In message <[email protected]>, dated Tue, 13 May 2014, "ce-test, qualified testing bv - Gert Gremmen" <[email protected]> writes:

Electrochemical reactions behave like charging a battery, it is the rms value that determines the charge, not the peak value.

I don not agree. I looked for a simple explanation on the web, but so far I found only quite complicated explanations based on the Nernst equation. However, I think you may see that the transfer of electrons from one substance to another, driven by an externally-applied electric field and creating conductive species, includes neither a squaring process or an averaging process. It's simply the reaction of the charged electrons to the field, and the field strength depends on the instantaneous voltage, not the RMS.

However, I did explain that using the peak voltage is a *prudent* assumption. If it proves costly, a lower creepage distance should be tested, but it's difficult and costly to test anything that depends on pollution. Again, you can be *prudent* and test with a worst-case pollutant, soot or carbon from motor brushes.
--
OOO - Own Opinions Only. With best wishes. See www.jmwa.demon.co.uk
Nondum ex silvis sumus
John Woodgate, J M Woodgate and Associates, Rayleigh, Essex UK

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