Dear Purity

Following on from Gerard's response, your question is in two parts:

1. How can you improve my R values where there is anisotropy ?

If you haven't done so already I would suggest that you try submitting the
data to the STARANISO server
https://staraniso.globalphasing.org/cgi-bin/staraniso.cgi
(carefully following the recommendations and instructions on the website).
Then repeat the refinement and map calculation - though there are no
guarantees that it will improve your R values (but it may well improve the
interpretability of your maps).

2. What is the cause of diffraction anisotropy ?

I think the answer to this question is well established: the crystal
diffraction limit is dependent on the number and strength of intermolecular
contacts (typically H-bonds and salt bridges, but could also be covalent
bonding such as S-S bridges and cross-links).  Fewer and/or weaker contacts
allows a greater degree of thermal motion and/or static disorder either
generally (isotropic case) or in specific directions (anisotropic case)
which manifests in correspondingly faster fall-off of the intensities in
all or just those specific directions.

Hope this helps!

-- Ian (Global Phasing)


On Wed, 21 Jan 2026 at 17:58, Ezennubia, Purity <
[email protected]> wrote:

> Hello everyone,
>
> It's becoming almost a regular norm for my crystals to be anisotropic when
> I look at the diffraction data. Its really unideal for me because when the
> data is anisotropic my R-work and R-free values are usually high when
> compared to some lucky data I got that was not anisotropic.
>
> I would like to hear from other people in this forum what causes a crystal
> to diffract anisotropically going to different resolution in the hkl axis.
>
> Thank you,
> Purity
>
> *Kelechi Purity Ezennubia*
> *Graduate research assistant *
> *Department of Chemistry & Biochemistry *
> *Baylor University *
> *Clinger lab C161R*
> *[email protected] <[email protected]>*
>
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