It's probably the capacitance. And yes, it's enough of a shock to scare you 
and reflexively drop something valuable.
I found this out the hard way; LC-filter in a metal box did a great job 
getting rid of line noise.

This would never pass today's regulatory requirements, and it probably 
would cause a GFCI to trip.

Connecting a resistor from the AC neutral to the chassis was done on many 
TV sets from the 1960's; RCA and Zenith had a 22meg resistor for 
bleeding-away charge on the metal chassis. And this was NOT one of the 
infamous hot-chassis sets. I suspect it had to do with exposed metal parts 
getting capacitively charged via the picture tube; with the resistor the 
current was very small (well-below threshold of sensation) even if hot and 
neutral got swapped.

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