Dan

What's your view on using CH4 as a lifting gas at volume scale?

Andrew

On Fri, 30 Dec 2022, 16:48 Daniele Visioni, <[email protected]>
wrote:

> Aside from simply being a greenhouse gas (and not to mention how it is
> produced - countries use weather balloons filled with hydrogen but the
> machinery to produce H on site is expensive, and the handling procedures
> are complex, see https://www.fp2fire.com/hydrogen-balloon-inflation/),
> hydrogen is a reactive species that tends to deplete hydroxyl radical
> molecules (forming H2O), which also happens to be what you need to produce
> H2SO4.
>
> So if you started using hydrogen you would:
> - have even more and possibly unknown reaction capable of modifying ozone
> (meaning the link to our study on ozone depletion you have on your website
> would be irrelevant), and potentially rendering your SO4 formation
> processes inefficient
> - risk balloon safety - normally you need to make sure you’re only putting
> H in your balloon (see link above). I doubt balloons have been tested with
> such a mixture inside, and that some form of reaction wouldn’t occur.
> - assuming you use 1g of H for 1g of sulfate, as Russell has already said,
> at scale you would emit in the stratosphere a quantity of hydrogen similar
> to current estimates for the whole hydrogen leak rate of a whole hydrogen
> economy in 2050 (source
> https://www.energypolicy.columbia.edu/research/commentary/hydrogen-leakage-potential-risk-hydrogen-economy#:~:text=The%20leakage%20rate%20stands%20between,%242%2Fkg%2DH2
> ).
> But if that hydrogen was released in the stratosphere directly its GWP
> would be much higher than that estimated from current surface leaks (
> https://acp.copernicus.org/articles/22/9349/2022/)
>
> So while doing stunts with Helium and sulfate you produce yourself may be
> seen as potentially harmless, without proper studies doing the same with
> hydrogen would be outright insane and hazardous.
>
> Onus would be on you to prove otherwise *before* outdoor tests.
>
>
> On 30 Dec 2022, at 11:22, Luke Iseman <[email protected]> wrote:
>
> Russell,
>
> My cofounder tweeted the "trade secrets" claim in error (see further up in
> this thread).
> I agree helium is a valuable resource and intend to switch to hydrogen in
> the future.
> I also don't have religion around balloons: if anyone has a surplus
> stratospheric aircraft sitting around along with a venue from which to fly
> it, that's probably a better value then balloons;)
>
> --------------------
> Luke Iseman
> lukeiseman.com
>
>
>
> On Thu, Dec 29, 2022 at 6:07 PM Russell Seitz <[email protected]>
> wrote:
>
>> Luke,  Make Sunsets has tweeted invoking "trade secrets ' in denying
>> simple requests to quantify how much  helium is needed  per
>>  " cooling credit".
>> This lack of transparency cannot stop anyone , policy analysts included
>> from running the numbers .
>>
>> Dimensional analysis  based on handbook  and commercially disclosed
>> values of the physical constants of  air, helium and SO2 indicates that you
>> can at best hope to lift 1.01 Kg per  STP cubic meter of 97% pure balloon
>> grade He.
>>
>> Since SO2 vapor's molecular weight makes it over twice as dense as air  (
>> ~64/29),  even if  if the dead weigh of the balloon and its telemetry are
>> completely disregarded it will still take  a tonne  or more of helium to
>> loft a  tonne of aerosol feedstock to stratospheric elevation.
>>
>> As you must be aware,  the short supply of helium ( the US strategic
>> reserve acquired after WWII was largely sold off by 2021)  has already
>> quadrupled its cost.,  and at present , annual   global production is
>> below100,000 tonnes and recoverable reserves stand at around 30 million
>> tonnes globally.
>>
>> Using NOAA's numbers:
>>
>> https://research.noaa.gov/article/ArtMID/587/ArticleID/2756/Simulated-geoengineering-evaluation-cooler-planet-but-with-side-effects
>>  it is clear that your scheme would  require lofting of a megatonne  or
>> more of SO2 a year per degree K of cooling: which is not only an order of
>> magnitude more that present production can bear, but enough to completely
>> deplete known reserves and resources by 2050.
>>
>> Finally, US helium is almost exclusively a byproduct of natural gas
>> production , and so entails substantial release of  methane and other
>> hydrocarbons that are greenhouse gases  more powerful than CO2
>>
>> On Wednesday, December 28, 2022 at 6:09:51 PM UTC-5 [email protected]
>> wrote:
>>
>>> Thanks Andrew, Olivier, Bala, and everyone else for diving in with
>>> critiques here. I'm a cofounder of Make Sunsets and want to clarify a few
>>> things:
>>>
>>> *Honesty: *
>>> We have no desire to mislead anyone. If we make a mistake (which we
>>> will), we'll correct it.
>>> *Radiative Forcing:*
>>> I didn't make this "gram offsets a ton" number up. It comes from David
>>> Keith's research:
>>> "a gram of aerosol in the stratosphere, delivered perhaps by high-flying
>>> jets, could offset the warming effect of a ton of carbon dioxide, a factor
>>> of 1 million to 1."
>>> <https://keith.seas.harvard.edu/news/whats-right-temperature-earth>
>>> and, again: "Geoengineering’s leverage is very high—one gram of
>>> particles in the stratosphere prevents the warming caused by a ton of
>>> carbon dioxide."
>>> <https://longnow.org/seminars/02015/feb/17/patient-geoengineering/>
>>> By stating "offsetting the warming effect of 1 ton of carbon for 1
>>> year," I was trying to be more conservative than Professor Keith. I am
>>> correcting "carbon" to read "carbon dioxide" on the cooling credit
>>> description right now, and I'm adding a paragraph at the start of the post
>>> stating that estimates vary, but a leading researcher cites a gram
>>> offsetting a ton.
>>> For the several hundred dollars of cooling credits we've already sold,
>>> I'll be providing evidence to each purchaser that I've delivered at least 2
>>> grams per cooling credit.
>>> Olivier, or anyone else: I'd be happy to post something by you to our
>>> blog explaining what you estimate the radiative forcing of 1g so2 released
>>> at 20km altitude from in or near the tropics will be and why. I will
>>> include language of your choosing explaining that you in no way endorse
>>> what we are doing.
>>> I very much hope to get suggestions from this community on
>>> instrumentation we should fly to improve the state of the science here.
>>> Again, I'm happy to do this with disclaimers about how researchers we fly
>>> things for are not endorsing our efforts. Or even without revealing who the
>>> researchers are: we'll fly test instruments and provide data, no questions
>>> asked:)
>>> *Telemetry: *
>>> My first 2 flights had no telemetry: in April, this was still in
>>> self-funded science project territory. After burning some sulfur and
>>> capturing the resultant gas, I placed this in a balloon. I then added
>>> helium, underinflating the balloon substantially, and let it go. There is
>>> technically a slim possibility that neither of these balloons reached the
>>> stratosphere, as I acknowledged to the Technology Review reporter. I will
>>> add Spot trackers to my next flights. These cut out at 18km, so I'l be able
>>> to confirm that I achieve at least this altitude. If (and this is a big if)
>>> I'm able to recover the balloons, I'll have a lot more data from the flight
>>> computer
>>> <https://www.highaltitudescience.com/collections/electronics/products/eagle-flight-computer>.
>>> I will eventually switch to Swarms
>>> <https://www.sparkfun.com/products/19236?utm_campaign=May%206%2C%202022&utm_medium=email&_hsmi=212205037&_hsenc=p2ANqtz-9EyQOQ6C-9XuSOHa7CggOC8Pf2tEow_Fppo5pXgTHO8-7gV-aHrrYpnPcliws6Ju8j2PBAX3Tkog0oVpwk8XqWX2xo0w&utm_content=212206499&utm_source=hs_email>,
>>> which should let me transmit more data regardless of balloon recovery.
>>> *Pricing: *
>>> Bala, you're totally right that this should be priced much lower. We're
>>> trying to make enough with our early flights to stay in business until we
>>> get meaningful traction with customers, and we plan to eventually drop
>>> prices to $1 per ton or less.
>>> *Reuse: *
>>> We are not yet reusing balloons, and Andrew is correct that latex UV
>>> degradation will limit our ability to do so with weather balloons. Given
>>> that balloon cost is our main expense per gram, even a few uses per balloon
>>> will dramatically improve the economics here.
>>>
>>> I expect to disagree with some of you, but I hope we can do so politely
>>> and assuming good intentions.
>>>
>>
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