Re: [geo] Arctic sea ice depletion to result in rise of CO2 in atmosphere |
Zee News

North Atlantic Deep Water (NADW) is thought to primarily form in the open
ocean and does not originate from the brine coming off the bottom of sea
ice.



Peter



Peter Flynn, P. Eng., Ph. D.

Emeritus Professor and Poole Chair in Management for Engineers

Department of Mechanical Engineering

University of Alberta

[email protected]

cell: 928 451 4455







*From:* [email protected] [mailto:
[email protected]] *On Behalf Of *Mike MacCracken
*Sent:* September-23-14 6:32 PM
*To:* Ken Caldeira; Greg Rau
*Cc:* Andrew Lockley; Geoengineering; [email protected]
*Subject:* Re: [geo] Arctic sea ice depletion to result in rise of CO2 in
atmosphere | Zee News



In my reading, the wording was very confusing. Reading more carefully, it
seemed to me that they were saying that there will be less CO2 in the ocean
as a result of melting back of the sea ice. An open Arctic with no sea ice
formation would imply less down-welling due to not forming dense brine
pockets, so one mechanism would be a consequence of that, and another might
be due to the greater stability of the ocean in the warm season. I did not
read the paper, but, once I got past some unclear wording, the sign sort of
made sense.

Mike


On 9/23/14 1:52 PM, "Ken Caldeira" <[email protected]> wrote:

Agree with Greg.

If there is any net effect of this process at all (relative to the no-ice
situation) then quantitatively it must be tiny tiny tiny.

If the alkalinity represented by the Ca2+ in the CaCO3 was in the surface
ocean with no ice, that would tend to draw CO2 into the ocean.


_______________
Ken Caldeira

Carnegie Institution for Science
Dept of Global Ecology
260 Panama Street, Stanford, CA 94305 USA
+1 650 704 7212 [email protected]
http://dge.stanford.edu/labs/caldeiralab
https://twitter.com/KenCaldeira

Assistant:  Dawn Ross <[email protected]>


On Wed, Sep 24, 2014 at 5:45 AM, Rau, Greg <[email protected]> wrote:

"A new study has revealed that Arctic Sea ice helps remove carbon dioxide
from the atmosphere and its depletion would result in an increase of
atmospheric concentration of the gas." [?!]

How does removing CO2 from air increase air CO2 concentrations? Anyway, can
believe that CaCO3 precipitates and CO2 is generated as seawater freezes
and brine is formed: Ca(HCO3)2aq ---> CaCO3s + CO2g + H2O.  But whether the
CO2 is then subducted with the sinking brine or degasses to the atmosphere
would seem critical to the air/ocean CO2 budget. That some CaCO3s is
entrained in the the ice seems logical, but how the preceding reaction is
reversed to consume this carbonate and CO2 is unclear. There would need to
be a way to concentrate CO2 to generate H2CO3 to then consume the CaCO3s to
(re)make Ca(HCO3)2aq.  How does that happen? Anyway, if it does happen this
would seem to offer a new explanation for glacial/ interglacial CO2
variations, not to mention a new method of modern day CDR - bomb sea ice
sheets with limestone particles.  Beneficial "chemtrails on ice" ;-)
Greg

------------------------------

*From:* [email protected] [[email protected]]
on behalf of Andrew Lockley [[email protected]]
*Sent:* Tuesday, September 23, 2014 4:56 AM
*To:* geoengineering
*Subject:* [geo] Arctic sea ice depletion to result in rise of CO2 in
atmosphere | Zee News

http://zeenews.india.com/news/eco-news/arctic-sea-ice-depletion-to-result-in-rise-of-co2-in-atmosphere_1474406.html

Arctic sea ice depletion to result in rise of CO2 in atmosphere Last
Updated: Tuesday, September 23, 2014 - 12:38

Washington: A new study has revealed that Arctic Sea ice helps remove
carbon dioxide from the atmosphere and its depletion would result in an
increase of atmospheric concentration of the gas.

Dorte Haubjerg Sogaard, PhD Fellow, Nordic Center for Earth Evolution,
University of Southern Denmark and the Greenland Institute of Natural
Resources, Nuuk, said that if their results are representative, then sea
ice plays a greater role than expected, and we should take this into
account in future global CO2 budgets.

The researchers said that they have long known that the Earth's oceans are
able to absorb huge amounts of CO2. But they also thought that this did not
apply to ocean areas covered by ice, because the ice was considered
impenetrable. However, this is not true, as the new research shows that sea
ice in the Arctic draws large amounts of CO2 from the atmosphere into the
ocean.

Sogaard said that the chemical removal of CO2 in sea ice occurs in two
phases. First crystals of calcium carbonate are formed in sea ice in
winter. During this formation CO2 splits off and is dissolved in a heavy
cold brine, which gets squeezed out of the ice and sinks into the deeper
parts of the ocean. Calcium carbonate cannot move as freely as CO2 and
therefore it stays in the sea ice. In summer, when the sea ice melts,
calcium carbonate dissolves, and CO2 is needed for this process. Thus, CO2
gets drawn from the atmosphere into the ocean -and therefore CO2 gets
removed from the atmosphere.

ANI

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