation of France
              until the 18th century.

              The study involved
              vaporising a microscopic
              portion of a stone with a laser
              and then analysing the
              isotopes, or different types, of
              oxygen atoms given off.

              Composition and
              temperature

              Oxygen isotope values in
              gems such as emeralds reflect
              the composition and
              temperature of the fluids that
              eventually crystallised to
              form the emerald, as well as
              the composition and
              temperature of the rocks that
              the fluids journeyed through
              before their consolidation into
              the gemstone.

              There is a narrow range of
              these isotope values for each
              site where emeralds have been
              discovered worldwide.

              Along with more traditional
              gemological aspects, such as
              optical properties and the
              inclusion of other materials,
              researchers can use these
              unique isotope values to
              pinpoint where an emerald
              was "born."

              The researchers, led by Gaston
              Giuliani of the Institut de
              Recherche pour le
              Développement and the
              Centre de Recherches
              Pétrographiques et
              Géochimiques-CNRS in
              Vandoeuvre, France, tested
              stones from all of the world's
              major emerald mines.

              Major surprises

              They found that some ancient
              emeralds came from deposits
              supposedly discovered in the
              20th Century, showing that
              these mines were known as
              far back as Roman times.

              A major surprise was the
              number of gems from
              Colombian mines. These
              emeralds were only traded
              worldwide after the Spanish
              invasion of Latin America in
              the 16th Century.

              Yet, three of the four major
              emeralds analysed from the
              collection of the Nizam of
              Hyderabad in India,
              supposedly from "lost" Asian
              mines, were actually from
              Colombia and not as legend
              tells from Alexander the Great
              (around 300 BC).

              The researchers now plan to
              apply the oxygen isotope
              technique to studying rubies.

              "This type of analysis was a
              small part of our work
              initially," said Giuliani. "But
              we see that as geologists
              working with gemstones and
              gemologists, we may be
              permitted to make a
              contribution to the study of
              trade and human history."

              The research is reported in the
              journal Science.

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