What does anomalous difference Fourier look like?

-----Original Message-----
From: CCP4 bulletin board [mailto:[email protected]] On Behalf Of Annemarie 
Weber
Sent: Monday, February 03, 2014 11:37 AM
To: [email protected]
Subject: [ccp4bb] unexplained density

Dear all,
I am refining a 1.4 A resolution structure and found some well-defined 
but unfortunately unexplained density. The protein was purified in HEPES 
buffer with PMSF and protease inhibitor cocktail tablets (Roche) added. 
It was cocrystallized with AMPPNP in PEG2000MME and Tris. I modelled a 
molecule into the density, which fits quite well but I do not know what 
it is and how it got there. Attached are two pictures with the 
difference density and the molecule I modelled in there.
Has anybody seen something like this before? Maybe some degradation 
product of the buffer/PMSF?
Any suggestions will be highly welcome.
Thanks a lot
Annemarie
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