I'm looking to experiment with making a cold cathode character display. I 
have plenty of experience experimenting with manufactured IN-12 tubes and 
the power supplies that drive these, but I want to step further to 
experiment in making my own.

What grade of materials / tubing / valves should I be looking at to try and 
build my own jig for evacuating air from a tube and populating a gas?

I don't suppose just about any valve with do (like liquid control valve) 
and looking at my hobbyist grade vacuum chamber, the tubing contains a 
spooled wire on the inside to provide rigidity to counter the vacuum forces.

Would brass / copper tubing sealed with aluminum weld be suitable?

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