The hardest part is the lighting because any reflected light off the
shiny parts of the painting surface will cause problems. The best
lighting to counter reflection is cross polarized light. That is, polarize
the light source in one direction with a cross polarizer on the lens.
You can order "Linear Polarizing Laminated Film" in sheets to use
on the light sources. If you use flash, keep some distance between
the polarizing film and the flash head or else you may bleach out
the polarizing film. The cross polarization should greatly reduce the
effect of reflected light off the painting. It is a common technique
used in macro work. See for example:

http://www.naturescapes.net/042004/wh0404.htm

I have used this technique, ordering the film from Edmund Optics.
I forgot to back off the distance of the flash tube to the film and
bleached out the center after just a few shots. The cross polarization
reduces the effective flash light by a lot, 5-8 stops, so the flash will
typically do a near full dump. If the paintings have surface texture
then at least two lights angled 45 degrees to the painting will help.

The other issue will be lens distortion. I'm not that familiar with Canon
glass to recommend which will give the best flat field performance.
You may want to experiment with your lenses first, picking the one 
the is easiest to correct in PS. Stopping down will help with corner
resolution. Stopping down while using cross polarized flash will
typically cause a full flash dump. Studio lights will be more ideal.

Accurate color reproduction is, well, good luck. I suggest testing white
balance and perhaps add a color chart next to the painting with some
test shots to help with color correcting the main shot. I have used
some scanner calibration targets, the best price coming from:

http://www.targets.coloraid.de/

Again, realize that reflected light off the surface of the target is the
same problem as with the painting.

I have been experimenting with cross polarized flash light with
portraits. I never liked seeing the photographers complete flash and
lighting setup reflected in the eyes. So I wanted to see if I could
minimize the amount of flash reflected in the eyes, as well as shinny
parts of the skin. The large loss of light though cross polarization is
the main limitation, and the burn out on the polarizing film from the
intense flash burst. I wish I understood how ETTL II flash worked
better. I have not found a reliable exposure mode.

Wayne

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