We need auxiliary information for sigma(k) to make the definition generic.   

Something like this ... check my math and whther it's < or <=

If k numbers from top to bottom then (left side of diagram attached)
for   1 < k <= Nsigma    we have     sigma(k) = -k/Nsigma  
                                                          zlev(k) is undefined
for   k > Nsigma             then           sigma(k) is undefined  (_FillValue?)
                                                          zlev(k) has  valid 
entries for Nsigma < k < N

If k numbers bottom to top then (right side of diagram attached)
for  1 < k <= N-Nsigma                    sigma(k) is undefined
                                                           zlev(k) has valid 
entries for 1 < k < Nsigma
for   k > N - Nsigma        we have    sigma(k) = (k-N)/Nsigma
                                                           zlev(k) is undefined 
for k > N-Nsigma

With sigma defined thus as part of the standard, and/or as 1-D vector of 
sigma(k) saved in the output file (this is what we do in ROMS to accommodate 
multiple alternate stretchings in the"sigma" space for ocean_s_coordinate), and 
zlev included in the output as a 1-D vector, then the rule is generic. 

This will work for both numbering conventions:
If sigma is defined 
z(n,k,j,i) = eta(n,j,i) + sigma(k)*(min(depth_c,depth(j,i))+eta(n,j,i))
If sigma is  not defined
z = zlev(k) 

I don't know how you write this in CF-speak. But it's a robust way to code a 
calculation of z(n,sigma(k),i,j) 

![2021-03-03 14 11 
42-1](https://user-images.githubusercontent.com/7196577/109864209-8cf3e280-7c30-11eb-8c1e-dd0ab25d46a1.jpg)


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