One more probable step in piecing together what ‘we’ are from the
scientific community.

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'Nature's Batteries' May Have Helped Power Early Lifeforms

ScienceDaily (May 25, 2010) — Researchers at the University of Leeds
have uncovered new clues to the origins of life on Earth.

The team found that a compound known as pyrophosphite may have been an
important energy source for primitive lifeforms.

There are several conflicting theories of how life on Earth emerged
from inanimate matter billions of years ago -- a process known as
abiogenesis.

"It's a chicken and egg question," said Dr Terry Kee of the University
of Leeds, who led the research. "Scientists are in disagreement over
what came first -- replication, or metabolism. But there is a third
part to the equation -- and that is energy."

All living things require a continual supply of energy in order to
function. This energy is carried around our bodies within certain
molecules, one of the best known being ATP (adenosine triphosphate),
which converts heat from the sun into a useable form for animals and
plants.

At any one time, the human body contains just 250g of ATP -- this
provides roughly the same amount of energy as a single AA battery.
This ATP store is being constantly used and regenerated in cells via a
process known as respiration, which is driven by natural catalysts
called enzymes.

"You need enzymes to make ATP and you need ATP to make enzymes,"
explained Dr Kee. "The question is: where did energy come from before
either of these two things existed? We think that the answer may lie
in simple molecules such as pyrophosphite which is chemically very
similar to ATP, but has the potential to transfer energy without
enzymes."

The key to the battery-like properties of both ATP and pyrophosphite
is an element called phosphorus, which is essential for all living
things. Not only is phosphorus the active component of ATP, it also
forms the backbone of DNA and is important in the structure of cell
walls.

But despite its importance to life, it is not fully understood how
phosphorus first appeared in our atmosphere. One theory is that it was
contained within the many meteorites that collided with the Earth
billions of years ago.

"Phosphorus is present within several meteoritic minerals and it is
possible that this reacted to form pyrophosphite under the acidic,
volcanic conditions of early Earth," added Dr Kee.

The findings, published in the journal Chemical Communications, are
the first to suggest that pyrophosphite may have been relevant in the
shift from basic chemistry to complex biology when life on earth
began. Since completing this research, Dr Kee and his team have found
even further evidence for the importance of this molecule and now hope
to team up with collaborators from NASA to investigate its role in
abiogenesis.

The study was funded by the STFC and the Engineering and Physical
Sciences Research Council (EPSRC).

http://www.sciencedaily.com/releases/2010/05/100525094906.htm

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