https://acp.copernicus.org/articles/25/4531/2025/

*Authors*
Erin J. Emme and Hannah M. Horowitz

24 April 2025

*Abstract*
The processes contributing to Arctic cold-season (November–April) sea salt
aerosols (SSAs) remain uncertain. Observations from coastal Alaska suggest
that emissions from open leads in sea ice, which are not included in
climate models, may play a dominant role. Their Arctic-wide significance
has not yet been quantified. Here, we create an emission parameterization
of SSAs from leads by combining satellite data of lead area (the Advanced
Microwave Scanning Radiometer–Earth Observation System (AMSR-E) product)
and a chemical transport model (GEOS-Chem) to quantify pan-Arctic SSA
emissions from leads during the cold season from 2002 to 2008 and to
predict their impacts on atmospheric chemistry, evaluating the results of
our simulated SSAs against in situ observations. The AMSR-E product detects
large leads with certainty (> 3 km in size), and, hence, our study is
limited to quantifying emissions from large leads. Lead emissions vary
seasonally and interannually. Simulated total monthly SSA emissions
increase by 1.1 %–1.8 % (≥60° N latitude) and 5.6 %–7.5 % (≥75° N) for the
2002–2008 cold seasons. SSA concentrations primarily increase at the
location of leads, where standard model concentrations are low. GEOS-Chem
overestimates SSA concentrations at Arctic sites compared to ground
observations, even when lead emissions are not included, suggesting
underestimation of SSA sinks and/or uncertainties in SSA emissions from
blowing snow and the open ocean. Multi-year monthly mean surface bromine
atom (Br) concentrations increase by 2.8 %–8.8 % due to SSAs from leads for
the 2002–2008 cold seasons. Changes in ozone concentrations are negligible.
While leads contribute < 10 % to Arctic-wide SSA emissions in the years
2002–2008, these emissions occur in regions of low background aerosol
concentrations. Leads may increase in frequency under future climate
change, which could increase SSA emissions from leads.

*Source: European Geosciences Union*

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