Re: [Biofuel] Fwd: Uses of glycerin

2005-03-01 Thread Keith Addison



1.


This is what I have, but I will look into further for you.

New Waste Stream Specific Information

1. A corn and soybean oil biodiesel manufacturing company produces a 
byproduct, glycerine.  The glycerine is agricultural grade and looks 
similar to thin maple syrup.


2.  Notable Constituents

The notable constituents are BOD 100,000 mg/l, COD 1,760,000 mg/l, 
and passed a solubility test.  All constituents passed the 
established Waste Acceptance Criteria.


So it's a commerial operation, and it sounds like they're separating 
the glycerine from the rest of the by-product and refining it.


2.


Hi Keith,

Here's what I found out.

The actual BOD was closer to one million that is relflect in the COD value.

Is that just the glycerin? The by-product of making biodiesel is a
cocktail of glycerin, soaps (from free fatty acids), excess methanol
(which can be recovered), and the lye catalyst (NaOH or KPH). There
is often more soap than glycerin, does the process handle the soap
too, as well as the high pH?

It's my understanding that the typical process starts with various 
oils and at different concentrations, so they have to shock the 
reaction since they don't know what they are starting with 
necessarily.  This technique of over treating the reaction requires 
more washing the product, which results in more byproduct wastewater 
to manage (lye, methanol, etc.).


The customer we are working with explained that their system is 
fairly unique in the industry because they have chosen to perform 
precision chemistry because they pretreat the oils before 
beginning the process.  By knowing their oils are consistent with 
each batch because of the pretreatment, thus their process is 
considered by them to be more streamlined.  They also generate 
minimal byproduct wastewater to manage, and it's fairly pure in that 
they generally don't produce soap, have minimal catalyst present, 
and minimal generation of methanol.


As for pH, since the chemistry is the anaerobic digester is healthy, 
a high pH wasn't much of a concern.  If your Volatile 
acids:alkalinity ratio is low this acts as a buffer.  Our main 
concern was foaming with the introduction of glycerin, and we did 
see an increase hence the slow feed rate to the digester.


Hope that helps.


Anyone know what this means? I think I do know, somewhere or other, 
but it doesn't come to mind.



The actual BOD was closer to one million that is relflect in the COD value.


Thanks!

Keith




Forwarded message from a Journey to Forever reader.

Best wishes

Keith



Hello,

I work at a wastewater treatment plant and I was doing a search on glycerin
and biofuels and came across your website.  It's has good information
thanks.

Here's another use of glycerin:  Our treatment is accepting the glycerin
from a biofuel producer, we feed it to our digesters, slowly very slowly.
The addition of glycerin has dramatically increased our gas production,
that we run all three engines that produce  electricity for our plant and
occasionally need to flare off the excess methane (we have 4 flares).

This might be of interest to your readers that use digestion for
electricity.


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RE: [Biofuel] Fwd: Uses of glycerin

2005-03-01 Thread Juan Boveda

Hola Francisco.
Methane generating bacteria are sensitive to aerobic conditions and 
generally they do not produce methane in the presence of  oxygen of the air 
but if the fermenter is like a pool deep enough and not agitated, it could 
happen that the bottom is anaerobic and in the surface is thin aerobic 
film.
The feed rate on any fermenter will depend on many variables like size of 
the fermenter, temperature, pH, type of bacterial species, design and 
management of the fermenter (plug flow, well mixed and power used per unit 
of volume, re-use or not of bacterial mass, back flow of sediment if any or 
liquids), physical state and chemical structure of the material to feed the 
fementer, solubility, size of the material, carbon to nitrogen and 
phosphorus ratio, etc, etc.
Regards.

Juan

-Mensaje original-
De: francisco j burgos [SMTP:[EMAIL PROTECTED]
Enviado el: Domingo 27 de Febrero de 2005 9:34 PM
Para:   [EMAIL PROTECTED]; [EMAIL PROTECTED]
Asunto: Re: [Biofuel] Fwd: Uses of glycerin

Dear pals:
the digester where glycerin is feed is it an aerobious(works in presence of 
air) digester or an anaerobious(works without air presence) digester?.
What is the glycerin feed rate to the digester?.
Thanks in advance,
Francisco
- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, February 27, 2005 6:02 PM
Subject: [Biofuel] Fwd: Uses of glycerin


 Forwarded message from a Journey to Forever reader.

 Best wishes

 Keith


Hello,

I work at a wastewater treatment plant and I was doing a search on
glycerin
and biofuels and came across your website.  It's has good information
thanks.

Here's another use of glycerin:  Our treatment is accepting the glycerin
from a biofuel producer, we feed it to our digesters, slowly very slowly.
The addition of glycerin has dramatically increased our gas production,
that we run all three engines that produce  electricity for our plant and
occasionally need to flare off the excess methane (we have 4 flares).

This might be of interest to your readers that use digestion for
electricity.


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Re: [Biofuel] Fwd: Uses of glycerin

2005-02-28 Thread francisco j burgos


the digester where glycerin is feed is it an aerobious(works in presence of 
air) digester or an anaerobious(works without air presence) digester?.

What is the glycerin feed rate to the digester?.
Thanks in advance,
Francisco
- Original Message - 
From: Keith Addison [EMAIL PROTECTED]

To: [EMAIL PROTECTED]
Sent: Sunday, February 27, 2005 6:02 PM
Subject: [Biofuel] Fwd: Uses of glycerin



Forwarded message from a Journey to Forever reader.

Best wishes

Keith



Hello,

I work at a wastewater treatment plant and I was doing a search on 
glycerin

and biofuels and came across your website.  It's has good information
thanks.

Here's another use of glycerin:  Our treatment is accepting the glycerin
from a biofuel producer, we feed it to our digesters, slowly very slowly.
The addition of glycerin has dramatically increased our gas production,
that we run all three engines that produce  electricity for our plant and
occasionally need to flare off the excess methane (we have 4 flares).

This might be of interest to your readers that use digestion for
electricity.


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Biofuel archives at Infoarchive.net (searchable):
http://infoarchive.net/sgroup/biofuel/








Re: [Biofuel] Fwd: Uses of glycerin

2005-02-28 Thread Phillip Wolfe


Pan wrote The addition of glycerin has dramatically
increased our gas  production, that we run all three
engines that produce  electricity for our plant and
occasionally need to flare off the excess methane (we
have 4 flares(end quote)

Pan - Can you lead me to some weblinks for the
technical briefs as to why glycerin has
dramatically increased (y)our gas  production...

I will also search the JTF website.

Phillip Wolfe




--- francisco j burgos [EMAIL PROTECTED] wrote:

 Dear pals:
 the digester where glycerin is feed is it an
 aerobious(works in presence of 
 air) digester or an anaerobious(works without air
 presence) digester?.
 What is the glycerin feed rate to the digester?.
 Thanks in advance,
 Francisco
 - Original Message - 
 From: Keith Addison [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Sunday, February 27, 2005 6:02 PM
 Subject: [Biofuel] Fwd: Uses of glycerin
 
 
  Forwarded message from a Journey to Forever
 reader.
 
  Best wishes
 
  Keith
 
 
 Hello,
 
 I work at a wastewater treatment plant and I was
 doing a search on 
 glycerin
 and biofuels and came across your website.  It's
 has good information
 thanks.
 
 Here's another use of glycerin:  Our treatment is
 accepting the glycerin
 from a biofuel producer, we feed it to our
 digesters, slowly very slowly.
 The addition of glycerin has dramatically
 increased our gas production,
 that we run all three engines that produce 
 electricity for our plant and
 occasionally need to flare off the excess methane
 (we have 4 flares).
 
 This might be of interest to your readers that use
 digestion for
 electricity.
 
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  http://journeytoforever.org/biofuel.html
 
  Biofuel archives at Infoarchive.net (searchable):
  http://infoarchive.net/sgroup/biofuel/
 
  
 
 
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 http://infoarchive.net/sgroup/biofuel/
 




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Re: [Biofuel] Fwd: Uses of glycerin

2005-02-28 Thread Keith Addison



increased our gas  production, that we run all three
engines that produce  electricity for our plant and
occasionally need to flare off the excess methane (we
have 4 flares(end quote)

Pan - Can you lead me to some weblinks for the
technical briefs as to why glycerin has
dramatically increased (y)our gas  production...

I will also search the JTF website.

Phillip Wolfe


No, Phillip, Pan didn't write that, I posted it as a forward, it was 
feedback sent to me by a visitor to the Journey to Forever website:



  Forwarded message from a Journey to Forever
 reader.


You should re-read the whole thread I think.

http://wwia.org/pipermail/biofuel/Week-of-Mon-20050221/006366.html
http://wwia.org/pipermail/biofuel/Week-of-Mon-20050228/thread.html#6368

There is more information about glycerin and biogas in the list 
archives though:


http://infoarchive.net/sgroup/biofuel/
Information Archive at NNYTech

Best wishes

Keith




--- francisco j burgos [EMAIL PROTECTED] wrote:

 Dear pals:
 the digester where glycerin is feed is it an
 aerobious(works in presence of
 air) digester or an anaerobious(works without air
 presence) digester?.
 What is the glycerin feed rate to the digester?.
 Thanks in advance,
 Francisco
 - Original Message -
 From: Keith Addison [EMAIL PROTECTED]
 To: [EMAIL PROTECTED]
 Sent: Sunday, February 27, 2005 6:02 PM
 Subject: [Biofuel] Fwd: Uses of glycerin


  Forwarded message from a Journey to Forever
 reader.
 
  Best wishes
 
  Keith
 
 
 Hello,
 
 I work at a wastewater treatment plant and I was
 doing a search on
 glycerin
 and biofuels and came across your website.  It's
 has good information
 thanks.
 
 Here's another use of glycerin:  Our treatment is
 accepting the glycerin
 from a biofuel producer, we feed it to our
 digesters, slowly very slowly.
 The addition of glycerin has dramatically
 increased our gas production,
 that we run all three engines that produce
 electricity for our plant and
 occasionally need to flare off the excess methane
 (we have 4 flares).
 
 This might be of interest to your readers that use
 digestion for
 electricity.


___
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[EMAIL PROTECTED]
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Biofuel archives at Infoarchive.net (searchable):
http://infoarchive.net/sgroup/biofuel/



[Biofuel] Fwd: Uses of glycerin

2005-02-27 Thread Keith Addison



Best wishes

Keith



Hello,

I work at a wastewater treatment plant and I was doing a search on glycerin
and biofuels and came across your website.  It's has good information
thanks.

Here's another use of glycerin:  Our treatment is accepting the glycerin
from a biofuel producer, we feed it to our digesters, slowly very slowly.
The addition of glycerin has dramatically increased our gas production,
that we run all three engines that produce  electricity for our plant and
occasionally need to flare off the excess methane (we have 4 flares).

This might be of interest to your readers that use digestion for
electricity.


___
Biofuel mailing list
[EMAIL PROTECTED]
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Biofuel at Journey to Forever:
http://journeytoforever.org/biofuel.html

Biofuel archives at Infoarchive.net (searchable):
http://infoarchive.net/sgroup/biofuel/