Re: [Biofuel] Washing Biodiesel

2005-06-02 Thread Manick Harris
Hi Terry,
Looks like the reaction2RCOONa + Ca (Acetate)2-- (RCOO)2Ca + 2Na(Acetate) to me.(soluble soap)+ (hard water)--(insol. scum)+ (soluble salt)
Bill has achieved a way of removing fatty acids dissolved in biodiesel. Congrats to Bill. Sabash! Terry DeSimone [EMAIL PROTECTED] wrote:

Hello Bill, 
 Thought I'd read about everything there was on biodiesel,but don't recall anything on water hardness. Could you direct me to a link or post so I can learn more about this? By "hardness" I'm assuming you mean calcium? 
 TerryBill Clark [EMAIL PROTECTED] wrote:
Sorry for the unrelated text at the bottom of my last e-mail regardingAcusorb beads. Meant to cut that.I have been experiencing wash problems (bubble wash using Simon's superbubbler), specifically failures in the wash test. At first I suspectedtitration problems as well as process problems. Then I saw the message inthe archives regarding soft water. The municipal water supply in the City ofEufaula is very soft (near 0 grains of hardness). It also has a pH of 8.5.Treating the wash water with vinegar resulted in some reduction of emulsionformation but not complete elimination of the problem.After consulting the City's water works, I began using a water hardnessincreaser made for use in swimming pools. The results were dramatic;complete elimination of emulsions. I now use .5 oz. of hardness increaser in50 gallons of wash water (200
 gal. biodiesel) along with 1 cup of vinegar.This increases hardness by 60 ppm. The manufacturer of the hardnessincreaser informed me that I may see some scale formation with the additionof vinegar but I will cross that bridge when I reach it.As I stated in my previous post, I use Acusorb beads as the final step in mywashing process. It does a fine job of drying and buffering the biodiesel. Inow use 1 wash before filtering the biodiesel through the beads. A shaketest of the final product using distilled water results in very fastseparation with clear biodiesel on top and pH nuetral water on the bottom.I am neither recommending nor condemning the use of Acusorb beads. I havefound a way to make them useful to me. My use of the beads is more a matterof speed of process. If time were not a factor, the cost of the beads mightprohibit my use of them.If there are factors I have neglected please let me know. Even though I
 havegood results in my final shake test, my obsessive-compulsive nature keeps mefrom feeling cofident about anything.Good biodieseling to everyone.Bill Clark___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the full Biofuel list archives (46,000 messages):http://infoarchive.net/sgroup/biofuel/Search the Biofuels-biz list archives:http://infoarchive.net/sgroup/biofuels-biz/___Biofuel mailing listBiofuel@sustainablelists.orghttp://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.orgBiofuel at Journey to Forever:http://journeytoforever.org/biofuel.htmlSearch the full Biofuel list archives
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Re: [Biofuel] Washing Biodiesel

2005-06-02 Thread ings . group

Bill:

The folks in your town should be thankful.  After their shower they
still have a thin layer of natural (and yet clean) oils on their skin.
Others, like me, need to soften our water to accomplish that or live
with dry cracking skin, especially in the winter.


Ray

On Wed, 01 Jun 2005 17:11:25 -0400, Bill Clark [EMAIL PROTECTED]  
wrote:



Hi Terry,

Here is one from the archives: Message #45295. There is a post from  
Keith that
refers to problems with soft water, nothing detailed, but I can't seem  
to find

it right now.

Soft water problems make sense to me. People who don't live here often  
complain
that they can't get the soap off in the shower. Your pretty slick when  
you step
out of the shower here. When washing clothes we only use half the  
recommended

rate of detergent.

I should have been more detailed about my conversation with the water  
works
people. They gave me a target of 60-80 ppm of hardness. This will  
provide enough

hardness without affecting the ability of the water to dissolve soaps.

Best wishes,

Bill Clark

- Original Message -

From: Terry DeSimone

To: Biofuel@sustainablelists.org

Sent: Wednesday, June 01, 2005 2:27 PM

Subject: Re: [Biofuel] Washing Biodiesel


Hello Bill,

Thought I'd read about everything there was on biodiesel,but don't recall
anything on water hardness. Could you direct me to a link or post so I  
can learn

more about this? By hardness I'm assuming you mean calcium?

Terry

Bill Clark [EMAIL PROTECTED] wrote:

Sorry for the unrelated text at the bottom of my last e-mail regarding
Acusorb beads. Meant to cut that.

I have been experiencing wash problems (bubble wash using Simon's super
bubbler), specifically failures in the wash test. At first I suspected
titration problems as well as process problems. Then I saw the message in
the archives regarding soft water. The municipal water supply in the  
City of
Eufaula is very soft (near 0 grains of hardness). It also has a pH of  
8.5.
Treating the wash water with vinegar resulted in some reduction of  
emulsion

formation but not complete elimination of the problem.

After consulting the City's water works, I began using a water hardness
increaser made for use in swimming pools. The results were dramatic;
complete elimination of emulsions. I now use .5 oz. of hardness  
increaser in
50 gallons of wash wa! ter (200 gal. biodiesel) along with 1 cup of  
vinegar.

This increases hardness by 60 ppm. The manufacturer of the hardness
increaser informed me that I may see some scale formation with the  
addition

of vinegar but I will cross that bridge when I reach it.

As I stated in my previous post, I use Acusorb beads as the final step  
in my
washing process. It does a fine job of drying and buffering the  
biodiesel. I

now use 1 wash before filtering the biodiesel through the beads. A shake
test of the final product using distilled water results in very fast
separation with clear biodiesel on top and pH nuetral water on the  
bottom.


I am neither recommending nor condemning the use of Acusorb beads. I have
found a way to make them useful to me. My use of the beads is more a  
matter
of speed of process. If time were not a factor, the cost of the beads  
might

prohibit my use of them.

If there are factors I have neglected please let me know. Even though! I  
have
good results in my final shake test, my obsessive-compulsive nature  
keeps me

from feeling cofident about anything.

Good biodieseling to everyone.

Bill Clark


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Re: [Biofuel] Washing Biodiesel

2005-06-02 Thread Bill Clark
Hi Ray,

We are thankful for the quality and plentifulness of our water supply. The
people I was referring to are visitors or newcomers. Established citizens
are well aware of the benefits of soft water on skin.

Thanks,

Bill Clark
- Original Message - 
From: [EMAIL PROTECTED]
To: Biofuel@sustainablelists.org
Sent: Thursday, June 02, 2005 12:04 PM
Subject: Re: [Biofuel] Washing Biodiesel


 Bill:

 The folks in your town should be thankful.  After their shower they
 still have a thin layer of natural (and yet clean) oils on their skin.
 Others, like me, need to soften our water to accomplish that or live
 with dry cracking skin, especially in the winter.


 Ray

 On Wed, 01 Jun 2005 17:11:25 -0400, Bill Clark [EMAIL PROTECTED]
 wrote:

  Hi Terry,
 
  Here is one from the archives: Message #45295. There is a post from
  Keith that
  refers to problems with soft water, nothing detailed, but I can't seem
  to find
  it right now.
 
  Soft water problems make sense to me. People who don't live here often
  complain
  that they can't get the soap off in the shower. Your pretty slick when
  you step
  out of the shower here. When washing clothes we only use half the
  recommended
  rate of detergent.
 
  I should have been more detailed about my conversation with the water
  works
  people. They gave me a target of 60-80 ppm of hardness. This will
  provide enough
  hardness without affecting the ability of the water to dissolve soaps.
 
  Best wishes,
 
  Bill Clark
 
  - Original Message -
 
  From: Terry DeSimone
 
  To: Biofuel@sustainablelists.org
 
  Sent: Wednesday, June 01, 2005 2:27 PM
 
  Subject: Re: [Biofuel] Washing Biodiesel
 
 
  Hello Bill,
 
  Thought I'd read about everything there was on biodiesel,but don't
recall
  anything on water hardness. Could you direct me to a link or post so I
  can learn
  more about this? By hardness I'm assuming you mean calcium?
 
  Terry
 
  Bill Clark [EMAIL PROTECTED] wrote:
 
  Sorry for the unrelated text at the bottom of my last e-mail regarding
  Acusorb beads. Meant to cut that.
 
  I have been experiencing wash problems (bubble wash using Simon's super
  bubbler), specifically failures in the wash test. At first I suspected
  titration problems as well as process problems. Then I saw the message
in
  the archives regarding soft water. The municipal water supply in the
  City of
  Eufaula is very soft (near 0 grains of hardness). It also has a pH of
  8.5.
  Treating the wash water with vinegar resulted in some reduction of
  emulsion
  formation but not complete elimination of the problem.
 
  After consulting the City's water works, I began using a water hardness
  increaser made for use in swimming pools. The results were dramatic;
  complete elimination of emulsions. I now use .5 oz. of hardness
  increaser in
  50 gallons of wash wa! ter (200 gal. biodiesel) along with 1 cup of
  vinegar.
  This increases hardness by 60 ppm. The manufacturer of the hardness
  increaser informed me that I may see some scale formation with the
  addition
  of vinegar but I will cross that bridge when I reach it.
 
  As I stated in my previous post, I use Acusorb beads as the final step
  in my
  washing process. It does a fine job of drying and buffering the
  biodiesel. I
  now use 1 wash before filtering the biodiesel through the beads. A shake
  test of the final product using distilled water results in very fast
  separation with clear biodiesel on top and pH nuetral water on the
  bottom.
 
  I am neither recommending nor condemning the use of Acusorb beads. I
have
  found a way to make them useful to me. My use of the beads is more a
  matter
  of speed of process. If time were not a factor, the cost of the beads
  might
  prohibit my use of them.
 
  If there are factors I have neglected please let me know. Even though! I
  have
  good results in my final shake test, my obsessive-compulsive nature
  keeps me
  from feeling cofident about anything.
 
  Good biodieseling to everyone.
 
  Bill Clark
 
 
  ___
  Biofuel mailing list
  Biofuel@sustainablelists.org
 
http://sustainablelists.org/mailman/listinfo/biofuel_sustainablelists.org
 
  Biofuel at Journey to Forever:
  http://journeytoforever.org/biofuel.html
 
  Search the full Biofuel list archives (46,000 messages):
  http://infoarchive.net/sgroup/biofuel/
 
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  http://infoarchive.net/sgroup/biofuels-biz/
 
 
 
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  http://journeytoforever.org/biofuel.html
 
  Search the full Biofuel list archives (46,000 messages):
  http://infoarchive.net/sgroup/biofuel/
 
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RE: [biofuel] washing biodiesel in large processor

2004-07-12 Thread Dermot

Hi Todd,

This mixing method you describe looks much easier than bubble washing or
mist washing.
What I intend to do is to use the pump from my reactor vessel to mix the
biodiesel and water. Presumably this is ok?

You emphasise that it is important that the reaction be fully complete.
From what I have been reading on Journeytoforever it seems that the best way
to ensure that is to use the correct amount of lye, i.e. 3.5 or 4 grams plus
titration plus plenty of excess methanol.

I intend doing my first large batch soon (50 litres). It titrates at 2.4 so
I am going to use say 6.4 grams/litre of lye plus 25% methanol to ensure a
complete reaction.

I have read the journeytoforever advice on the different amounts of methanol
to use for different oils but as I am going to recover the methanol I don't
think it matters if I use too much.  I presume most of the excess methanol
will end up in the glycerine and not the biodiesel.

I would appreciate your advice on this. Is there anything radically wrong
with what I have proposed above?

Regards,
Dermot

-Original Message-
From: Appal Energy [mailto:[EMAIL PROTECTED]
Sent: 09 July 2004 00:36
To: biofuel@yahoogroups.com
Subject: Re: [biofuel] washing biodiesel in large processor

Ardis,

You will find, after enough experimentation and out of pocket costs, that
mechanical agitation in a wash tank is the least expensive, consumes the
least energy, requires the least amount of time and leaves you with a
finished product as good as or better than mist- or bubble-washing.

Plain, pure and simple, mist- and bubble-washing have become
institutionalized amongst home-brewers primarily due to the frequency of
incomplete reactions that lend to washing problems. In short, they are both
methods of treating incomplete reactions with little kid's gloves in the
hopes that any resulting emulsion won't be too bad or too noticeable.

The fact of the matter is that no wash method should be used on any batch
unless it is known for certain that the reaction has completed.
Unfortunately, many people fail to guarantee this for themselves, opting to
just go ahead and wash it gently.

The method of guarantee is extremely simple. Put one ounce of what is
believed to be finished fuel in a baby food jar (or similar) with an equal
amount of water. Seal the jar and shake violently for 15 seconds. Completed
fuel should begin to separate instantly and there should be two distinct
layers in less than ~30 seconds. If it takes longer than this or if an
emulsion layer forms any thicker than the normal paper thin interface
layer between oil and water, you've got a batch that has not completed.

The degree of incompletion can vary. If the fuel/water separate slowly but
are by-and-large complete in a matter of 1-2 minutes and there is no
emulsion layer other than the interface, there's no great need to retreat
the reaction if the fuel is intended for personal use. If you have an
emulsion beyond the thin interface layer the batch needs to be retreated. No
amount of light mist- or bubble-washing can change this - unless, of course,
you don't care what grade of fuel you run through your engine.

The wash test and mechanical washing (motor, prop and shaft) work well no
matter what method you use - acid/base or straight base, single or double
stage.

Some concern has been expressed in the past over the use of air to dry fuel,
the concern being fuel oxidation. It's beyond me why those who express such
concern (and rightfully so) don't say word one about bubble washing doing
the exact same thing.

Others express concern with pump- or prop-washed fuel not clearing as
quickly as mist- or bubble-washed. There's sound reason for this, all things
being equal. Pumps and propellers have the ability of better mixing the fuel
and water (atomizing it), bringing both in more frequent contact with each
other. This means greater surface to surface contact between water molecules
and all suspended/dissolved impurities. Fifteen minutes with a 1/2 hp motor
and 4 - 6 prop in a 200 gallon wash tank or bigger will achieve the same
thing or more as an all-day-affair with a mist- or bubble-washer. This
allows for hours of washing time to be converted to settling time, in turn
hastening the entire wash process.

Anyway, when all is said and done and no matter what wash method you choose,
you'll best serve your own interests if you make sure that your reaction is
complete before attempting any type of wash. All bubble- and mist-washing
tend to do is offer brewers the opportunity to wash an incompletely reacted
batch with one eye closed and sometimes the other eye squinted.

Todd Swearingen

- Original Message -
From: ardis streeter [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Cc: [EMAIL PROTECTED]
Sent: Wednesday, July 07, 2004 7:29 PM
Subject: [biofuel] washing biodiesel in large processor


 Hi,all '  I was wondering if anyone could tell me
 which way might be best for washing large batches of
 biodiesel??My

Re: [biofuel] washing biodiesel in large processor

2004-07-10 Thread Keith Addison
 PROTECTED]
Sent: Wednesday, July 07, 2004 7:29 PM
Subject: [biofuel] washing biodiesel in large processor


  Hi,all '  I was wondering if anyone could tell me
  which way might be best for washing large batches of
  biodiesel??My processor is capable of processing up to
  200 gallons at a time.I am still building the
  processor so I was looking for some imfo.from
  experenced biodiesel producers.So far  I have the
  stainless pick up tank done,the methanol,lye mix tank
  done,the processing tank with heat exchangers and
  mixer done.Currently I am building the wash tank and
  was wondering if bubble washing or top mist washing
  would be better for a tank that is 46 inches in dia.
  and aprox. 90 inches high.The tank will hold aprox.
  480 gallons.Also was wondering if the tank needs an
  agitoror or if the wash tank should be set up with a
  pump to stir the fuel,water wash?? Also would like to
  know if the wash water should be pre-heated because
  well water is around 55 degrees,would this cause a
  problem with proper washing.Thanks for any help||



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Re: [biofuel] washing biodiesel in large processor

2004-07-09 Thread Appal Energy

Ardis,

You will find, after enough experimentation and out of pocket costs, that
mechanical agitation in a wash tank is the least expensive, consumes the
least energy, requires the least amount of time and leaves you with a
finished product as good as or better than mist- or bubble-washing.

Plain, pure and simple, mist- and bubble-washing have become
institutionalized amongst home-brewers primarily due to the frequency of
incomplete reactions that lend to washing problems. In short, they are both
methods of treating incomplete reactions with little kid's gloves in the
hopes that any resulting emulsion won't be too bad or too noticeable.

The fact of the matter is that no wash method should be used on any batch
unless it is known for certain that the reaction has completed.
Unfortunately, many people fail to guarantee this for themselves, opting to
just go ahead and wash it gently.

The method of guarantee is extremely simple. Put one ounce of what is
believed to be finished fuel in a baby food jar (or similar) with an equal
amount of water. Seal the jar and shake violently for 15 seconds. Completed
fuel should begin to separate instantly and there should be two distinct
layers in less than ~30 seconds. If it takes longer than this or if an
emulsion layer forms any thicker than the normal paper thin interface
layer between oil and water, you've got a batch that has not completed.

The degree of incompletion can vary. If the fuel/water separate slowly but
are by-and-large complete in a matter of 1-2 minutes and there is no
emulsion layer other than the interface, there's no great need to retreat
the reaction if the fuel is intended for personal use. If you have an
emulsion beyond the thin interface layer the batch needs to be retreated. No
amount of light mist- or bubble-washing can change this - unless, of course,
you don't care what grade of fuel you run through your engine.

The wash test and mechanical washing (motor, prop and shaft) work well no
matter what method you use - acid/base or straight base, single or double
stage.

Some concern has been expressed in the past over the use of air to dry fuel,
the concern being fuel oxidation. It's beyond me why those who express such
concern (and rightfully so) don't say word one about bubble washing doing
the exact same thing.

Others express concern with pump- or prop-washed fuel not clearing as
quickly as mist- or bubble-washed. There's sound reason for this, all things
being equal. Pumps and propellers have the ability of better mixing the fuel
and water (atomizing it), bringing both in more frequent contact with each
other. This means greater surface to surface contact between water molecules
and all suspended/dissolved impurities. Fifteen minutes with a 1/2 hp motor
and 4 - 6 prop in a 200 gallon wash tank or bigger will achieve the same
thing or more as an all-day-affair with a mist- or bubble-washer. This
allows for hours of washing time to be converted to settling time, in turn
hastening the entire wash process.

Anyway, when all is said and done and no matter what wash method you choose,
you'll best serve your own interests if you make sure that your reaction is
complete before attempting any type of wash. All bubble- and mist-washing
tend to do is offer brewers the opportunity to wash an incompletely reacted
batch with one eye closed and sometimes the other eye squinted.

Todd Swearingen

- Original Message - 
From: ardis streeter [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Cc: [EMAIL PROTECTED]
Sent: Wednesday, July 07, 2004 7:29 PM
Subject: [biofuel] washing biodiesel in large processor


 Hi,all '  I was wondering if anyone could tell me
 which way might be best for washing large batches of
 biodiesel??My processor is capable of processing up to
 200 gallons at a time.I am still building the
 processor so I was looking for some imfo.from
 experenced biodiesel producers.So far  I have the
 stainless pick up tank done,the methanol,lye mix tank
 done,the processing tank with heat exchangers and
 mixer done.Currently I am building the wash tank and
 was wondering if bubble washing or top mist washing
 would be better for a tank that is 46 inches in dia.
 and aprox. 90 inches high.The tank will hold aprox.
 480 gallons.Also was wondering if the tank needs an
 agitoror or if the wash tank should be set up with a
 pump to stir the fuel,water wash?? Also would like to
 know if the wash water should be pre-heated because
 well water is around 55 degrees,would this cause a
 problem with proper washing.Thanks for any help||




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[biofuel] washing biodiesel in large processor

2004-07-08 Thread ardis streeter

Hi,all '  I was wondering if anyone could tell me
which way might be best for washing large batches of
biodiesel??My processor is capable of processing up to
200 gallons at a time.I am still building the
processor so I was looking for some imfo.from
experenced biodiesel producers.So far  I have the
stainless pick up tank done,the methanol,lye mix tank
done,the processing tank with heat exchangers and
mixer done.Currently I am building the wash tank and
was wondering if bubble washing or top mist washing
would be better for a tank that is 46 inches in dia.
and aprox. 90 inches high.The tank will hold aprox.
480 gallons.Also was wondering if the tank needs an
agitoror or if the wash tank should be set up with a
pump to stir the fuel,water wash?? Also would like to
know if the wash water should be pre-heated because
well water is around 55 degrees,would this cause a
problem with proper washing.Thanks for any help||  




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[biofuel] Washing Biodiesel Turnaround Time?

2004-04-12 Thread Kevin Shea

I have Josh Tickell's book From the fryer to the fuel tank and it explains 
that washing the biodiesel adds several days to the process.

What is several days?

Is two days enough? three?

Perhaps other variables delay the washing, but what is a good rule-of-thumb 
from our groups members?


Thank you, 
Kevin Shea


[Non-text portions of this message have been removed]




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[biofuel] Washing biodiesel

2004-02-05 Thread j_schearer

x-charset ISO-8859-1I am a newcomer to the discussion board, so please bear 
with me.  Is 
washing the biodiesel a necessary step?  Reading Joshua Tickell's 
book, he claims that he does not wash the biodiesel and has not had 
any problems running it.  Then when I looked at the Journey to 
Forever website, there is a lot of emphasis on washing it.  Which 
would be the best way?  Thanks. Jonathan.   




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RE: [biofuel] Washing biodiesel

2004-02-05 Thread Bohdan Ilich

check the pH. if its not washed any aluminium parts of the engine will
corrode.

-Original Message-
From: j_schearer [mailto:[EMAIL PROTECTED]
Sent: Thursday, 5 February 2004 2:42 AM
To: biofuel@yahoogroups.com
Subject: [biofuel] Washing biodiesel


I am a newcomer to the discussion board, so please bear with me.  Is 
washing the biodiesel a necessary step?  Reading Joshua Tickell's 
book, he claims that he does not wash the biodiesel and has not had 
any problems running it.  Then when I looked at the Journey to 
Forever website, there is a lot of emphasis on washing it.  Which 
would be the best way?  Thanks. Jonathan.   




Biofuel at Journey to Forever:
http://journeytoforever.org/biofuel.html
http://journeytoforever.org/biofuel.html 

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Re: [biofuel] Washing biodiesel

2004-02-05 Thread Appal Energy

x-charset ISO-8859-1Jonathan,

To wash or not to wash? Take your pick. It's your poison.

Todd Swearingen

- Original Message - 
From: j_schearer [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Sent: Wednesday, February 04, 2004 11:41 AM
Subject: [biofuel] Washing biodiesel


 I am a newcomer to the discussion board, so please bear with me.  Is 
 washing the biodiesel a necessary step?  Reading Joshua Tickell's 
 book, he claims that he does not wash the biodiesel and has not had 
 any problems running it.  Then when I looked at the Journey to 
 Forever website, there is a lot of emphasis on washing it.  Which 
 would be the best way?  Thanks. Jonathan.   
 
 
 
 
 Biofuel at Journey to Forever:
 http://journeytoforever.org/biofuel.html
 
 Biofuels list archives:
 http://archive.nnytech.net/index.php?list=biofuel
 
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Re: [biofuel] Washing biodiesel

2004-02-05 Thread Keith Addison

Hello Jonathan, welcome

I am a newcomer to the discussion board, so please bear with
me. Is washing the biodiesel a necessary step? Reading
Joshua Tickell's book, he claims that he does not wash the
biodiesel and has not had any problems running it. Then when
I looked at the Journey to Forever website, there is a lot
of emphasis on washing it. Which would be the best way?
Thanks. Jonathan.

This was posted to one of the local forums:

 2 Nov 2003 05:34:47 -0800 (PST)
 
 come on , you guys- not only is Tickell's book almost
 entirely inaccurate for homebrew (and I believe for
 other non-DIY info as well), but someone just blew
 themselves up following the sort of practices it
 advocates (or burned his shed down in an explosion and
 got burned in the process using the sort of equipment
 recommended in the book) .  Plus Tickell has been told
 for years that a bunch of his info is incorrect but
 has kept putting out editions of the book that
 `change... nothing... except for the cover photo.
 
 It might be OK as a book to give to your mystified
 grandma to explain why you're so obsessed and to argue
 how biodiesel might be ecologically friendly, but it's
 absolutely not OK to recommend it as a way to learn
 how to make the stuff. everything in the DIY homebrew
 side of it is just about all wrong, outdated, or
 dangerous, and instead, the best source for
 information about how to make biodiesel is online:
 
 http://www.journeytoforever.orghttp://www.journeytoforever.org
 http://biodiesel.infopop.cchttp://biodiesel.infopop.cc
 
 Mark

Mark (Girl Mark) is a hardened biodieseler, teacher, advocate, 
campaigner. It's a bit fierce maybe, but I don't disagree. She says a 
lot more about that book here:
http://infoarchive.net/sgroup/BIOFUEL/29919/

I don't disagree with that either.

Here's more:

I have to say something doesn't sit right with his letter or organization
(or, as many people have pointed out, his publication of unsafe biodiesel
processor plans in a widely distributed book. Ah well. Judge for yourself.

-Aaron

There's lots more. Don't take any notice of that book, it'll only 
lead you astray. Follow the washing information at Journey to Forever.
http://journeytoforever.org/biodiesel_bubblewash.html
Bubble washing: Journey to Forever

Best

Keith





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Re: [biofuel] Washing Biodiesel.

2001-08-14 Thread Paul Gobert

I have solved the wash problems that plagued my BD production.
Previous attempts at washing using the bubble wash technique proved
disasterous with froth  and emulsion formation. Usually half the BD ended up
overflowing the container.
Tried using a gentler wash setup on small scale allowing water droplets to
fall through the BD. This was more successful , but there was still a
problem with the water/oil globules persisting and slowing the process.
First wash with 10% vinegar helped but the flow rate had to be watched.
Decided that if I was going to use vinegar the cheapest way would be to
prepare it from glacial acetic acid (conc acetic acid). Vinegar is 10%
acetic acid. Acetic acid and BD mix well so I mixed the glacial acetic acid
into the BD prior to washing. The result was better than I could have hoped
for. No froth or emulsion, wash rate up to maximum flow.
Retried bubble wash technique with equally successful results. Have droped
level of glacial added from initial 8mls/l of BD (equivalent to ammount used
in 10% vinegar wash) to 4ml and then 2ml. Results still great, anticipate
level could be dropped even further, will investigate.
Don't know the  theory behind it. Thought the vinegar wash was neutralising
residual NaOH in BD but all my recent batches have tested pH 6 and titrated
ever so slightly acid prior to washing.
Have added about 15L of washed , dried and filtered BD to tank of Toyota so
far with no problems.
More to come.
Regards Paul.


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Re: [biofuel] Washing Biodiesel.

2001-08-14 Thread Keith Addison

Hi Paul

Good news, very interesting.

I have solved the wash problems that plagued my BD production.
Previous attempts at washing using the bubble wash technique proved
disasterous with froth  and emulsion formation. Usually half the BD ended up
overflowing the container.
Tried using a gentler wash setup on small scale allowing water droplets to
fall through the BD. This was more successful , but there was still a
problem with the water/oil globules persisting and slowing the process.
First wash with 10% vinegar helped but the flow rate had to be watched.
Decided that if I was going to use vinegar the cheapest way would be to
prepare it from glacial acetic acid (conc acetic acid). Vinegar is 10%
acetic acid. Acetic acid and BD mix well so I mixed the glacial acetic acid
into the BD prior to washing. The result was better than I could have hoped
for. No froth or emulsion, wash rate up to maximum flow.
Retried bubble wash technique with equally successful results. Have droped
level of glacial added from initial 8mls/l of BD (equivalent to ammount used
in 10% vinegar wash) to 4ml and then 2ml. Results still great, anticipate
level could be dropped even further, will investigate.
Don't know the  theory behind it. Thought the vinegar wash was neutralising
residual NaOH in BD but all my recent batches have tested pH 6 and titrated
ever so slightly acid prior to washing.
Have added about 15L of washed , dried and filtered BD to tank of Toyota so
far with no problems.
More to come.

Yes please. Paul, you're using Aleks's two-stage acid-base process, aren't you?

Regards Paul.


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