Re: [Biofuel] Fw: Electronic PH meter

2005-06-19 Thread Pieter Koole
Hi,
Is phenolphtalein the same as phenol red ?

Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: bob allen [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Saturday, June 18, 2005 3:52 PM
Subject: Re: [Biofuel] Fw: Electronic PH meter


 Howdy Kieth and Willem, the issue of the use of a pH meter as opposed to
other methods for
 determination of the end point of a titration comes up from time to time.
It seems that many
 believe one really needs a pH meter.  I think not and here is why.
Although a pH meter may be more
 accurate if all the variables were tightly controlled, they're not.  How
accurately can one measure
 the 1 ml of oil? One maybe two significant digits?  If different oils have
different densities,
 (they do but small) then one should really adjust the volume of oil used
in the titration
 accordingly. Because density is a function of temperature, how accurately
does one know the
 temperature? How accurately can one prepare the titrant solution? How
accurately can one measure the
 titrant? Finally the titration is done in a nonaqueous heterogeneous
solution, hence pH isn't even
 strictly defined; pH being defined as minus the log of the hydrogen ion
concentration in water. If
 you heat the oil/isopropyl alcohol mix to get homogeneity, the hydrogen
ion concentration changes.
 (It is actually worse, it is the hydrogen ion activity, but that is
another matter.)


 Hence use of a pH meter to me is overkill.  What you get is a very precise
endpoint for a titration
 which is really fairly inaccurate, due to the aforementioned difficulties
in the volumetric
 measurements, temperature, etc.

 I use phenolphthalein to determine the endpoint.  It is quick, requires no
calibration, costs a heck
 of a lot less than a pH meter, and provides sufficient precision for the
measurement at hand.


  Hi Willem
 
  Hi all,
 
  I am slowly getting the parts together to construct a small biodiesel
  set-up
  (approx. 30 litres).
  When I told a friend recently avout my plans he gave me an electronic
PH
  meter, pen type. Accuracy is 1 decimal. He said this would replace the
  titration, but could give me no more info.
 
 
  It won't replace titration, you use it for titration. You can use
  phenolphthalein, or pH test strips, or a pH meter - whichever you use,
  titration involves measuring the pH. See:
 
  Basic titration
  Better titration
  pH meters
  Phenolphthalein
  http://journeytoforever.org/biodiesel_make2.html#titrate
 
  pH meters are best, IMO. You need to calibrate them often (get
  calibration fluid from a lab supply) and you have to look after them
  properly. There's a Technical tips link at the url above.
 
  Best wishes
 
  Keith
 
 
  Can anyone tell me if this is so and how I convert the reading to the
  amount
  of lye to be used?
 
  Best regards,
  Willem
 
 
 
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 --
 Bob Allen
 http://ozarker.org/bob

 Science is what we have learned about how to keep
 from fooling ourselves - Richard Feynman

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[Biofuel] Fw: Electronic PH meter

2005-06-19 Thread Keith Addison

Hello Pieter


Hi,
Is phenolphtalein the same as phenol red ?


No.

You've already got the link, below:


  Basic titration
  Better titration
  pH meters
  Phenolphthalein
  http://journeytoforever.org/biodiesel_make2.html#titrate


It says:

Phenolphthalein is often confused with phenol red, obtained at 
pool supply stores and used for checking water. It's not the same 
thing, and phenol red won't really do for titrating WVO, its pH range 
isn't broad enough. It ranges from pH 6.8, at which point it's 
yellow, through orange, to a maximum of pH 8.2, red. For accurate 
titration you need to be able to measure pH 8.5.


Phenolphthalein is colorless up to pH 8.3, then it turns pink 
(magenta), and red at its maximum of pH 10.4. When it stays pink for 
more than 10 seconds, it's measuring pH 8.5.


With good-quality oil with low FFA levels you might just get away 
with using phenol red for titration, but for higher FFA levels it 
isn't accurate enough. Use 1% phenolphthalein solution (1.0w/v%).


Why don't you read the whole page, Pieter? Both pages:

http://journeytoforever.org/biodiesel_make.html
Make your own biodiesel

http://journeytoforever.org/biodiesel_make2.html
Make your own biodiesel - page 2

Keith



Met  dank en vriendelijke groet,
Pieter Koole

- Original Message -
From: bob allen bob at ozarker.org
To: Biofuel at sustainablelists.org
Sent: Saturday, June 18, 2005 3:52 PM
Subject: Re: [Biofuel] Fw: Electronic PH meter

 Howdy Kieth and Willem, the issue of the use of a pH meter as opposed to
other methods for
 determination of the end point of a titration comes up from time to time.
It seems that many
 believe one really needs a pH meter.  I think not and here is why.
Although a pH meter may be more
 accurate if all the variables were tightly controlled, they're not.  How
accurately can one measure
 the 1 ml of oil? One maybe two significant digits?  If different oils have
different densities,
 (they do but small) then one should really adjust the volume of oil used
in the titration
 accordingly. Because density is a function of temperature, how accurately
does one know the
 temperature? How accurately can one prepare the titrant solution? How
accurately can one measure the
 titrant? Finally the titration is done in a nonaqueous heterogeneous
solution, hence pH isn't even
 strictly defined; pH being defined as minus the log of the hydrogen ion
concentration in water. If
 you heat the oil/isopropyl alcohol mix to get homogeneity, the hydrogen
ion concentration changes.
 (It is actually worse, it is the hydrogen ion activity, but that is
another matter.)


 Hence use of a pH meter to me is overkill.  What you get is a very precise
endpoint for a titration
 which is really fairly inaccurate, due to the aforementioned difficulties
in the volumetric
 measurements, temperature, etc.

 I use phenolphthalein to determine the endpoint.  It is quick, requires no
calibration, costs a heck
 of a lot less than a pH meter, and provides sufficient precision for the
measurement at hand.


  Hi Willem
 
  Hi all,
 
  I am slowly getting the parts together to construct a small biodiesel
  set-up
  (approx. 30 litres).
  When I told a friend recently avout my plans he gave me an electronic
PH
  meter, pen type. Accuracy is 1 decimal. He said this would replace the
  titration, but could give me no more info.
 
 
  It won't replace titration, you use it for titration. You can use
  phenolphthalein, or pH test strips, or a pH meter - whichever you use,
  titration involves measuring the pH. See:
 
  Basic titration
  Better titration
  pH meters
  Phenolphthalein
  http://journeytoforever.org/biodiesel_make2.html#titrate
 
  pH meters are best, IMO. You need to calibrate them often (get
  calibration fluid from a lab supply) and you have to look after them
  properly. There's a Technical tips link at the url above.
 
  Best wishes
 
  Keith
 
 
  Can anyone tell me if this is so and how I convert the reading to the
  amount
  of lye to be used?
 
  Best regards,
  Willem
 



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Re: [Biofuel] Fw: Electronic PH meter

2005-06-19 Thread Pieter Koole
Thanks Keith.

Pieter Koole

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Sunday, June 19, 2005 2:05 PM
Subject: [Biofuel] Fw: Electronic PH meter


 Hello Pieter

 Hi,
 Is phenolphtalein the same as phenol red ?

 No.

 You've already got the link, below:

Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate

 It says:

 Phenolphthalein is often confused with phenol red, obtained at
 pool supply stores and used for checking water. It's not the same
 thing, and phenol red won't really do for titrating WVO, its pH range
 isn't broad enough. It ranges from pH 6.8, at which point it's
 yellow, through orange, to a maximum of pH 8.2, red. For accurate
 titration you need to be able to measure pH 8.5.

 Phenolphthalein is colorless up to pH 8.3, then it turns pink
 (magenta), and red at its maximum of pH 10.4. When it stays pink for
 more than 10 seconds, it's measuring pH 8.5.

 With good-quality oil with low FFA levels you might just get away
 with using phenol red for titration, but for higher FFA levels it
 isn't accurate enough. Use 1% phenolphthalein solution (1.0w/v%).

 Why don't you read the whole page, Pieter? Both pages:

 http://journeytoforever.org/biodiesel_make.html
 Make your own biodiesel

 http://journeytoforever.org/biodiesel_make2.html
 Make your own biodiesel - page 2

 Keith


 Met  dank en vriendelijke groet,
 Pieter Koole
 
 - Original Message -
 From: bob allen bob at ozarker.org
 To: Biofuel at sustainablelists.org
 Sent: Saturday, June 18, 2005 3:52 PM
 Subject: Re: [Biofuel] Fw: Electronic PH meter
 
   Howdy Kieth and Willem, the issue of the use of a pH meter as opposed
to
 other methods for
   determination of the end point of a titration comes up from time to
time.
 It seems that many
   believe one really needs a pH meter.  I think not and here is why.
 Although a pH meter may be more
   accurate if all the variables were tightly controlled, they're not.
How
 accurately can one measure
   the 1 ml of oil? One maybe two significant digits?  If different oils
have
 different densities,
   (they do but small) then one should really adjust the volume of oil
used
 in the titration
   accordingly. Because density is a function of temperature, how
accurately
 does one know the
   temperature? How accurately can one prepare the titrant solution? How
 accurately can one measure the
   titrant? Finally the titration is done in a nonaqueous heterogeneous
 solution, hence pH isn't even
   strictly defined; pH being defined as minus the log of the hydrogen
ion
 concentration in water. If
   you heat the oil/isopropyl alcohol mix to get homogeneity, the
hydrogen
 ion concentration changes.
   (It is actually worse, it is the hydrogen ion activity, but that is
 another matter.)
  
  
   Hence use of a pH meter to me is overkill.  What you get is a very
precise
 endpoint for a titration
   which is really fairly inaccurate, due to the aforementioned
difficulties
 in the volumetric
   measurements, temperature, etc.
  
   I use phenolphthalein to determine the endpoint.  It is quick,
requires no
 calibration, costs a heck
   of a lot less than a pH meter, and provides sufficient precision for
the
 measurement at hand.
  
  
Hi Willem
   
Hi all,
   
I am slowly getting the parts together to construct a small
biodiesel
set-up
(approx. 30 litres).
When I told a friend recently avout my plans he gave me an
electronic
 PH
meter, pen type. Accuracy is 1 decimal. He said this would replace
the
titration, but could give me no more info.
   
   
It won't replace titration, you use it for titration. You can use
phenolphthalein, or pH test strips, or a pH meter - whichever you
use,
titration involves measuring the pH. See:
   
Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate
   
pH meters are best, IMO. You need to calibrate them often (get
calibration fluid from a lab supply) and you have to look after them
properly. There's a Technical tips link at the url above.
   
Best wishes
   
Keith
   
   
Can anyone tell me if this is so and how I convert the reading to
the
amount
of lye to be used?
   
Best regards,
Willem
   


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Re: [Biofuel] Fw: Electronic PH meter

2005-06-18 Thread bob allen
Howdy Kieth and Willem, the issue of the use of a pH meter as opposed to other methods for 
determination of the end point of a titration comes up from time to time.  It seems that many 
believe one really needs a pH meter.  I think not and here is why.  Although a pH meter may be more 
accurate if all the variables were tightly controlled, they're not.  How accurately can one measure 
the 1 ml of oil? One maybe two significant digits?  If different oils have different densities, 
(they do but small) then one should really adjust the volume of oil used in the titration 
accordingly. Because density is a function of temperature, how accurately does one know the 
temperature? How accurately can one prepare the titrant solution? How accurately can one measure the 
titrant? Finally the titration is done in a nonaqueous heterogeneous solution, hence pH isn't even 
strictly defined; pH being defined as minus the log of the hydrogen ion concentration in water. If 
you heat the oil/isopropyl alcohol mix to get homogeneity, the hydrogen ion concentration changes. 
(It is actually worse, it is the hydrogen ion activity, but that is another matter.)



Hence use of a pH meter to me is overkill.  What you get is a very precise endpoint for a titration 
which is really fairly inaccurate, due to the aforementioned difficulties in the volumetric 
measurements, temperature, etc.


I use phenolphthalein to determine the endpoint.  It is quick, requires no calibration, costs a heck 
of a lot less than a pH meter, and provides sufficient precision for the measurement at hand.




Hi Willem


Hi all,

I am slowly getting the parts together to construct a small biodiesel 
set-up

(approx. 30 litres).
When I told a friend recently avout my plans he gave me an electronic PH
meter, pen type. Accuracy is 1 decimal. He said this would replace the
titration, but could give me no more info.



It won't replace titration, you use it for titration. You can use 
phenolphthalein, or pH test strips, or a pH meter - whichever you use, 
titration involves measuring the pH. See:


Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate

pH meters are best, IMO. You need to calibrate them often (get 
calibration fluid from a lab supply) and you have to look after them 
properly. There's a Technical tips link at the url above.


Best wishes

Keith


Can anyone tell me if this is so and how I convert the reading to the 
amount

of lye to be used?

Best regards,
Willem




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messages):

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--
Bob Allen
http://ozarker.org/bob

Science is what we have learned about how to keep
from fooling ourselves - Richard Feynman

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Re: [Biofuel] Fw: Electronic PH meter

2005-06-18 Thread Keith Addison

Howdy Bob

Howdy Kieth and Willem, the issue of the use of a pH meter as 
opposed to other methods for determination of the end point of a 
titration comes up from time to time.  It seems that many believe 
one really needs a pH meter.  I think not and here is why.  Although 
a pH meter may be more accurate if all the variables were tightly 
controlled, they're not.  How accurately can one measure the 1 ml of 
oil? One maybe two significant digits?


You can measure 4ml four times as accurately, so use 4ml and divide by 4. See:

Better titration
http://journeytoforever.org/biodiesel_make2.html#bettertitrate

Accurate measurement
http://journeytoforever.org/biodiesel_make2.html#measure

This is one of the reasons, among the more obvious ones, that we 
always recommend starting with one-litre test batches - you learn 
precision that way. Or as much precision as you're capable of.


If different oils have different densities, (they do but small) then 
one should really adjust the volume of oil used in the titration 
accordingly.


That will start to matter when you get to high-FFA oils titrating at 
say 7 or 8ml or above, very marginal at less than that IMHO. We've 
processed higher titration oils than 7 or 8 accurately and reliably 
(single-stage base) using pH meters, but phenolphthalein wasn't 
reliable at that level.


Because density is a function of temperature, how accurately does 
one know the temperature?


At processing temperature.

How accurately can one prepare the titrant solution? How accurately 
can one measure the titrant? Finally the titration is done in a 
nonaqueous heterogeneous solution, hence pH isn't even strictly 
defined; pH being defined as minus the log of the hydrogen ion 
concentration in water.


Bob, how can it be a non-aqueous solution when you're adding 0.1% v/w 
NaOH (or KOH) solution which is 99.9% water?


If you heat the oil/isopropyl alcohol mix to get homogeneity, the 
hydrogen ion concentration changes. (It is actually worse, it is the 
hydrogen ion activity, but that is another matter.)


But it will be the same as what's encountered in the subsequent processing.

Hence use of a pH meter to me is overkill.  What you get is a very 
precise endpoint for a titration which is really fairly inaccurate, 
due to the aforementioned difficulties in the volumetric 
measurements, temperature, etc.


We've had three different pH meters, well-calibrated and maintained, 
in consistent agreement and differing from phenolphthalein results, 
and the pH meter results were consistently borne out by the 
subsequent processing results, whereas phenolphthalein were off, this 
with high-FFA oils where you can really see the difference.


The phenolphthalein was obtained from two different lab supply houses 
and was fresh. We use phenolphthalein for demos and at our seminars 
because of the pretty pink colour and it's a cheap entry, but we 
seldom use it otherwise. At our workshops we use pH meters.


I use phenolphthalein to determine the endpoint.  It is quick, 
requires no calibration, costs a heck of a lot less than a pH meter, 
and provides sufficient precision for the measurement at hand.


To each his own Bob.

Best wishes

Keith





Hi Willem


Hi all,

I am slowly getting the parts together to construct a small biodiesel set-up
(approx. 30 litres).
When I told a friend recently avout my plans he gave me an electronic PH
meter, pen type. Accuracy is 1 decimal. He said this would replace the
titration, but could give me no more info.



It won't replace titration, you use it for titration. You can use 
phenolphthalein, or pH test strips, or a pH meter - whichever you 
use, titration involves measuring the pH. See:


Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate

pH meters are best, IMO. You need to calibrate them often (get 
calibration fluid from a lab supply) and you have to look after 
them properly. There's a Technical tips link at the url above.


Best wishes

Keith



Can anyone tell me if this is so and how I convert the reading to the amount
of lye to be used?

Best regards,
Willem



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Re: [Biofuel] Fw: Electronic PH meter

2005-06-18 Thread the skapegoat
I haven't done much with biodiesel yet, but I can shed some light on pH meters vs. phenolphthalien(PHTH) from a chemist's perspective.

As acids become weaker, it is important to become more careful in the selection of a chemical indicator (such as PHTH), as the change in pH is much slower than it is for a strong acid titration. PHTH is the most commonly used indicator for strong acid titrations because it has such a clear color change. Fortunately it appears to change color over the same range as the equivalence pt. for FFAs. 
The difficulty in either method is knowing what the equivalence point is going to be. This will vary based on the type of oil and the degree of hydrogenation. I don't suspect it will vary much, but it will vary. If your goal is a pH of 8 or 9, then usingPHTH is going to be as good as a pH meter. If you have a better idea of what the equivalence point is going to be, then a pH meter works better. And if you haven't a clue, there is a rather tedious method of determining what it should be using a pH meter. I'll probalby use this method myself at least once so I have a better understanding of the behavior, but I wouldn't necessarily recommend it for everyone, and I certainly am not going to do it for each batch.
The point is there are a number of reasons why PHTH may not work as well as a pH meter in some cases yet works fine in other cases. This is something I think everyone will have to decide for themselves.



Keith Addison [EMAIL PROTECTED] wrote:
Howdy BobHowdy Kieth and Willem, the issue of the use of a pH meter as opposed to other methods for determination of the end point of a titration comes up from time to time. It seems that many believe one really needs a pH meter. I think not and here is why. Although a pH meter may be more accurate if all the variables were tightly controlled, they're not. How accurately can one measure the 1 ml of oil? One maybe two significant digits?You can measure 4ml four times as accurately, so use 4ml and divide by 4. See:Better titrationhttp://journeytoforever.org/biodiesel_make2.html#bettertitrateAccurate measurementhttp://journeytoforever.org/biodiesel_make2.html#measureThis is one of the reasons, among the more obvious ones, that we always recommend starting with one-litre test batches -
 you learn precision that way. Or as much precision as you're capable of.If different oils have different densities, (they do but small) then one should really adjust the volume of oil used in the titration accordingly.That will start to matter when you get to high-FFA oils titrating at say 7 or 8ml or above, very marginal at less than that IMHO. We've processed higher titration oils than 7 or 8 accurately and reliably (single-stage base) using pH meters, but phenolphthalein wasn't reliable at that level.Because density is a function of temperature, how accurately does one know the temperature?At processing temperature.How accurately can one prepare the titrant solution? How accurately can one measure the titrant? Finally the titration is done in a nonaqueous heterogeneous solution, hence pH isn't even strictly defined; pH being defined as minus the log of the
 hydrogen ion concentration in water.Bob, how can it be a non-aqueous solution when you're adding 0.1% v/w NaOH (or KOH) solution which is 99.9% water?If you heat the oil/isopropyl alcohol mix to get homogeneity, the hydrogen ion concentration changes. (It is actually worse, it is the hydrogen ion activity, but that is another matter.)But it will be the same as what's encountered in the subsequent processing.Hence use of a pH meter to me is overkill. What you get is a very precise endpoint for a titration which is really fairly inaccurate, due to the aforementioned difficulties in the volumetric measurements, temperature, etc.We've had three different pH meters, well-calibrated and maintained, in consistent agreement and differing from phenolphthalein results, and the pH meter results were consistently borne out by the subsequent processing results, whereas phenolphthalein
 were off, this with high-FFA oils where you can really see the difference.The phenolphthalein was obtained from two different lab supply houses and was fresh. We use phenolphthalein for demos and at our seminars because of the pretty pink colour and it's a cheap entry, but we seldom use it otherwise. At our workshops we use pH meters.I use phenolphthalein to determine the endpoint. It is quick, requires no calibration, costs a heck of a lot less than a pH meter, and provides sufficient precision for the measurement at hand.To each his own Bob.Best wishesKeithHi WillemHi all,I am slowly getting the parts together to construct a small biodiesel set-up(approx. 30 litres).When I told a friend recently avout my plans he gave me an electronic PHmeter, pen type. Accuracy is 1
 decimal. He said this would replace thetitration, but could give me no more info.It won't replace titration, you use it for titration. You can use phenolphthalein, or 

Re: [Biofuel] Fw: Electronic PH meter

2005-06-18 Thread Ken Provost
on 6/18/05 1:08 PM, the skapegoat at [EMAIL PROTECTED] wrote:


 As acids become weaker, it is important to become more careful in the
 selection of a chemical indicator (such as PHTH), as the change in pH
 is much slower than it is for a strong acid titration.  PHTH is the most
 commonly used indicator for strong acid titrations because it has such a
 clear color change.  Fortunately it appears to change color over the same
 range as the equivalence pt. for FFAs. The difficulty in either method is
 knowing what the equivalence point is going to be.  This will vary based
 on the type of oil and the degree of hydrogenation.


I'm not sure, but I THINK what you're saying may be the same as my own
observation with phenolphthalein, which is it displays a WIDE RANGE of
pinkness. It doesn't just turn pink -- sometimes it turns pink and
then turns colorless after awhile. Sometimes it's hard to tell if it's
the same shade of pink it was a little earlier. I've always assumed the
difference was small and didn't matter.   -K


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[Biofuel] Fw: Electronic PH meter

2005-06-17 Thread Willem Bravenboer

Hi all,

I am slowly getting the parts together to construct a small biodiesel 
set-up

(approx. 30 litres).
When I told a friend recently avout my plans he gave me an electronic PH
meter, pen type. Accuracy is 1 decimal. He said this would replace the
titration, but could give me no more info.
Can anyone tell me if this is so and how I convert the reading to the amount
of lye to be used?

Best regards,
Willem

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Re: [Biofuel] Fw: Electronic PH meter

2005-06-17 Thread Keith Addison

Hi Willem


Hi all,

I am slowly getting the parts together to construct a small biodiesel set-up
(approx. 30 litres).
When I told a friend recently avout my plans he gave me an electronic PH
meter, pen type. Accuracy is 1 decimal. He said this would replace the
titration, but could give me no more info.


It won't replace titration, you use it for titration. You can use 
phenolphthalein, or pH test strips, or a pH meter - whichever you 
use, titration involves measuring the pH. See:


Basic titration
Better titration
pH meters
Phenolphthalein
http://journeytoforever.org/biodiesel_make2.html#titrate

pH meters are best, IMO. You need to calibrate them often (get 
calibration fluid from a lab supply) and you have to look after them 
properly. There's a Technical tips link at the url above.


Best wishes

Keith



Can anyone tell me if this is so and how I convert the reading to the amount
of lye to be used?

Best regards,
Willem



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