I've used sharpies with no ill effects. They do have a ability to write on anything and a tendency to bleed through porous materials, not to mention an odor of xylene, all of which are a bit disquieting. Recently I found a Staedtler felt tip specifically recommended for writing on CDs.
<http://www.staedtler.com/Lumocolor_CD_DVD_pen_gb.Staedtler?ActiveID=2318>

They say you can leave the top off for days and they won't dry out. Haven't tried it but I know that sharpies don't work that way.
--
Alan P. Hayes
Meaning and Form: Writing, Editing and Document Design
Pittsfield, Massachusetts

Photographs at
http://www.ahayesphoto.com/americandead/index.htm

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