Thanks Lee,
I am charging sparingly anyway, because I need to keep my household
electric consumption close to 300 kWh per month or pay a hefty higher rate
for the overage, I managed to get the home itself near 100 kWh/mo by switching
to LED lights and using a gas dryer, heater and cooktop and the 3 adults in
the household use a laptop each, so the times that I charge (typically 4 
weekdays
as I like to commute by bike once a week) and at least once a weekend, I can get
about 10kWh per charge and stay around the 200 kWh/mo budget for charging; 
luckily
I can charge at work as well, so typically I leave work with an (almost) full 
pack
after 6-8 hours of level 1 charging. (I tend to start my work from home, then go
to the office after traffic has cleared).
Since I also charge level 1 at home, my charging current is never more than 12A,
ramping down to below 10A when charging is under way or when the grid is weak at
the outlet, only if I plug in at a 240V J1772 can I get 20A of charge current 
into
the pack (120V nomonal, rising to ~147V under full charge, with current falling 
to
about 4-5A at that voltage from the resonant transformer. The only thing I can 
select
on my Bycan charger is whether I want the shutoff after 2 hours or 8 hours after
detecting the 147V max charge voltage. (The latter is the "equalizing" mode)
The charger is not often allowed to complete this anyway, on average 1 or 2 
times a month.

I am a little concerned if I may have reversed a few cells at the moments that 
I needed
to go a little further than the pack wanted, due to unexpected hills or when 
driving 
more freeway (fast) than anticipated, causing the pack to sag (under load) 
below 90V
which I then tend to counter by reducing power and trying to keep voltage above 
90V
under load, nursing the car along until I can plug in an recharge immediately...
Anyway, time will tell if these cells are weak and deteriorating or simply 
getting older.

Cor van de Water
Chief Scientist
Proxim Wireless Corporation http://www.proxim.com
Email: cwa...@proxim.com    Private: http://www.cvandewater.info
Skype: cor_van_de_water     XoIP: +31877841130
Tel: +1 408 383 7626        Tel: +91 (040)23117400 x203



-----Original Message-----
From: Lee Hart [mailto:leeah...@earthlink.net]
Sent: Sun 8/23/2015 1:49 PM
To: Cor van de Water; Electric Vehicle Discussion List
Subject: Re: [EVDL] Difference in water use per cell for GC batteries
 
Cor van de Water via EV wrote:
> My pack of 20 Golfcart batteries is now almost 4 years old and
> it has brought my truck over 14k miles so far, but tonight when
> I inspected a couple of the batteries I noticed something strange -
> while some cells had minimal water loss (level about 1/2" under the
> top of the cell) there were several other cells that barely had their
> plates covered, the level had gone down more than a full inch in those!
> How can this difference be explained?

4-5 years is about right for Sam's Club (Eveready a.k.a. Interstate) 
golf cart batteries. That's what I've been getting, too. Trojans and US 
Battery brands are a little better.

As others have noted, water usage increases as a flooded lead-acid 
battery ages. This happens for several reasons; some due to the battery, 
and some due to the charger.

Flooded batteries use a lead-antimony alloy for the plates. The antimony 
hardens the plates (makes them stronger), which extends life. But it 
also increases water usage, the self-discharge rate, and lowers the 
fully-charged voltage.

As the battery ages, the antimony migrates to the surface of the plates. 
This worsens all these effects. The battery gasses more, uses more 
water, and its fully charged voltage will be less. (It doesn't otherwise 
affect the amphour capacity, though. Loss of capacity comes from other 
effects.)

Most chargers do not compensate for new/old batteries. They blindly 
charge all batteries as if they are new. This means that old batteries 
get charged to too high a voltage. That significantly worsens gassing 
and water usage. The resulting chronic overcharging also shortens life. 
(This is why the batteries in an old batteries tend to "suddenly" all 
die together).

Big industrial EV chargers use the dv/dt or di/dt algorithms to 
compensate for battery age, and thus extend their life. Rather than 
charge to a specific ending voltage (or current), they charge until the 
*rate of change* in voltage or current goes below some limit. If your 
charger has this option, use it.

If not, your best bet is to reduce your charger's end-of-charge voltage 
(for example, from 2.5v/cell to 2.45v/cell). Also increase your final 
charging current (from 4 amps to 8 amps). In other words, rather than 
shutting off at 7.5v at 4 amps, change it to shut off at 7.35v at 8 amps.

Old batteries also need more frequent equalization. While you might only 
need to do this every 2 months when new, it could need to be done ever 2 
weeks when old. "Equalization" is a long slow low-current charge to an 
"unlimited" voltage. Basically, you charge at something like 2-4 amps 
until the voltage stops rising.

If you take care of them in their "declining years", the batteries can 
easily provide double the life and number of miles before the pack needs 
to be replaced. :-)

-- 
Do the thing that needs to be done, even if no one else yet notices
that it needs doing. -- anonymous
--
Lee Hart, 814 8th Ave N, Sartell MN 56377, www.sunrise-ev.com


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