Charel Wohl et al, *Marine emissions of methanethiol increase aerosol
cooling in the Southern Ocean*, *Science Advances* (2024). DOI:
10.1126/siadv.adq 2465 <https://dx.doi.org/10.1126/sciadv.adq2465>

-------------------------

phys.org /news/2024-11-oceans-emit-sulfur-cool-climate.html
<https://phys.org/news/2024-11-oceans-emit-sulfur-cool-climate.html> Oceans
emit sulfur and cool the climate more than previously thought University of
East Anglia 27/11/2024
------------------------------

For the first time, researchers have quantified the global emissions of a
sulfur gas produced by marine life, revealing that it cools the climate
more than previously thought, especially over the Southern Ocean.

The study, published <https://www.science.org/doi/10.1126/sciadv.adq2465>
in the journal *Science Advances,* shows that the oceans not only capture
and redistribute the sun's heat, but produce gases that make particles with
immediate climatic effects; for example, through the brightening of clouds
that reflect this heat.

This broadens the climatic impact of marine sulfur because it adds a new
compound, methanethiol, that had previously gone unnoticed. Researchers
only detected the gas recently, because it had previously been notoriously
hard to measure. Earlier work had focused on warmer oceans, whereas the
polar oceans are the emission hotspots.

The research was led by a team of scientists from the Institute of Marine
Sciences (ICM-CSIC) and the Blas Cabrera Institute of Physical Chemistry
(IQF-CSIC) in Spain. They included Dr. Charel Wohl, previously at ICM-CSIC
and now at the University of East Anglia (UEA) in the UK.

Their findings represent a major advance on one of the most groundbreaking
theories proposed 40 years ago about the role of the ocean in regulating
Earth's climate.

This suggests that microscopic plankton
<https://phys.org/tags/microscopic+plankton/> living on the surface of the
seas produce sulfur in the form of a gas, dimethyl sulfide, that—once in
the atmosphere—oxidizes and forms small particles called aerosols.

Aerosols reflect part of the solar radiation back into space and therefore
reduce the heat retained by the Earth. Their cooling effect is magnified
when they become involved in making clouds, with an effect opposite of—but
of the same magnitude as—that of well-known warming greenhouse gases such
as carbon dioxide or methane.

The researchers argue that this new work improves our understanding of how
the climate of the planet is regulated by adding a previously overlooked
component, and that the work illustrates the crucial importance of sulfur
aerosols. They also highlight the magnitude of the impact of human activity
on the climate and that the planet will continue to warm if no action is
taken.

Dr. Wohl, of UEA's Centre for Ocean and Atmospheric Sciences and one of the
lead authors, said, "This is the climatic element with the greatest cooling
capacity, but also the least understood. We knew methanethiol was coming
out of the ocean, but we had no idea about how much and where. We also did
not know it had such an impact on climate.

"Climate models have greatly overestimated the solar radiation actually
reaching the Southern Ocean, largely because they are not capable of
correctly simulating clouds. The work done here partially closes the
longstanding knowledge gap between models and observations."

With this discovery, scientists can now represent the climate more
accurately in models that are used to make predictions of +1.5 ºC or +2 ºC
warming, a huge contribution to policy-making.

"Until now, we thought that the oceans emitted sulfur into the atmosphere
only in the form of dimethyl sulfide, a residue of plankton that is mainly
responsible for the evocative smell of shellfish," said Dr. Martí Galí, a
researcher at the ICM-CSIC and another of the main study authors.

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Dr. Wohl added, "Today, thanks to the evolution of measurement techniques,
we know that plankton also emit methanethiol, and we have found a way to
quantify, on a global scale, where, when and in what quantity this emission
occurs. Knowing the emissions of this compound will help us to more
accurately represent clouds over the Southern Ocean and calculate more
realistically their cooling effect <https://phys.org/tags/cooling+effect/>."

The researchers gathered all the available measurements of methanethiol in
seawater, added those they had made in the Southern Ocean and the
Mediterranean coast, and statistically related them to seawater
temperature, obtained from satellites.

This allowed them to conclude that annually and on a global average,
methanethiol increases known marine sulfur emissions by 25%.

"It may not seem like much, but methanethiol is more efficient at oxidizing
and forming aerosols than dimethyl sulfide and, therefore, its climate
impact is magnified," said co-lead Dr. Julián Villamayor, a researcher at
IQF-CSIC.

The team also incorporated the marine emissions of methanethiol into a
state-of-the-art climate model to assess their effects on the planet's
radiation balance. It showed that the impacts are much more visible in the
Southern Hemisphere, where there is more ocean and less human activity, and
therefore the presence of sulfur <https://phys.org/tags/sulfur/> from the
burning of fossil fuels is lower.

*More information:* Charel Wohl et al, Marine emissions of methanethiol
increase aerosol cooling in the Southern Ocean, *Science Advances* (2024). DOI:
10.1126/sciadv.adq2465 <https://dx.doi.org/10.1126/sciadv.adq2465>
------------------------------

Explore further
New study highlights the impact of two new marine gases on climate models'
accuracy
<https://phys.org/news/2023-01-highlights-impact-marine-gases-climate.html>
------------------------------

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