https://pubs.acs.org/doi/10.1021/acsami.5c07156

*Authors*
Zhi-Jun Zhu, Ziqi Li, Xiaohong Wu, Chen Liu, Nanhao Chen, Yichi Zhang, Yan
Chen, Xing Ouyang, Akbar Bashir, Da-Zhu Chen

*01 June 2025*

*Abstract*
Radiative cooling has emerged as a highly innovative, clean, and
environmentally sustainable cooling solution, leveraging passive heat
dissipation without the need for additional energy inputs. Herein, we
introduce an advanced radiative cooling fiber membrane incorporating 10 wt
% SiO2/PHBV with a micronano-multistage architecture. This membrane is
fabricated via electrospinning technology, utilizing
poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) as the biodegradable
matrix, which features multiple absorption peaks within the atmospheric
window. The SiO2 nanoparticles embedded within the membrane enhance Mie
scattering and act as selective emissive materials in this window. The
fiber membrane achieves an impressive solar reflectivity of 0.95 and an
emissivity of 0.89 in the atmospheric window. When exposed to direct
sunlight with an average radiation intensity of 537.06 W/m2, the membrane’s
cooling temperature is 4.85 °C, yielding a temperature differential of
approximately 12.8 °C relative to human skin. The average cooling power of
the membrane is 64.05 W/m2, with a peak cooling power of 91.75 W/m2 under
an average solar radiation intensity of 751.83 W/m2. Furthermore, the fiber
membrane exhibits a remarkable 151% elongation at break and a water contact
angle of 124.5°, highlighting its suitability for use in personal wearable
cooling fabrics.

*Source: ACS Publications*

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