Re: [Biofuel] Keith Addison passed away

2014-11-06 Thread Aleksander Kac
Oh, such sad news. Hardly a day will pass of me not thinking of Keith - as 
always. Deepest sympathies, Midori.

Rest in peace, brother.
Aleks

-Original Message-
From: sustainablelorgbiofuel-boun...@lists.sustainablelists.org 
[mailto:sustainablelorgbiofuel-boun...@lists.sustainablelists.org] On Behalf Of 
Keith Addison
Sent: Wednesday, November 05, 2014 2:35 PM
To: sustainablelorgbiofuel@lists.sustainablelists.org
Subject: [Biofuel] Keith Addison passed away

Dear biofuel friends,

Keith, who contributed so much to the handmade biofuel movement and related 
appropriate technology and organic movements, died of pneumonia in August 2014.

This is Midori, Japanese partner of Keith Addison.
My apology for being late to tell you this sad news. It took a while for me to 
recover from his death and rearrange related matters. Still continues..

I'd like to maintain his projects available online, in which Keith devoted so 
much - literally he devoted more than 10 years of his life to 
journeytoforever.org and biofuel mailinglists. I cannot contribute to it 
anymore, but at least I will keep them as they are, available to the public for 
coming years.

Regarding to this mailinglist, I suppose he left the managing to somebody else 
around 2013 - please advise me how this is arranged now, off-list if it's more 
suitable. I now manage his emails at ke...@journeytoforever.org and I see 
more than 100 moderator requests piling up (most of them are Post by 
non-member to a members-only list). I also manage the domain name 
sustainablelists.org. Do we still need it for the list? Please advise.

There have been so many issues on and around these mailinglists over the 
decade. Keith used to tell me hours about what's going on on the list, both 
happy and annoying issues. No matter what - I really appreciate for your 
support and contribution for Keith over these years. Thank you so much. I hope 
we all remember Keith and what he taught us.

Many thanks and best wishes,

Midori
Kyoto, Japan
- I can be reached at i...@journeytoforever.org. Please specify to Midori 
in the title. Thanks.

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Re: [Biofuel] Any beekeeping contacts in Switzerland?

2014-08-19 Thread Aleksander Kac
To see alpine beekeping and beehouses you need to come to Slovenia. I'm 
starting to keep bees myself this year, with one colony. I will
build a beehouse into a whole side of my roofed patio, so it will be a part of 
the house. This is not traditional, but also not unheard of.
A trip to Slovenia will also be substantially cheaper than Switz, an to not 
forget, Slovenia is the original home of the carnica bee. We call it The Grey.
Some links:
Slovenian beekeeping association: http://www.czs.si/turizem_en/index.php
Slovenian beehouse plans (just click on TIP A, B and C) by my friend, the 
architect Marjan Debelak : http://www.czs.si/cebelar_cebelnjaki.php
Traditional Slovenian hive (Alberti Žnideršič hive, AKA AŽ hive) 
http://www.logar-trade.si/panji/?klasid=10601000 although all sorts of hive 
systems are in use.

Cheers, A.

-Original Message-
From: sustainablelorgbiofuel-boun...@lists.sustainablelists.org 
[mailto:sustainablelorgbiofuel-boun...@lists.sustainablelists.org] On Behalf Of 
Zeke Yewdall
Sent: Tuesday, August 19, 2014 8:39 PM
To: sustainablelorgbiofuel@lists.sustainablelists.org
Subject: [Biofuel] Any beekeeping contacts in Switzerland?

I am trying to find out more about the beehouses used in Switzerland (and other 
mountainous regions in Europe).  There's very little info on them here in the 
US, but the standard langstroth hive does not work as well in cold winter 
climates, from what I can gather.  And, they require electric fences for any 
protection from bears, and even with them, bear invasions are common in the 
mountains.  But, they're cheap... the US way of doing
things.I am considering making a trip to Switzerland next summer to
research these more and see how they function, however, I need to get some 
contacts there first and see if it's possible to set up a tour of beehouses, 
etc. My not speaking German is not helping the research ;) But, I figured this 
list might have some ideas.

Thanks

Zeke
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Re: [Biofuel] Fwd: New Engine 100 MPG

2011-05-27 Thread Aleksander Kac
Well, I need to say something here. Why all these inventions?

You can buy a whole production car capable of 100 mpg today. 

The world record in fuel economy set by Gerhardt Plattner with this car is 
actually way better: 107 mpg from austria to denmark and back, 2007 km on 45 
litres of diesel, using autobahns, climbing mountain highway passes etc. 
http://carscoop.blogspot.com/2011/05/gerhard-plattner-does-it-again-drives.html 
(7% better fuel economy at these low values is no easy job in real world 
traffic)

It's not a hybrid.

It's got aircon and everything a modern car should have. 

It hasn't got an exotic engine, the engine is a common rail 1.2 litre tdi.

It's even almost half reasonably priced.

And it's not even a kei or very small car : Skoda Fabia Greenline II 
http://www.buyacar.co.uk/cars/skoda/skoda_fabia/review_skoda_fabia_greenline_ii_4637.jhtml

Cheers, Aleks


-Original Message-
From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED]] On Behalf Of Lee Dyson
Sent: Friday, May 27, 2011 3:13 AM
To: sustainablelorgbiofuel@sustainablelists.org
Subject: [Biofuel] Fwd: New Engine 100 MPG

Hello All,

was sent this, looks interesting. Looks like if it can be vaporised and 
combustible you can run this engine on it, diesel also. Looks like the idea has 
been around since at least the 1950's

Lee


Begin forwarded message:

 Subject: FW: New Engine 100 MPG
 
  
  
  
 
 
 New Engine! VEY Cool!  
 
 Here is another German Invention! 
 
 Oh, and by the way! Let’s watch this invention closely, so we can observe 
 the MANOEUVERING  of the Oil Companies, Lawyers, Politicians, Unions and 
 Wall Street, to cut this invention off at the knees, delay  and/or even 
 stop it’s development. They will all contribute to stopping this engine 
 from ever reaching the American consumer in a reasonable time frame at a 
 reasonable price. JUST WATCH! 
 
 Be sure and watch the video….  Interesting..!! 
 
 For a good demo, See: 
 http://www.engineeringtv.com/video/Opposed-Piston-Opposed-Cylinder
 
 Saving the World Two Strokes at a Time
 
 
 
 
 This is no wimp engine. It's a two cylinder with four pistons 
 delivering 300+ Horse Power It's extremely small and very 
 efficient and is presently in use in test applications The 
 configuration below is equivalent to a extremely ballsy four 
 cylinder engine when doubled, it's an extremely ballsy 600+ H.P. 
 engine
 
 
 
 
 
 
 
 It’s called OPOC (Opposed Piston Opposed Cylinder), and it’s a 
 turbocharged two-stroke, two-cylinder, with four pistons, two in each 
 cylinder, that will run on gasoline, diesel or ethanol. The two pistons, 
 inside a single cylinder, pump toward and away from each other, thus 
 allowing a cycle to be completed twice as quickly as a conventional 
 engine while balancing it's own loads.
 
 The heavy lifting for this unconventional concept was performed Prof. 
 Peter Hofbauer. During his 20 years at VW, Hofbauer headed up, among 
 other things, development of VW’s first diesel engine and the VR6.
 
 The OPOC has been in development for several years, and the company 
 claims it’s 30 percent lighter, one quarter the size and achieves 50 
 percent better fuel economy than a conventional turbo diesel engine.
 
 They’re predicting 100 MPG in a conventional car!
 
 
  
 
  
  
 
 
 


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Re: [Biofuel] Fwd: New Engine 100 MPG

2011-05-27 Thread Aleksander Kac
Well.
Regardless of every sane argument I need to drive to make a living.
To pay the house I live in, to pay for my internet connection, you get it, I 
believe.
I need to drive a lot some days. I need to carry tools sometimes. I need to be 
on time and I'm hot. 

So yes, its 33 deg C out there, and the humidity is high, and aircon helps a 
lot. 

I work 13-14 hours some days, staying cool during drives helps to stay alert on 
the road. 
So yes, I not only believe aircon is nice, I believe it's neccessary on some 
days. 

Traffic is heavy only some days, but mostly very bearable where I live. 

The most we need to take real good care of these days are the cyclists. 

These are not people getting from A to B, these are people with nothing to do 
all afternoon and they didn't tire themselves during their work day. But I 
still take care.

So yes, passive and active safety elements in cars are essential. And we don't 
have tank traffic at all. We don't even have many tanks left anymore. There are 
some
large vehicles on road and I happen to own one. And no, it's not putting in 
danger any one, it's rather useful for that matter. 

Cheers, Aleks



-Original Message-
From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED]] On Behalf Of Dawie Coetzee
Sent: Friday, May 27, 2011 11:54 AM
To: sustainablelorgbiofuel@sustainablelists.org
Subject: Re: [Biofuel] Fwd: New Engine 100 MPG

Hi Aleks, Jason

Well, I need to say something here. Why all these inventions?

Why indeed?

You can buy a whole production car capable of 100 mpg today.

Unfortunately it is fundamentally one of several million of them, and done that 
way can't be otherwise. 


The  world record in fuel economy set by Gerhardt Plattner with this car is  
actually way better: 107 mpg from austria to denmark and back, 2007 km  on 45 
litres of diesel, using autobahns, climbing mountain highway  passes etc. 
http://carscoop.blogspot.com/2011/05/gerhard-plattner-does-it-again-drives.html 
(7% better fuel economy at these low values is no easy job in real world 
traffic)

It's not a hybrid.

Good.

It's got aircon and everything a modern car should have.

Should a modern car have aircon and everything else? Why? Perhaps because it 
spends so much time in heavy traffic? Isn't THAT rather the problem? 


It hasn't got an exotic engine, the engine is a common rail 1.2 litre tdi.

That's one common rail too exotic!

It's even almost half reasonably priced.

And it's not even a kei or very small car : Skoda Fabia Greenline II 
http://www.buyacar.co.uk/cars/skoda/skoda_fabia/review_skoda_fabia_greenline_ii_4637.jhtml
 

Primarily because it needs to 'protect' its occupants against all that tank 
traffic ...

Cheers, Aleks

This looks like a lot of fun to me. Seventeen of them might achieve remarkable 
fuel economy; no great matter if the eighteenth and nineteenth don't. And they 
would achieve that fuel economy the right way, that is, pretty much by accident.

Regards

Dawie







From: Aleksander Kac [EMAIL PROTECTED]
To: sustainablelorgbiofuel@sustainablelists.org 
sustainablelorgbiofuel@sustainablelists.org
Sent: Fri, 27 May, 2011 8:27:01
Subject: Re: [Biofuel] Fwd: New Engine 100 MPG

Well, I need to say something here. Why all these inventions?

You can buy a whole production car capable of 100 mpg today. 

The world record in fuel economy set by Gerhardt Plattner with this car is 
actually way better: 107 mpg from austria to denmark and back, 2007 km on 45 
litres of diesel, using autobahns, climbing mountain highway passes etc. 
http://carscoop.blogspot.com/2011/05/gerhard-plattner-does-it-again-drives.html 
(7% better fuel economy at these low values is no easy job in real world 
traffic)

It's not a hybrid.

It's got aircon and everything a modern car should have. 

It hasn't got an exotic engine, the engine is a common rail 1.2 litre tdi.

It's even almost half reasonably priced.

And it's not even a kei or very small car : Skoda Fabia Greenline II 
http://www.buyacar.co.uk/cars/skoda/skoda_fabia/review_skoda_fabia_greenline_ii_4637.jhtml
 

Cheers, Aleks


-Original Message-
From: [EMAIL PROTECTED] 
[mailto:[EMAIL PROTECTED]] On Behalf Of Lee 
Dyson
Sent: Friday, May 27, 2011 3:13 AM
To: sustainablelorgbiofuel@sustainablelists.org
Subject: [Biofuel] Fwd: New Engine 100 MPG

Hello All,

was sent this, looks interesting. Looks like if it can be vaporised and 
combustible you can run this engine on it, diesel also. Looks like the idea has 
been around since at least the 1950's

Lee


Begin forwarded message:

 Subject: FW: New Engine 100 MPG
 
  
  
  
 
 
 New Engine! VEY Cool!  
 
 Here is another German Invention! 
 
 Oh, and by the way! Let’s watch this invention closely, so we can observe 
 the 
MANOEUVERING  of the Oil Companies, Lawyers, Politicians, Unions and Wall 
Street, to cut this invention off at the knees, delay  and/or even stop 
it’s 
development. They will all contribute to stopping

Re: [Biofuel] I sussed it out

2011-03-09 Thread Aleksander Kac
Ahoy!
Hi Aleks!

  hope all is well with you Keith

Got more problems than a cat with 20 kittens and only two tits. :-)
Changing countries has never been so complicated before. Nearly there
though - I'll go out in an hour or so and dash about the place again,
and that should be it, then I can take it easy for a while. Yes,
all's well.

Way cool! How is Cape Town?

Warm! (It's snowing again today in Kyoto.)

I believe, the summer is ending?

Not quite yet. There've been a couple of foggy mornings, cooler, and 
some wind, but not really - I think the wind really starts blowing in 
April.

Looking forvard to a nice
fall, eh.

Indeed I am. And you to a nice spring? Does Slovenia have a 
Mediterranean climate?

Partly. The terrain rises considerably from the Adriatic sea 
inlands. The effect can be felt some 60-70 km inwards. Not where
I live. But in favourable weather conditions, the fall can have
prolonged periods of mild climate even past november 1st. 2009
was such a year, my sweatheart was sunbathing untill mid december,
with outside day temperatures reaching 17-18°C at the end of november.
More influental even are mediterranean cyclons. We can definitely
feel those. November 28th 2010 we got a foot of snow, and for
a week every other day yielded another foot till the cyclone 
disintegrated.

BTW, I got my sweetheart a kei car yesterday!

Good! Now you'll want one for yourself. :-)

Well. As with every story men tell about the wimens, my previous
statement is only a half truth.
The fact is, I bought the car for myself. I'm getting rid of the
Fat Girl (Toyota LC 80 series), and I wanted a small car for my daily
commute to work. I didn't want just any car, I wanted one with a small
and efficient engine. And it had to be reasonably priced, in a
reasonable/fixable condition. The latter I don't know yet, you see. I
have driven it for 30 minutes only ... Just as I got home, her response
was: Just in time. My Kia has a shot bearing and the CV joint is making
strange noises. Hand them [car keys] over.
So, you see, my driving tests are of a rather limited time. And my nose
is still somewhat sagged.


It's a Subaru VIVIO, 17 years old.
A little gem of an engine: only 660 cc and multipoint injection. 
It's a 4WD, works like
magic on snow. A full fuel tank is les than 25 litres, which will 
take you 500 kilometers
far. I have been an utter idiot for not getting one of these a while 
ago. This car
is surprisingly roomy for its rather small size, and quite 
comfortable. Least of all,
you can get a new winter tire for it for les than 30 euros. On the 
side of the registration
and insurance costs: only a 50 cc moped is cheaper per year. 
Anyways, way cheap, only sipping
fuel and a quite comfortable ride. And sadly the only kei car 
available in continental Europe
AFAIK. Pitty they stopped making them in '95.

I think they still make them.

Subaru stopped making them in '97, although old stock was inported to the EU
until '99. But no new ones were imported after '95 to Slovenia. As there engines
are EURO 3, they can not be imported, even from other EU countries. And even
if that were possible, ther are only 40 on sale in the whole EU today, at
ridicoulous prices.

Pics:
http://www.google.com/images?q=Subaru+VIVIOum=1ie=UTF-8source=univsa=Xei=7mR3TcC6FYKEvgO1sYHcBQved=0CCsQsAQ

Kei cars:
http://en.wikipedia.org/wiki/Kei_cars

There are dealers that export second-hand kei trucks all over the 
world, including to Europe I think, and probably kei cars too, not 
sure.

Not to this little country they are not! We are (as can be seen on
many, many, way too many other occasions) saintlier as Pope Ratzy.
It can be seen on Google Earth, search for Slovenia. You can observe
a faint golden aura along the borders to Austria, Italy, Hungary and
Croatia. For a similar visual effect search up The City of Vatican and,
during summer, The Apostolic Palace of Castel Gandolfo. A nice little
aura, but ours is stronger ...

I'd like to get another kei truck. They should be available here. 
I'll check it out.

Cheers for now - all best

Good luck! All the best,
Aleks

Keith

Cheers, Aleks


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Re: [Biofuel] I sussed it out

2011-03-08 Thread Aleksander Kac
snipped
hope all is well with you Keith

Got more problems than a cat with 20 kittens and only two tits. :-) 
Changing countries has never been so complicated before. Nearly there 
though - I'll go out in an hour or so and dash about the place again, 
and that should be it, then I can take it easy for a while. Yes, 
all's well.

Way cool! How is Cape Town? I believe, the summer is ending? Looking forvard to 
a nice
fall, eh. 

BTW, I got my sweetheart a kei car yesterday! It's a Subaru VIVIO, 17 years old.
A little gem of an engine: only 660 cc and multipoint injection. It's a 4WD, 
works like
magic on snow. A full fuel tank is les than 25 litres, which will take you 500 
kilometers
far. I have been an utter idiot for not getting one of these a while ago. This 
car
is surprisingly roomy for its rather small size, and quite comfortable. Least 
of all,
you can get a new winter tire for it for les than 30 euros. On the side of the 
registration
and insurance costs: only a 50 cc moped is cheaper per year. Anyways, way 
cheap, only sipping
fuel and a quite comfortable ride. And sadly the only kei car available in 
continental Europe
AFAIK. Pitty they stopped making them in '95.

Cheers, Aleks

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Re: [Biofuel] Paying for fire response service (was Alabama Town's Failed Pension..)

2010-12-31 Thread Aleksander Kac
{Small Snip}
Proceeding from the assumption that a fire-response service is a 
rational response to the threat of structure fires and related hazards 
to residents, it becomes necessary to fund that service.  How to go 
about it, on a sustainable basis?  Let's suppose a fire house includes 3 
major trucks (pumper, ladder, utility/rescue), has a staff of roughly 30 
(to support 7x24 response) and can reasonably service a radius of 8 km, 
with up to 8,000 structures.  (I'm completely guessing here, but a quick 
search turned up a ratio of 1.5 firefighters per 1,000 population for 
the U.S., and one engine company per 15,000 to 20,000 population).  A 
building, massive supporting infrastructure (e.g., water mains), 3 
expensive pieces of rolling stock, and 30 full-time salaries plus 
benefits, and administrative overhead.  As a wild guess, let's say that 
represents an annual expenditure of $4,000,000.  That's about $500 a 
household per year.  That figure is inflated as it includes more than 
fire services (such full-time services include domestic water supply, 
emergency health response and rescue capabilities).  Moving to the 
volunteer model, the annual cost is likely to be more in the range of 
$150,000 a year (assuming the trucks and building have a service life of 
30 years).  Let's assume the $75 annual fee from the story.  It takes 
2,000 subscribers to support that cost.  For a rural volunteer fire 
department, that seems in the ballpark to me.

Let's suppose we get 10 call-outs a year for structure fires in the 
rural situation (1 per 200 structures per year, which seems high to me). 
  If we only charge those whose structures actually require a call-out 
(user-pay to the extreme), the cost to them will be $15,000 per 
call-out.  (At that price, I expect some will decline the service when 
it arrives, and will take higher personal risks trying to fight the fire 
themselves.)  If they are not home to approve the charges, it is allowed 
to burn down without intervention.  Seems less than optimal to me.

Or we can move to the community pays model.  Everybody pays $75 a year, 
and no questions about fighting the fire, whether anybody is home or 
not.  Either via a tax, a subscription or whatever.  Of course, someone 
will object to this tax or fee, as they can better spend it on 15 
Starbucks coffees (or whatever).

So, the inevitable result is that the number of funders will decrease, 
likely slowly at first (the freeloader model).  But after a couple of 
years, the volunteers will get tired of going door to door begging for 
renewals.  Some folks will figure, I didn't need the fire department for 
the past few years, so why not save the $75.  Eventually, half the 
people don't subscribe, and the cost goes up to $150 a year for those 
that do.  Somebody has a fire that is not a subscriber, and the 
volunteer fire department puts out their fire anyway because they agree 
to accept payment on the spot of whatever the going rate is.  Word gets 
out that this happened.  Next year, nobody pays for a subscription, 
figuring they can pay a small amount in the event they ever need the 
service.  The volunteer department goes broke, as they can't make the 
loan payments on the firehouse, the trucks or the fuel bill.  (An 
enterprising arsonist then wipes out all the structures in the 
community.)  Also seems less than optimal.

So, if you are the chief official for the volunteer fire service, and 
you can't get funded via the tax base, how do you propose to find the 
revenue to support the minimum required operating costs?  Labour is 
already free or very close to it.  Probably not paying municipal taxes 
on the firehouse.  But there are real costs associated with having the 
building and equipment.

Personally, I think I would end up where this situation did.  I would 
elect to try to keep the service operational, hoping residents would 
have the sense to support it.  However, if not supported by taxes or 
some form of mandatory payment, I expect with time someone will choose 
not to pay.  Eventually comes the tough decision.  If they have a fire, 
and have not paid to support the (volunteer) service, do you provide the 
service anyway (which will eventually lead to the end of the service 
being viable for the whole community), or do you make a very harsh 
example 'pour encourager les autres'?

I'm curious, and looking for responses from this list.

If you are in the position of the chief official, how do you fund 
desirable, low rate of incidence, high consequences, prevention 
operations when there are no mandatory mechanisms available?

If you are in the position of a homeowner, and the funding mechanism is 
not mandatory, do you pay the annual subscription?  Is there a price 
point where you will choose not to pay?  What would motivate you to pay 
or not pay if the amount is small?

Darryl
{Big Snip}

How it functions in Europe, particularly Slovenia where I live, is like this:
pro and voluntary 

Re: [Biofuel] greenhouse farming

2010-12-01 Thread Aleksander Kac
http://www.fourseasonfarm.com/resources/index.html#greenhouses

This chap wrote a book. I ordered it last week, but I can't comment as amazon 
says it'll take another
two weeks to get here. I just built a hybrid (well, bigger than a cold frame 
and not a full size
greenhouse) last weekend. It will be unheated. I've looked up some information 
on the internet
regarding greenhouses, as my sweatheart has a strong interest in veggie 
gardening in winter and the
accompanied financial benefits, specially during winter. There seem to be two 
schools of thought:
using heated greenhouses and unheated greenhouses. 
For starters I made this small thing, 2,5 by 1,5 metres, about 1,5 metres tall, 
both roofs sloping.
Sadly its burried under one and a half feet of snow today ... winter came in 
early this year. Next year I'm
planning a bigger, walk in greenhouse. It'll be unheated, as we don't aspire to 
tomatoes in winter.
This year we got salad greens in the hybrid. I'm quite confident it'll work 
fine, as in the
previos winter our winter lettuce survided quite nicely under more than 2 feet 
of snow just
covered with gardening fabric. But that was just surviving, not growing. We're 
hoping for more with this
new setup.

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[Biofuel] Status (biofuel@wwia.org)

2005-02-13 Thread aleksander . kac


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Re: [Biofuel] paper chromatography

2005-01-28 Thread aleksander . kac

Liz,

I have a student who is studying biodiesel as his chemistry project. We 
have 
located a method of thin Layer Chromatography for the quality analysis but 

he also wants to try paper chromatography. We ahve tried some solvents but 

they only work for the glycerides layer. Does anyone have a method that 
works for paper chromatography.

To analyze what? MG, DG and TG content? I don't think paper chrom' will 
work,
because the stains will smear too much on paper. PC is more adapt for ion
detection, sodium, phosphate ... at least what I did in high school.


Cheers, Aleks


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Re: [Biofuel] Global Warming Approaching Point of No Return, Warns Leading Climate Expert

2005-01-27 Thread aleksander . kac

 I believe one degree is the
 difference between water or ice. 

Nope. One degre is the difference between 1 degree and 0 degree
water. The difference between the solid and liquid state of matter
is several times bigger. Ice has a lot more energy trapped inside
then just the deltaT of 1.
But global warming is, AFAIK, measured by air T (mean values over
a period, dunno what period). 1 degree of deltaT of air is very hard
to feel in still air.
BTW, I feel the effects of global warming. We haven't got any snow 
this winter. It's not a lot warmer on average, but we had few days in
january reaching about 10 degC (on the + side). In a country that hosts
4 ski WC events and several nordic events ... The most recent woman's
slalom and Gslalom races in Maribor were organized entirely on 
artificially
made snow. Both tracks were soaked with rain a couple of days before 
the race, making the whole effort almost melt away.

Cheers, Aleks


 Mick,
 Can you feel the difference of 1 degree increase on average? 
 Andy

  As I sit here freezing, in temperatures colder than normal, I have a 
hard
  time swallowing the global warming concept.
  Mick


snip
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Re: [Biofuel] Euro warrantees - was Re: 2nd batch: looks better...

2005-01-26 Thread aleksander . kac

snip

The use of biofuel conforming to EN14214 as a blend component at up 
to 5% is accepted by the European vehicle manufacturers and their 
guarantees are honoured, providing the finished fuel remains in 
conformity with the diesel fuel standard EN 590. A blend component 
exceeding this percentage will no long be in conformity with EN 590, 
and any vehicle guarantees are then a matter for individual 
companies. As the major injection equipment manufacturers refuse to 
guarantee their systems beyond 5% biodiesel (this includes 100% 
biodiesel), many vehicle manufacturers may be reluctant to honour 
guarantees for such fuels. Therefore it is important to obtain the 
advice of local vehicle manufacturers and importers on this point, 
and to label filling station distributor pumps clearly so the 
customer knows what fuel he is buying.

This basically concurs with my experiences with the HDi PSA
diesels and neat bio. Although nothing broke, the OBD shut the
engine down. 

snip
I've just heard that the Peugeot HDi eqipped cars have an inline
fuel sensor. The owner I spoke to said, that this was to prevent the
use of colored fuel/heating oil in the engine by shutting the fuel
valve and preventing the destruction of the cat exhaust with sulphur 
contained in heating oil. 
Any on list owners know about this? I phoned the nearest garage
to find out if this is true, but the guy on the other side wanted
to know the cars VIN, which I couldn't provide, duh.

Cheers, Aleks

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Re: [Biofuel] 2nd batch: looks better, but still some questions

2005-01-24 Thread aleksander . kac

snip
Aleks said this in a message a few months ago:

Opel in his new DI engines forbidds use of bio in any form. New
VW models do not tolerate biodiesel also (any form, not even B5) in
someengines.
We have had a LC Toyota (100 series) with a totally broken IP after 
only6.000
km on neat bio (costly repair, 12.000 US).We've been in the EU for a 
very short
time (meaning biofuels are legal now
in Slovenija) and have had serious damage on  engines. I could go on 
andon:BMW
- no good OBD shuts the engine down, Peugeot - will stop engine,beacuse
antiPMchemical injected in the exhaust is not compatible with neat 
bio,Mercedes
- OBD gets all fuzzy, can't recognize the neat bio as a fuel .
http://infoarchive.net/sgroup/BIOFUEL/38648/

And Chuck said this:

I've used b10, b20, b30, b50,b80  all approximate percentages and with 
zero
problems in my 96 passat tdi.  If you go to www.tdiclub.com you will find
many many tdi owners (older and new vehicles) using b100 for years with 
no
problems.
http://infoarchive.net/sgroup/BIOFUEL/38766/

It would be nice to have some confirmation of this one way or the other.


Latest:
Sorry, Mat and I had to stop experimenting with other people's cars. 
No, seriously. :-).

Mat's brother is still mad, because of the fuel lift pump broke in his VW
Polo tdi. Uses neat dino now, engine's fine.

Most of the users, including me, stepped back a little, using blends.

The repaired Toy runs fine on 30% bio 70% dino for 6000 km now.

I drive my Jeep on a 50% bio blend, fine for the moment, after about 4000 
km
post injection system rebuild.

The owner of the Merc with the cdi engine gave up. Drives on dino, no 
trouble
since.

Mat's sister with the Renault Clio Dci gave up, drives on neat dino, no
trouble since.

On the other hand, the oil delivery guy drives his ~95 (not sure, the 
old shape) 
passat on a blend of bio and WVO for several years now, absolutely no 
problems. 
And it's not a kit car, all is regular, TDI pump, injectors, no other 
fuel heating ...

Seems that older TDI engines (pre 2000) are particularly adapted to 
biodiesel.
Also older mercedes diesel and turbodiesel engines (Mat went to see/buy 
the
Biocar guy/kit last friday), got a lift back to the trainstation from a 
guy
with a Merc 300 turbodiesel, older model, with 200.000 km on the engine
on neat rapeoil w/Biocar kit. No problem whatsoever.

No rule of thumb here. Read instructions booklet prior to neat biodiesel
use. If in doubt, start with blends. In case of any trouble, blame the
gas station (EU, where diesel is already blended with bio). It works some-
times, especially if workshop is not familiar with biodiesel.
Sometimes it's better not mention it at all. You might get stuff fixed 
for free, under warranty.

Cheers, Aleks




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Re: [Biofuel] 2nd batch: looks better, but still some questions

2005-01-24 Thread aleksander . kac

Hakan,

I am confused, in front of me I have the sales literature and
specs of VW Lupo 3L in Spanish.

It is clearly stated that the VW Lupo 3L is RME compatible
clean or in any mix and that is biodiesel on Rape seed.

I do not have the latest literature for other VW models, but
have a remembrance that they say the same. When I get
to it, I will get the Golf TDI, since my wife will change her
8 years old one.

snip

Only the Lupo. Tested, 60.000 km by my friend Mat. Read the 
instruction booklet of the v6 tdi Passat, or 2004 Touran.
These, if sold in my country, state: no biodiesel allowed.
The Lupo is a pdi (pumpe-dse), the newer are a sort of
common rail engines if I got it right. If this is correct,
I can understand why they don't recomend the use of other
fuels. And VW's research is oriented towards Sundiesel anyway.

I'd keep the old tdi. Why's your wife changing it? '96 is
a nice vintage for tdi engines. I know loads of owners
of about this age of cars. All are very happy with them.

Cheers, Aleks


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Re: [Biofuel] Keith? Query about WVO refining and Glycerin Purifying

2005-01-21 Thread aleksander . kac

When I start my homebrew biodiesel refining with that
150 lbs of WVO I've been discussing, I would to
circulate the byproduct crude glycerin into
distillation and purify it to about 90% purity or
better. The reason is that I would like to recycle
and send the glyerin to a local natural soap bar
manufacture nearby.   Am I taking this too far? 

You are not meaning boling the glycerine and then
condensing it, are you? this can't be done at atmos-
pheric pressure. Glycerine will crak just a few degC
below atmospheric bpT, so glyc distillation must be
done under lower than atmospheric pressure.
OTOH, distilling away the methanol is reasonable, as
for the low energy input and a valuable fossil chemical
recovery.

Cheers, Aleks

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Re: [Biofuel] Plastic Tanks for Biodiesel

2005-01-21 Thread aleksander . kac

snip
I've found two types of containers that I'd like to use for storage, or
washing / bubbling...  Both contained silicon...  One is a sealed top 55
gal drum with two 2 bungs on top, the other is a 275 gal cube with a
metal cage around it.  It has a 2 valve at the bottom, and a 6 bung /
cover on top.

I don't yet know what type of plastic they are... I'll go see them
tomorrow or Sat.

The cube is what we call an intermediate bulk container or IBC and
it will sweat, but a friend of mine uses one for bio storage for about
2 years now and the container is still fine. OTOH, in contact with
bio, most plastic containers will sweat and still do fine.

What can I use to get the residue silicone out?  Is this a good idea at
all?

Silicone-what?

What types of plastics are OK to use for these purposes?  Which are not?

Look it up at journey to forever. I use white PVC.

Cheers, Aleks

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Re: [Biofuel] Metric measurements

2005-01-21 Thread aleksander . kac

Luc,

snip
The only place metric fails is in micro measurements where 1000's of an 
inch 
is required, but that is neither here nor there for the average person. 

One 1000th of an inch is 0.0254 milimeter. Rather coarse for machining ...
We have milimeters (1/1000th of a meter) and micrometers (1/1000th of a 
mm).
So, what's not covered by metric? 
You can go smaller still, we've got Angstroms.

1000's of an inch are regularly used by the average rodbuilder. But these 
are
easily transformed into metric units.


Cheers, Aleks



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Re: patents, biotech and cellulosic ethanol was RE: [Biofuel] ethanol from wood

2005-01-20 Thread aleksander . kac

Dave,
snip

As it has been
explained to me, it is a matter of getting the enzymes cheap enough to
make it cost effective--one cannot make the enzymes themselves, they are
a product of biotech. Am I mistaken? What are the enzymes and where do
they come from?

snip
Enzymes are a product of nature, i.e. microorganisms, such as bacteria
fungi, plants, human and animal internal organs, et al. Enzymes are rather 

large molecules of proteinic origin, capable of doing a simple task, 
given the right conditions (temperature, pH). 
They can splice complex carbohydrates to simpler (mashing, for example) 
sugars that yeast can digest to make alcohol, for instance. 
Mankind has been utilizing these little friends in alcohol beverage 
making, cheesemaking, meat conservation, leather, breads, honey for 
ages... 
Fungi are one example of enzymatic cellulosic material breakdown to make 
simpler carbohydrates for food.

Biotech came into the game later, to simplify and make cheaper and faster 
nature's processess. Try the difference between a small brewery pub beer
and industrial beer. Biotech made it possible, for example to simplify
beer fermentation and shorten lagering, and all the complex nuances of 
the beer's taste are gone. But biotech research is expensive and all the
richness of beer can still be tasted in small brewpubs.
Sorry, if I talk a lot of beer, but I'm a homebrewer and use malt's
own enzymes a lot, and nothing in my brew is biotech. For now, at least 
untill GMO barley creeps into Europe.

Cheers, Aleks
 


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[Biofuel] hydroxide - what are you using?

2005-01-19 Thread aleksander . kac

Biodiesel homebrewers,

what hydroxide are you using, sodium or potassium?
If you have switched from one to another, are the results any better?
Anyone ethyl esters yet - single stage, two stage, mistery process?

Just wondering, I switched from sodium to potassium hydroxide.
The wash seems a little easier. 
Ethyl esters - no conversion at all with potassium ethoxide (99% ethanol)
IPA esters with potassium methoxide as catalyst - no conversion, turned 
everything solid

Cheers,  Aleks
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Re: [Biofuel] Efficiency and expanded possibilities.

2005-01-14 Thread aleksander . kac

I'm sure there is a catalytic process to do this. One thing I know of is 
that methane can be conveted to syngas, which can then be converted to 
methanol through the critical process, or through a zinc-slurry process:
snip

The meth sold in my country is made exclusively by a catalytic conversion 
of
natural gas. 
I really don't know why bother to make fuel methanol, if you can have 
excellent CNG cars, range and all included. Look up the new Merc C-class 
CNG car, or the Fiat Multipla Bifuel. And if you drive on both fuels, the 
range almost doubles in comparison to a single fuel car. Then you move on
to partially cleaned biogas and compress it for use in the same equipment.
Although, here at work we have a big powerplant (3.3 megawatt) on biogas
containing roughly 48% methane, the rest CO2 and other gasses (it's land-
fill gas), we use it in our GEJenbacher gensets unpurified, just filtered.
Works fine, although silicon deposits are a major pain for the moment.
We just opened one genset (1 megawatt, V20 spark ignition engine), and 
cleaned
the combustion chambers, it's done with a special soak and rinse. But it
took the genny 15.000 hours to build up deposits thick enough to cause 
problems. It has be cleaned, mind you, because the compression has changed
and the engine does not fire propperly anymore. And also the LeaNOx firing
electronics goes bezerk.

Cheers, Aleks




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Re: [Biofuel] Efficiency and expanded possibilities.

2005-01-13 Thread aleksander . kac

Arttu, 
snip
Could methane, easily produced from rotting biomass, be used to make 
propane?  It's easier and safer to handle than methane in transportation 
use, that's why ask.  They do it in making polymers, but that's with 
extremely long hydrocarbon-chains.

Rotting biomass produces a mix of gasses, rather difficult to separate
and clean up the methane to a grade capable of polymerization. But it is
done, as methane from natural gas/fermentation is used not to make propane 

but other stuff, mainly methanol. Propane's main source are the world's 
wells of oil and gas. Much cheaper than synthesized propane (still). 

There's also no real reason why not to use methane as road vehicle fuel. 
If it's hard to liquefy, use it compressed, the technology, is here, 
the Swedes and Italians are doing it for ages. Along with half of Asia ... 

Google compogas for a package example.

Cheers, Aleks



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Re: [Biofuel] China VW Competition - Golf ECO.Power

2005-01-12 Thread aleksander . kac

Todd,

You're right Alex, at least in part.

 Let's not just linch all other auto makers than Volkswagen ...
 There's a lot going on outside the USofA.

I should have qualified that, at least in part, leaning more heavily on 
American auto manufacturers than most others. Then again, its rather 
difficult to give accolades to the likes of Volvo, Daimler, Benz, etc. 
because they make a few small cars, when on the flip side they're as party 

and parcel to the Super Size It syndrome that has swept the industry. 
Even 
VW participates in it with their Tourag.

The touareg also comes with a nifty 2.5 turbodiesel known from the VW
van range. It will easy last you 1/2 a million of km and doesn't really 
need
good roads. The touareg is rather compact by american standards. 
snip

Pats on the back come when they've all got lines of affordable production 
vehicles for the masses that achieve a realistic 60 mpg and better. Please 

note the word affordable, which not only includes a vehicle costing 
considerably less than a home mortgage, but includes long-term maintenance 

as well, not paper-delicate technologies that will only last 20 years if 
kept in a clean room at Intel or Sony and bankrupt an owner over the same 
period if not.

Affordable? But you already have them in Am'rika (along with very 
affordable fuel)! 
Just for example, a Toy Prius will cost You roughly half of that what it 
costs me in Slovenija (I can't afford it anyway, there are only 2 here). 
I can't immagine the ammount of money it costs in Denmark. Niels, how much 
?
Our countries really don't encourage us citizens buying cars.
But then again, housing is more expensive still in my country, no fear the 

cost of a car will come even close to a home mortgage. With my meager pay 
savings, I could buy a condo in Florida, and noway here in Slovenija.
You already have very affordable things, I suspect that a car's price in 
the US 
wouldn't even cover European prices for energy, raw materials and labour.
Europeans can't have cheaper cars, but americans demand affordable ...
Heck, I drive an american car, made in Toledo, Ohio. 
It's cheaper to buy than a european or japanese car ... a lot.

Even for those manufacturers that offer a larger selection of small 
vehicles, their's not much to be proud of. Fifty plus mpg has been around 
now for 25 years. What pride is there to be taken in marketing cars that 
get 
less? They may be cute. They may be cuddly. But they can't be called 
inventive simply because they offer a cleverly disguised CD player and 
GPS 
for the map challenged.

How many small cars does one need to choose from? There's plenty of them, 
with good mileage.
AFAIK, a cd player doesn't hurt. Neither does GPS, if you drive, for 
example
in an Italian town you've never been before. Saves fuel and sheet metal. 
The inventiveness stays with safety in small cars, there's been terriffic 
progress in the last 25 years. Look up the EuroNCAP reports for Renault's
small cars. All got five stars, all you can get. And yes, they are 
inventive.

Cheers, Aleks



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Re: [Biofuel] first time post- first batch

2005-01-11 Thread aleksander . kac

Mark,
you're not serious making a first batch of 100 gal, are you?
Have you made any trial batches?
How'd it go?
How do you wanna heat a 100 gal of WVO?


Cheers, Aleks

Hello all.My name is Mark Rose.I live in Yarmouth Nova Scotia,Canada.I am 
new to the list and have been preparing for some time for my first batch 
of biodiesel.
I have a decent supply of waste fat and have approx 130 gallons ready to 
process.The processor is a 250 gallon stainless milk tank with built in 
variable speed agitator.We are about two weeks from our first mix of 100 
gallons.
I'm looking for a little tech advice and hoping also to find biodieselers 
in eastern Canada to talk to about this process.I have been doing alot of 
reading (this list is great!) online and have learned much.(although 
nearly not enough)
I'm unsure as to how long I should mix my first batch (100 gal) and if the 
agitator speed is crucially important.The forward speed of my tank mixer 
is not as fast as the reverse speed (wash cycle).Should I mix longer than 
two hours? Should I let it settle longer than 24 before pouring off the 
glycerin?(should still be warm enough to pour-fully insulated tank)
Thanks in advance for your interest.Looking forward to your 
reply..Mark Rose



 
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Re: [Biofuel] China VW Competition - Golf ECO.Power

2005-01-11 Thread aleksander . kac

snip 
 That's ~62 mpg, ten more miles per gallon than the 1.6 liter, four 
 cylinder diesel of Rabbit and mid 1980's Golf fame.
 
 Don't know if a 20% improvement in 20-25 years is all that great. But at 

 least it's an improvement, providing it ever becomes a production 
 vehicle, especially when all the other auto makers are moving in the 
 opposite direction.
 
 Todd Swearingen

What all the other auto makers? Don't forget Peugeot, Renault, Opel,
Skoda, Seat, Audi, yeah, even Saab, Volvo, BMW, Mecedes-Benz, and there
are again Toyota, Honda, Fiat, Alfa Romeo, Ford, Hyunday, Mazda, 
Suzuki ... to name but a few, building really safe, good, comfortable 
and economic diesel cars.

I believe you meant the minority of auto makers on the other side of
the Atlantic.
Let's not just linch all other auto makers than Volkswagen ...
There's a lot going on outside the USofA.

Cheers, Aleks

snip




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Re: [Biofuel] New Car

2004-12-29 Thread aleksander . kac

While I know some of you think that anyone who buys a new car is nuts, 
some 
of us just don't have the time to play back yard mechanic.  I learned long 

ago that hiring someone to do the kind of work that needs to be done with 
an older car means bankruptcy.  The old adage of if you want it done right 

do it yourself is really true of keeping cars running.  Building a 
sustainable farm takes all my time.

That said, My Dear Husband would like to know what the opinion of the 2005 

Volkswagon Golf TDI is?  He is buying me one this Friday and we hope to 
run 
biodiesel in it after it is off warranty.

Kim,

Don't do it. We've had trouble over here in Europe trying to run 2004 
wagens 
on neat bio with horrible results. Of course my friend running this car 
did
not tell it at the shop it was running on bio, so vw fixed the thing for 
free.
The change included injectors, pump and OBD. 
Strangely, the instruction booklet doesn't mention any big no-no regarding 
fuel,
as opposed to the V6 tdi passat, in which it is strictly forbidden to 
drive
on biodiesel ...
The biodiesel is within EU standars, except present water level (was 1000 
mg/litre).
The 04 engine was built to run not on biodiesel but on sunfuel - 
synthetic
fuel from biomass, a project VW and Mercedes Benz joined with german 
scientists.

Buy an earlier model. And even with that one: we had a broken fuel lift 
pump 
on a wv polo tdi '03, reason unknown, but it happened while driving on 
neat bio.
Owner paid rather large sum for repair, the car was just a month out of 
warranty.
You should look into 2000 or older models; my oil supplier drives a '96 
passat
tdi on a 50% blend of WVO and biodiesel during summer and 20% dino in bio 
in 
winter - hasn't missed a firing in 4 years now - I know, because he never 
failed
a delivery :-).

Cheers, Aleks

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Re: [Biofuel] Happy Happy!

2004-12-24 Thread aleksander . kac

YEP!
Hic ..  #..*.* .*^  ^ :o)

Cheers, ...^, hic
Aleks ...





Keith Addison [EMAIL PROTECTED]
Sent by: [EMAIL PROTECTED]
24.12.2004 05:49
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Subject:[Biofuel] Happy Happy!


Here's wishing you a Merry Christmas, for the Christians, a happy 
solstice for the pagans, Happy Happy! for all of them and everyone 
else too, and Happy Humbug for Todd! LOL! And may we all have a 
happy, healthy, prosperous and productive 2005, peace and goodwill to 
all mankind, and to all womankind too - thanks for holding up half 
the sky! Thanks to everyone for everything.

Keith and Midori
Journey to Forever
KYOTO Pref., Japan
http://journeytoforever.org/

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RE: [Biofuel] it looks like soapy milk facts

2004-12-20 Thread aleksander . kac

Dermot,

transfer esters to a separate washing vessel. That's why samples a and b 
wash fine and the the
batch washed in the reactor doesn't. Aparently some of the glycerinuous 
phase clings to the surface
and, as mentioned by Luc, to the plumbing. I also wash my biodiesel 
reactor after each batch to ensure
that nothing of the glyc phase rests int it.

Cheers, Aleks

I had the same experience with pump washing. It just doesn't work. It
appears to be too violent even if your reaction is perfect. The washing 
has
to be gentle. It would seem to me that the initial wash has got to be 
quite
gentle even with well made biodiesel and that subsequent washes can then 
be
as violent as you like and you will still get good separation.

Regards
Dermot

Here's my rather lengthy query to the group on this subject last summer.

I would appreciate any suggestions or help from people who have experience
with washing biodiesel by using a pump. I have tried unsuccessfully to do 
it
and have ended up with about 50% mayonnaise.

Here's what I did:

I heated the used oil, which was over a year old, to 130 degrees 
centigrade
for over an hour to make sure there was no water present. I then took a
sample and allowed it to cool before titrating it.
I got a titration reading of around 2.7. I did the titration three times 
and
it was always around this figure. I added 4 grams to this figure and made 
a
few one litre test batches mixing 6.7 grams of lye to the methanol.  I 
used
22% methanol (220 ml) in order to ensure a complete reaction.

I made sure that the lye mixed completely with the methanol.  When I mixed
the methoxide with the wvo I got a very good separation and everything
seemed fine.
I then siphoned off the top layer of biodiesel and added an equal amount 
of
water to it.  I shook it about 15 times and I got a good separation within
seconds and after maybe an hour I had almost completely clean biodiesel on
top and white coloured water underneath. There was no middle layer.  After 
a
few days I siphoned off the washed biodiesel and washed it a few more 
times.
Same result, perfect separation after a few hours and it separated quite
quickly initially. I will call this sample A.

I then took another litre sample of the unwashed biodiesel and ran it
through the whole process again to see if I had a complete reaction. I
titrated it but it immediately turned purple so I used the figure of 4 
grams
of lye to mix with the 220 ml of methanol. I mixed the methoxide and
biodiesel thoroughly and was pleased to see that I got no separation,
indicating that there had been a complete reaction the first time.  I 
washed
it again and got good separation very quickly. So far so good.

I felt confident enough now to do my first large batch in my processor. By
large I mean 50 litres.
My processor is an old discarded plastic tractor mounted spray tank. It is
rectangular in shape but has a slight cone shaped bottom. I use a pump 
mixer
to pump the contents from the bottom of the tank to the top where I have a
three quarter inch pipe connected to a wand which has about 40 small holes
drilled to enable good mixing. This wand is submerged near he bottom of 
the
tank. The pump is a sliding vane type and is powered by a 2 horsepower 
motor
running at 1750 rpm.

I heated the wvo in a separate heater tank using a butane burner and 
brought
it up to 65 degrees centigrade. I then transferred it by pump to the
reaction vessel and turned on my pump. I then gradually added the 
methoxide
mixture (at room temp) to the pump inlet and mixed away for about an hour 
to
ensure good mixing. I have the reactor tank well insulated so the
temperature didn't drop below 55 degrees centigrade during the reaction 
time
of one hour.

Next morning I saw that everything went very well.  I had good separation
and the glycerine had fallen to the bottom and was liquid, just as the 
trial
batches had been, so it was easy to draw off the glycerine.
I drew off a pint of biodiesel and did the wash test by shaking it
vigorously for about ten shakes. I got good separation almost immediately
and it cleared to lovely biodiesel and milky water in a few minutes. I
drained off the water and let the biodiesel air dry for a few days when it
turned the nice clear straw yellow. Call this sample B.

I was happy that I had made good biodiesel so I decided to pump wash the
biodiesel in the reaction vessel. I added to the approximately 50 litres 
of
biodiesel about 30 litres of water and circulated it through the processor
for about half an hour. The result was mayonnaise. I let it settle for a 
day
and then drained off the milky white water. The only problem was that 
before
long I realised that most of the mixture was at this stage mayonnaise so I
stopped draining off the lower layer.  What was left of the mixture(about 
20
litres) I put into a plastic carboy and went on holidays for a week. When 
I
came back I had three layers; the top 30 percent was biodiesel, a large
middle layer of 

Re: [Biofuel] Questions regarding biodiesel processing

2004-12-16 Thread aleksander . kac

Rob,

I have made small scale and feel able to continue to make small scale
batches.

Move to actual fuel production with straight base methods. Drive on
the fuel for a while. Most skills you'll gain will help you in any
type of process you should use; the only thing is, that the two stage
can play you some tricks - troubleshooting will be in order then.
Troubleshooting, while helping you out, is a waste of energy and 
precious chemicals.

I do have three reliable ongoing sources for oil, but have not titrated.
My impression based on reading Aleks' fool proof method is that the
acid-base two stage process is accomodating of all potential oils - is
that not correct? 

The two stage a/b will make fuel out of many different oil sources, but 
I'm
of course not claiming anything goes 100%. But it will do a thing for you
no straight base will do: it enhances your yield. Conservation of 
resources
is crucial, even for biodiesel, especially since bio is not 100% 
renewable.
Not to mention the extra % of yield will drammatically lower the price
of your fuel (that's what I was after - should have named it differently,
I relize that).

He does also mention arriving at an empirical 3.25 g lye
per litre, so perhaps the pH of the oil does matter to some extent?

Input oil quality:
It does matter, as in anything you might cook : 
You can easily make pie out of dogshit, it just won't taste good
 - old Slovenian saying.

snip

Cheers, Aleks


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Re: [Biofuel] Martin's Job

2004-12-15 Thread aleksander . kac

Yes, a fine proposal. But let's not forget Keith, also spending a lot of 
his
resources keeping us (the nuthouse) alive for, how many years now? 
Journey has a donation button also. Both of them should deserve at
least some expense coverage from us all.

Cheers, Aleks





Gustl Steiner-Zehender [EMAIL PROTECTED]
Sent by: [EMAIL PROTECTED]
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Subject:[Biofuel] Martin's Job


Hallo Friends,

I may be out of line here with this idea I have but here it is. Martin
Klingensmith has volunteered his time and effort to giving this list a
good  home. More than the time and effort I believe he is spending his
own money on the physical resources (hardware/software) needed to keep
this list alive and upgrade it.

If  each  of  us  who  appreciate his efforts would consider sending a
dollar or two or five (or the foreign equivalent) to him to help him
defray  his  costs  it  would  not only be a kind gesture but show our
appreciation  of  his  work in a way which would allow him to continue
with  his  fine work and make the list even better and more secure and
efficient.   Anyone  who  was  around  for the last attack on the list
knows what I mean about being secure.

I  am not sure how Martin would feel about this as I haven't spoken to
him  about  it.   My  feelings  on  the matter are that this list is a
little  home for a bunch of good people and that it serves the greater
good  of  us  all.   I  am  willing to act as the collection point and
receive  any  contributions  which  anyone would care to make and send
them  on  to Martin, with his and the lists permission.  Any donations
could  be  sent  to  Martin  in  care  of me at my address and I would
forward  them to him unless Martin does not mind giving his address to
the list and receiving them directly.

What  are  the  lists  thoughts  on  this  those of the list owner and
administrators and, of course, Martin?

Happy Happy,

Gustl
-- 
Je mehr wir haben, desto mehr fordert Gott von uns.
Mitglied-Team AMIGA
ICQ: 22211253-Gustli

The safest road to Hell is the gradual one - the gentle slope, 
soft underfoot, without sudden turnings, without milestones, 
without signposts. 
C. S. Lewis, The Screwtape Letters

Es gibt Wahrheiten, die so sehr auf der Strae liegen, 
da sie gerade deshalb von der gewhnlichen Welt nicht 
gesehen oder wenigstens nicht erkannt werden.

Those who dance are considered insane by those who can't
hear the music. 
George Carlin

The best portion of a good man's life -
His little, nameless, unremembered acts of kindness and of love.
William Wordsworth



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Re: [Biofuel] Re: Source of Enzymes for ethanol production using corn

2004-11-29 Thread aleksander . kac

Hi Aleks, Johan

Sake brewers do it a different way. Do you know about this Aleks?

Yep. Momentarily I don't have enough space to try these 
mash/fermentations.
Hopefully, in a year or so.

snip

Huh? Bush what?

Bushwhacked? LOL!

:o)_ .

Cheers, Aleks


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Re: [Biofuel] CO2 and CO Biodiesel Emissions Reduction

2004-11-29 Thread aleksander . kac

Mamuel,

Thank you for the explanation.

Glad you like it :-).

After your hints and further investigation it seems a 50% reduction
of CO is a good average estimation for CO reduction while it is
dependent on engine technology, engine tuning and feedstock used.

Yes.

As for CO2, there is only a negligible reduction at the exhaust pipe
and to be honest, when we talk about the benefits of using biodiesel,
we should be very clear explaining that the 80-100% of CO2 reduction
claimed on almost every article and book on biodiesel is true only on the
global scale and only if the full energy cycle is considered.

I believe it is meant in this way, not to be exactely 100% as a part
of our fuel comes from dinosaur gas (methanol). Alkalis and acids also
need some dino heat to be produced, so, no, it is not a net 100% reduction
with biodiesel, but it is a helluvalot better than driving on pure
dinosaur oil.

In other words, the people using biodiesel in a particular metropolitan
area, will not experience any noticeable reduction on the emissions
of CO2 to the air that they breath. Only, in the longer term, they will
(hopefully!) experience the benefits of reduced global warming which
is not at all unimportant however not direct and not easily measurable.

Ah!
But a very large and noticeable reduction of particulate matter, which is
more important. CO2 causes just heat (and is/was largely absorbed by the
oil bearing plant), particulate matter causes immediate lung diseases 
including
cancer and a slow and painful death.
I think your matropolitans will prefer a net about 80% CO2 reduction plus
a net about 75% PAM reduction in a, ah hell, a not perfect biofuel, to
slow and painful deaths in the city, polluted by dinosaur oil exhaust.

Skol,
Aleks
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Re: [Biofuel] Re: Source of Enzymes for ethanol production using corn

2004-11-26 Thread aleksander . kac

I have been doing a lot of reading over the last few weeks; I would like
to distil my own ethanol but have a slight problem.  I live in Africa
and would appreciate it if anybody can supply me with a brand name for
alpha  beta-amylases.  Is there any alternative besides barley?

Sure, corn malt. You couldn't do a thing with barley, still need to malt 
it.
Malted grains contain all the enzymes you need.
 

Will I be able to recycle these enzymes; if so how?

Malt your corn for every batch. It's easy. Wet corn, allow to sprout
in damp warm place, wait for small rootlet to form and dry for storage
or grind and use immediately in mash.
 

I have been printing and reading all the available information on JtF
web page but cannot seem to find the quantities used for preparing the
mash, both for enzymes and yeast.  I have no idea how big MOTHERS spoons
are.

Rule of thumb: 60% of all your grist needs to be mashable, and you need
to liquify whatever starch you fill in as an adjunct (sorry, beer lingo).
You need roughly 80 M cells/ml if you want a strong start in fermentation.
Menaning, your starter needs to be of 20% your fermentable volume to
complete quickly. Yeast can be reciycled for several fermentations if
you keep it happy (plenty oxygen on the start and temperature control
during fermentation).

 

How much does a bushel weight?  Am I correct in saying that a gallon is
3.85 litres?

Huh? Bush what?

 

Cheers, Aleks



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Re: [Biofuel] Re: Source of Enzymes for ethanol production using corn

2004-11-26 Thread aleksander . kac

I have been doing a lot of reading over the last few weeks; I would like
to distil my own ethanol but have a slight problem.  I live in Africa
and would appreciate it if anybody can supply me with a brand name for
alpha  beta-amylases.  Is there any alternative besides barley?

Sure, corn malt. You couldn't do a thing with barley, still need to malt 
it.
Malted grains contain all the enzymes you need.
 

Will I be able to recycle these enzymes; if so how?

Malt your corn for every batch. It's easy. Wet corn, allow to sprout
in damp warm place, wait for small rootlet to form and dry for storage
or grind and use immediately in mash.
 

I have been printing and reading all the available information on JtF
web page but cannot seem to find the quantities used for preparing the
mash, both for enzymes and yeast.  I have no idea how big MOTHERS spoons
are.

Rule of thumb: 60% of all your grist needs to be mashable, and you need
to liquify whatever starch you fill in as an adjunct (sorry, beer lingo).
You need roughly 80 M cells/ml if you want a strong start in fermentation.
Menaning, your starter needs to be of 20% your fermentable volume to
complete quickly. Yeast can be reciycled for several fermentations if
you keep it happy (plenty oxygen on the start and temperature control
during fermentation).

 

How much does a bushel weight?  Am I correct in saying that a gallon is
3.85 litres?

Huh? Bush what?

 

Cheers, Aleks



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Re: [Biofuel] CO2 and CO Biodiesel Emissions Reduction

2004-11-26 Thread aleksander . kac

Manuel,

There is many articles and studies about the reduced emissions of CO2 and
CO when using biodiesel as compared to diesel emissions. Most sources
document 80-100% reduction of CO2 and 50% reduction of CO.

Can be even better.

Provided the calorific energy of biodiesel is quite similar to that of 
normal diesel,
and both are hidrocarbon compounds, how it comes the emissions of CO2 and 
CO
can be so much lower at the engine exhaust pipe. (not talking about the 
full
energy cycle, including the CO2 absorbed by the crops and so on).

During combustion, Where the energy comes if not from Carbon?
Where the carbon goes if not to CO2 and CO?

True.

Are the CO2 and CO emissions from biodiesel really lower than diesel
emissions?

Yes.

If so, do you know why? A chemical or stechiometrical explanation.

Look at the ester molecule. The catch lies in the oxygen bridge between
the alcohol and acid component of the ester. This has two advantages:
because the molecule breaks at the bridge the smaller part oxydizes
first, rapidly causing a smal temperature bump up for the next step(s). 
The second advantage is, that the fuel carries oxygen inside the molecule, 

thus further leanning the fuel/air mixture. I'm sure there are other 
pluses,
but these two are the ones I know of.

Cheers, Aleks



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[Biofuel] Devastating news ...

2004-11-26 Thread aleksander . kac

PRESIDENTIAL LIBRARY DESTROYED BY FIRE
Crawford, Texas--

A tragic fire this morning destroyed the personal library of 
President George W. Bush.
 
Both of his books have been lost.

A presidential spokesman said the president was devastated, as he had
almost finished colouring the second one.
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Re: [Biofuel] Please explain the chemestry

2004-11-24 Thread aleksander . kac

Roy,

I have just made my first batch of fuel, it worked just great considering
the rough measuring used.
Thanks for all the info.
I have a few questions someone may care to answer though.

On mixing the lye with the methanol a (part) chemical reaction seems take
place.
I assume it is a reaction and not just a solution because heat is 
produced.

Dissolving most of ionic compounds produces heat (latent heat stored in 
the
chemical bonds of the compound) apart from a few (ammoniun nitrate for one
which cools when dissolved - used as snow concrete in ski WC 
competitions
and, of course, is very bad for alpine pastures used as skiing ground).
Methanol, being the first in the row of alcohol chains retains a lot of
polar characterics, much like water. Although all alcs are at least 
slightly 
polar (the huge minus charge or electron presence above the O atom).

I say part because the amount of lye varies with the oil type not the
methanol quantity, therefore leaving differing amounts of methanol
un-reacted each time.

Not very true. The amount of reacted meth is depending only on the number
of molecules of oil which aremethylated in the process. The amount of lye
is 3.5 g/l + whatever needed to neutralize FFAs.

Will someone un-confuse my thinking on this bit, like what is really
happening here?

Next, when one puts the above concoction into the oil what is actually
happening and in what order? Why is the lye added to the methanol and not
the oil directly?

High school chemistry textbook  organic chemistry  nucleophillic 
substitution.


Cheers, Aleks

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Re: [Biofuel] hybrid vehicles

2004-11-22 Thread aleksander . kac

The hybrid Hummer. All diesel subs starting well before WW2.
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Re: [Biofuel] Washing Gone Wayward

2004-11-16 Thread aleksander . kac

Chickensoup!
(at least a mild case).
When heating does not disperse an emulsion you have to resort to heavier
mallets. Usually lowering/raising the pH does the trick. Since you do not 
want
any more emulsion, you should lower the pH, using citric acid, vinegar or
phosphoric acid in na 10% or less solution. Turn on your bubler on and add 

the acid (5%) of your washing water. Wash as usual, followed by at least 
2x 
water only and reheat.
This should do the trick.
Next time dont mix the bottom layer of washed bio with water and bio. It 
seems
to be an emulsifier. I collected these bottom inch layers in a separate 
vessel
and after some settling you can still save a lot of bio when the vessel is 
full.

Cheers, Aleks
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RE: [Biofuel] Washing Gone Wayward

2004-11-16 Thread aleksander . kac

Excellent insight Aleks, thank you very much.  I'll give it a shot and 
post
my findings.  My goodness, the learning curve is time intensive!

Now, however, I'm curious as to why mono or di glycerides would 
concentrate
in the wash water.  Enough catalyst but not enough methanol?  Incomplete
reaction?  h.

Thanks again,

Joey

Mono and di-glycs, for one, have a bigger molecular weight than 
methylates,
meaning, as a rule of thumb, a bigger specific weight. Thus, on the other
hand, meaning a concentration in the bottom portion of your brew. And some 
mono
and di-glycs are also emulsifiers, which perforce positions them between 
the 
water (the polar phase) and the esters (non-polar phase).
So, they don't concentrate in the wash water but in the whole phase 
divide.

What should you do?
Can't really say, I don't know your process. A few tricks:
you could mix a little longer, add more meth, add more lye, combine the 
three, 
play with the temperature. None of these solutions might give a 
satisfactory 
result, as the TE reaction never really completes. It somewhat depends on
the quality of the oil. Find biodiesel troubleshooting also on JtF and in 
the
archives.





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RE: Bible, Koran Torah Thumping, not to mention other general s heeple tricks was Re: [Biofuel] about God

2004-11-12 Thread aleksander . kac

snip
It is human nature to believe in A HIGHER BEEN because we all look for a
father or mother figure to cling to.

Um, I am a strong believer of higher beans ... :-) ... red kidney 
especially.
And that these beans cling to poles :o).
Yum.

Cheers
Aleks

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Re: [Biofuel] The Other People

2004-11-11 Thread aleksander . kac

Kim,
excellent morning reading :-)_  
Cheers, Aleks


Sorry, I forgot I can't send an attachment.  Here is the article for those 

who wanted to read it.
Bright Blessings,
Kim

We Are the Other People
by Oberon Zell


Ding-dong! goes the doorbell. Is it Avon calling? Or perhaps Ed McMahon 
with my three million dollars? No, it's Yahweh's Witlesses again, just 
wanting to have a nice little chat about the Bible...::
Boy, did they ever come to the wrong house!  So we invite them in:

Enter freely and of your own will... (Hey, it's Sunday morning, nothing 
much going on, why not have a little entertainment?)  Diane and I amuse 
ourselves watching their expressions as they check out the living room: 
great horned owl on the back of my chair; ceremonial masks and medicine 
skulls of dragons and unicorns on the wall; crystals, wands, staffs, 
swords; lots of Goddess figures and several altars; boa constrictors 
draped 
in amorous embrace over the elk horn; white doves sitting in the hanging 
planters; cats and weasels underfoot; iron dragon snorting steam atop the 
wood stove; posters and paintings of wizards and dinosaurs and witchy 
women, some proudly naked; sculptures of mythological beasties and lots 
more dinosaurs; warp six on the star-filled viewscreen of my computer; a 
five-foot model of the USS Enterprise and the skeleton of a plesiosaur 
hanging from the ceiling; very, very many books, most of them dealing with 

obviously weird subjects... To say nothing of the great horned owl perched 

on the back of my chair and the
Unicorn grazing in the front yard. You know; early Addams Family decor.

:   And then, of course, it being late in the morning, you can expect 
Morning Glory to come wandering out naked, looking for her wake-up cup of 
tea. Morning Glory naked is a truly impressive sight, and the Witlesses 
look as if she'd set titties on stun as they stand immobilized, hands 
clasped over their genitals. With the stage set and all the actors in 
place, the show is ready to begin.
:
:   Their mission, of course, it to save our heathen souls by turning us 
on 
to The Word of the Lord - their Bible. I guess they figure some of us 
just haven't heard about it yet, and we're all eagerly awaiting their 
joyous tidings of personal salvation through giving our rational faculties 

to Jesus. Every time they come around, I look forward to trying out a new 
riposte. Sure, it may be cruel and sadistic of me, but hey, I didn't call 
them up and ask them to come over; they entered at their own risk!
:
:   This time should be pretty good. After letting them run off their 
basic 
rap while lovely Morning Glory serves us all hot herb tea, I innocently 
remark: But none of that applies to us. We have no need for salvation 
because we don't have original sin. We are the Other People.
:
:   Hunh? What? they reply eloquently. It's clear they've never heard 
this one before.
:
:   Right, I say. It's all in your Bible. And I proceed to tell them 
the story, using their own book for reference:
:
:   Genesis 1:26 - The [Elohim] said, Let us make humanity in our own 
image, in the likeness of ourselves, and let them be masters of the fish 
of 
the sea, the birds of heaven, the cattle, all the wild beasts and all the 
reptiles that crawl upon the earth.
:
:   Elohim is a plural word, including male and female, and should 
properly 
be translated Gods or Pantheon.
:
:   27 The Gods created humanity in the image of themselves, In the image 
of the Gods they created them, Male and Female they created them.
:   28 The Gods blessed them, saying to them, Be fruitful, multiply, fill 

the earth and conquer it. Be masters of the fish of the sea, the birds of 
heaven and all living animals on the earth.
:
:   Now clearly, here we are talking about the original creation of the 
human species: male and female. All the animals,plants, etc. have all been 

created in previous verses. This is before the Garden of Eden, and Yahweh 
is not mentioned as the creator of these people. The next chapter talks 
about how Yahweh, an individual member of the Pantheon, goes about 
assembling his own special little botanical and zoological Garden in Eden, 

and making his own little man to inhabit it:
:
:   Gen 2:7 - Yahweh God fashioned a man of dust from the soil. Then he 
breathed into his nostrils a breath of life, and thus the man became a 
living being.
:   8 Yahweh God planted a garden in Eden which is in the east, and there 
he put the man he had fashioned.
:   9 Yahweh God caused to spring up from the soil every kind of tree, 
enticing to look at and good to eat, with the tree of life and the tree of 

the knowledge of good and evil in the middle of the garden.
:   15 Yahweh God took the man and settled him in the garden of Eden to 
cultivate and take care of it.
:
Now this next is crucial: note Yahweh's precise words:

16 Then Yahweh God gave the man this admonition, You may eat indeed 
of 
all the trees in the garden.
17 

Re: [Biofuel] Methanol Safety of Dispensing from 55 Gal. Drums to carboy safely

2004-11-10 Thread aleksander . kac

Drum in upright position: remove the small cap and fit a ball valve 
(preferably teflon inner husing) with a hose connector on the other side 
into the threads, sealing with teflon tape. Lay the drum flat on a stand 
(make of wood, or if enough skilled weld of steel tubes). Takes two quite 
strong chaps. Rotate the drum in suitable position (valve at bottom), 
attach hose to connector with hose clamp and ground drum. Put hose into 
carboy, open ball valve. After a few litres come out, flow stops, close 
ball valve, grab drum cap spanner, crack open the big cap and bleed some 
air in. Continue filling carboy. Once about 35 litres of meths is out, 
crack open big cap before transferring, close after finished (meths level 
is now lower than big cap). Cheap, safe. You should be able to get a ball 
valve and barbed hose connectors, hoses etc. at your home improvement 
store, just take a small cap with you for size reference.

Cheers, Aleks


After 11 months of research of biodiesel and pondering methanol safety, I 
have not come across any recent scenarios of dispensing methanol from a 55 
gal metal drum to a BD methoxide processor (carboy) with only one 
exception. 
(On Journey to Forever's site)
One chap using a 55 gal poly drum of methanol with a special bung cap 
fitted with a tire valve plug /shaft. 

The listed method is from memory, but I believe it is ...Applying 
compressed air to the tire plug will create pressure within the drum to 
exhaust pressured output (methanol) or pump methanol to the methoxide 
container etc.

To purchase a 55 gal. drum or drums of methanol is a vast saving compared 
to buying meth. in 5 gal pails here on the northeast coast of the US. 
Methanol is your most expensive raw material when it comes to biodiesel 
production.  My first question is 1.)  How to dispense the Methanol from a 
55 gal drum to my carboy safely using approved drum equipment?  Model 
number of hand pumps helps to include with reply!! etc.?

How do you ground the drum?
I can make a ground 55 gal drum clamp w/wire and ground it to the earth. 
-Solved

Method of delivery?
Not sure how the chap purchased the Methanol in a poly drum, or maybe he 
transferred it, since methanol should most likely be sold in a metal 
drums?.

2.)Question is: Can't find a rated 55 gal. drum pump (hand) to use for 
methanol that is explosive proof and is rated for methanol. Any help


Thank you, 
Kevin Shea
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Re: [Biofuel] My fuel tank after 4 years of bio

2004-11-09 Thread aleksander . kac

Yo Keith/community!
Well, all is well that ends well. I tuned the pump myself yesterday,
loosened the spring tensioner device of the diaphragm somewhat (to
start spritzing fuel in at a lower turbo boost) and I then minimally
enriched the mixture by rotating the eccentric pin towards a richer 
setting.
Bosch fuel pumps are no taboo for me anymore. Nor is the crappy
Bosch service. I found all the neccessary adjustments on the lrenthusiast
webpage, technical section (under more power). All the settings are
equal for any Bosch VE (distributor) pump.
Result: reasonable low end pull, no noticeable smoke increase. Oh,
and I made it through the smoke opacity test 2 weeks ago: 0.34 of 3.5
allowed. Like a new TDI engine.

Cheers, Aleks


Damn you say, LOL! We said Damn for just the opposite reason, and 
I imagine Luc said something similar. Our Town-Ace's tank had a lot 
of rust in it, though not eaten right through (like both our Land 
Rovers' tanks were). Not caused by biodiesel though. I think what 
happened is that the car stood idle for quite a while before it was 
sold, and the diesel fuel they sell here (and most other places?) is 
not exactly free of water - let them stand, and they rust. Heard of 
another such case not long ago with a Mercedes in the US. Anyway, 
biodiesel, being the wonderful stuff that it is, loosens the rust, 
which then clogged up the sediment filter, which is INSIDE the tank - 
you have to take the whole tank out to get at the filter. It was 
thoroughly gunged up with rust. This we discovered after the Town-Ace 
more or less stopped going, obvious case of fuel starvation. We threw 
away the sediment filter and cleaned the tank out, it was just 
surface stuff, though there was quite a lot of it, but no need for 
any further treatment. Then we replaced the sediment filter with one 
from a Kubota tractor, fitted outside the tank, thankyou, plus an 
extra 10 micron filter downstream of that, no more problem. This 
after 18 months of running on B100. No problems with any of the leads 
or plastic, all in good order - I agree, if properly made, biodiesel 
won't do them any harm. For the record, it's also 14 years old, a 
1990 Toyota Town-Ace 4x4 van 1.9-litre 4-cyl turbo diesel.

We're thinking on similar lines Aleks. We've got an Elsbett system, 
we'll be fitting it in a week or two, very nice too. I think this is 
the second one in Japan. Our friend Wada-san has the first, on his 
Golf. He came to visit us after he installed it, running on SVO 
instead of biodiesel. Well, WVO actually, from his office canteen. 
They'd told him it was good oil. He gave me a sample, but it didn't 
look too good to me. I tested it. It titrated at 7.5 ml, yuk! Poor 
Wada-san was deeply shocked. I don't think he eats at the office 
canteen anymore. I gave him a supply of 1 ml titration WVO, properly 
filtered, and a titration lesson, plus some biodiesel to help dilute 
the horrible stuff in his tank (which doesn't have a drain).

Regards

Keith



Oh, and it was about 5.200 litres of bio running through (150 batches in
35 litre reactor)


I took off my fuel tank last saturday, mainly to see if any buildup of
anything is
on the bottom and fuel feed and return manifolds inside the tank after
four
years of driving on bio and various blends of bio/dino.

The result: zero. Absolutely clean, no spot of rust, no nothing. All
plastic
parts in the fuel tank: intact (swimmer housing, plastic fuel feed
prefilter,
rubber wire insulation, electrics in the swimmer housing).

Nothing.
Damn.

The reason I did this, is I get poor acceleration after the engine 
restore
this year (most of the year, it turned out most of the car was in need of
something,
14 years old and 200.000 miles on the clock).
I laso had the fuel pump rebuilt, a Bosch VE (pre-electronic diesel) 
pump.
It turns out, the guys at the Bosch shop didn't tune the pump properly.
Arrgh.
On the other hand, I'm glad I did it. Both for the sake of bio harming
plastic
parts of cars (if properly made it does not) and the second reason is 
that
I want to fit the car with an Elsbett single tank vegoil system next
spring - to rule
out the fuel tank and lines if anything goes wrong.

Cheers, Aleks

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[Biofuel] Tweaking a Bosch VE pump

2004-11-09 Thread aleksander . kac

Everybody, since I got a lot offline traffic

For those who like to tinker on a fuel pump:

A land rover forum should be where to look for. I can't try
this here at work (no internet allowed as for previous
non work related searches i.e. biofuels, JtF ... here's 
democracy forya).
Start at this one 
dodgeram.org/tech/dsl/more_power/Power_ve.htm 
read the ram page first, then there's a link to the lr, 
read it WHOLE, grab your toolbox and get started.
READ EVERYTHING ON THE LR THREAD! You can do damage
if you are not entirely sure of what you're doing!

Cheers, Aleks
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[Biofuel] My fuel tank after 4 years of bio

2004-11-08 Thread aleksander . kac

I took off my fuel tank last saturday, mainly to see if any buildup of 
anything is
on the bottom and fuel feed and return manifolds inside the tank after 
four
years of driving on bio and various blends of bio/dino.

The result: zero. Absolutely clean, no spot of rust, no nothing. All 
plastic
parts in the fuel tank: intact (swimmer housing, plastic fuel feed 
prefilter,
rubber wire insulation, electrics in the swimmer housing). 

Nothing.
Damn.

The reason I did this, is I get poor acceleration after the engine restore
this year (most of the year, it turned out most of the car was in need of 
something, 
14 years old and 200.000 miles on the clock). 
I laso had the fuel pump rebuilt, a Bosch VE (pre-electronic diesel) pump.
It turns out, the guys at the Bosch shop didn't tune the pump properly.
Arrgh.
On the other hand, I'm glad I did it. Both for the sake of bio harming 
plastic
parts of cars (if properly made it does not) and the second reason is that
I want to fit the car with an Elsbett single tank vegoil system next 
spring - to rule
out the fuel tank and lines if anything goes wrong.

Cheers, Aleks
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Re: [Biofuel] My fuel tank after 4 years of bio

2004-11-08 Thread aleksander . kac

Oh, and it was about 5.200 litres of bio running through (150 batches in 
35 litre reactor)



I took off my fuel tank last saturday, mainly to see if any buildup of 
anything is
on the bottom and fuel feed and return manifolds inside the tank after 
four
years of driving on bio and various blends of bio/dino.

The result: zero. Absolutely clean, no spot of rust, no nothing. All 
plastic
parts in the fuel tank: intact (swimmer housing, plastic fuel feed 
prefilter,
rubber wire insulation, electrics in the swimmer housing). 

Nothing.
Damn.

The reason I did this, is I get poor acceleration after the engine restore
this year (most of the year, it turned out most of the car was in need of 
something, 
14 years old and 200.000 miles on the clock). 
I laso had the fuel pump rebuilt, a Bosch VE (pre-electronic diesel) pump.
It turns out, the guys at the Bosch shop didn't tune the pump properly.
Arrgh.
On the other hand, I'm glad I did it. Both for the sake of bio harming 
plastic
parts of cars (if properly made it does not) and the second reason is that
I want to fit the car with an Elsbett single tank vegoil system next 
spring - to rule
out the fuel tank and lines if anything goes wrong.

Cheers, Aleks
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Re: [Biofuel] re sec ond stage method

2004-11-04 Thread aleksander . kac

the two stage method is ok for high ffa content but still produces 
inferior products the glycerine is horrible for making soap and i have 
my doubts about the bd product  it still retains that awful smell and 
there is a not a good return ratio especially with no soap by product 
we abandoned  the two stage process, after substantial investment, 
because it did not meet our needs.

What kind of two stage did you use?

Cheers
Aleks

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Re: [Biofuel] biodiesel QA

2004-11-04 Thread aleksander . kac

koal2.cop.fi/leonardo/ 

Look it all up, somewhere on the webpage there's some 
info on quality testing.

Cheers, Aleks
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Re: [Biofuel] Fwd: Information on Sawdust processing

2004-10-28 Thread aleksander . kac

I use the same kind, no binder made briq's, for the bulk of my winter 
heating. Less than 2 kg of these
briq's are the thermal equivalent of one litre of heating oil. I need 
about 1 metric ton per winter, and
it's 3 times cheaper than heating oil per kWh of heat. The shawings and 
sawdust are produced in a
woodworking shop that makes parquette flooring, the briq's are just a 
byproduct to get rid of the shawings
and dust.

Aleks

Hi Peter,
my Rip and Sawdust (all dry less than 10%) is collected in a 5ft x 5ft 
x5ft
Storagecontainer,with Airfilterbags abouve and the Briquettepress under.
a continuos Screw like arm goes inside the Container around and fills the
loading zylinder from there the Rip is pushed by a Piston in the
Presszylinder.
Than the Presspiston pushes the stock with 380bars in the Pressclamb,wich
opens at a certain moment to let the pressed Briquette out.There is a 5 Kw
3 phase Motor,a Hydraulicpump and all Pistons are hydraulic activated.
a pretty elaborated Controlpanel is coordinating the pressing.
I heat my house with Briquettes and partly my Shop (illegal since i am not
allowed to burn Waste in an industrial shop)
The Briquettes come out bonehard and give a beautiful Fire,once in 
glow,the
Briquettes are falling appart,but burn completely out,there is almost no
ashes!
A important prerequisit is,the Rip and the Sawdust must be Dry.The machine
can not handle wet stock!
you can look at my machine under www.spaenex.de  go to Briquettepresses
my Model is SHB50
if you need more info about dont hesitate to ask
Fritz
- Original Message - 
From: Guag Meister [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Wednesday, October 27, 2004 9:14 PM
Subject: Re: [Biofuel] Fwd: Information on Sawdust processing


 Hi Fritz ;

 I have access to a small regular supply of sawdust for
 free.  Can you tell us a little about your process?

 Hydraulic or mechanical? What pressure?  Is it
 homebuilt?  Do you heat the die? How big is the die?
 Did you make the die yourself?  How? Do the briquetts
 stay together when burning?  How do you burn
 (fireplace, stove, gasify)?  Are there any web links
 which explain the  process that you use?

 Best  Regards,

 Peter G.
 Thailand

 --- Friedrich Friesinger [EMAIL PROTECTED]
 wrote:

  Hi Greg,
  you dont need any additives to press Sawdust to
  Briquettes,i make Briquettes
  every Day with my Woodshavings only by compressing
  it
  Fritz
  - Original Message - 
  From: Greg Harbican [EMAIL PROTECTED]
  To: [EMAIL PROTECTED]
  Sent: Wednesday, October 27, 2004 2:16 AM
  Subject: Re: [Biofuel] Fwd: Information on Sawdust
  processing
 
 
   Make BioDiesel, then use the glycerin glop as a
  binder and use a brick
  press
   to compress into a log/chunk, let harden
  Alternatively mix the saw dust
   with a drying oil or warm pitch or other similar
  substance ( shellac ?)
  that
   can be obtained locally, then compress with a
  prick press, then let
  harden.
  
   Greg H.
  
   - Original Message - 
   From: Keith Addison [EMAIL PROTECTED]
   To: [EMAIL PROTECTED]
   Sent: Tuesday, October 26, 2004 23:42
   Subject: [Biofuel] Fwd: Information on Sawdust
  processing
  
  
Greetings all
   
I was sent this by an NGO in Sri Lanka. Any
  advice for them? They're
not list members, but I'll forward any
  responses.
   
Thanks!
   
regards
   
Keith
   

   
From: National Development Foundation
  [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Subject: Information on Sawdust processing
Date: Mon, 25 Oct 2004 23:13:12 +0600
   
National Development Foundation
   
63/2, Yahampath Mawatha, Piliyandala Road,
  Maharagama, Sri Lanka.
   
Tele: +(94)-011-5526679 or +(94)-011-5522776
  E-mail:
   
 
 mailto:[EMAIL PROTECTED][EMAIL PROTECTED]
   
Monday, October 25, 2004,
   
Journey to Forever Organisation.
   
Dear Sir/Madam,
   
Ours is a Non-governmental, non-profit making
  organisation devoted to
development through self-help development
  programmes. We also
carryout environmental protection programmes
  with local communities
in Sri Lanka.
   
Recently we were informed of a long-standing
  problem in a suburban
city, due to sawdust. There are large numbers of
  timber mills,
carpentry workshops and woodwork centers in the
  area. They produce
tons and tons of saw dust and dump them into the
  nearby lake
polluting the area. Recently the government has
  no other alternative,
but found another dumping site and the sawdust
  is now dumped in this
site spending large sums of money for
  transportation. For a
developing country like ours this type of
  spending is unaffordable.
   
We have been trying to find a solution to
  re-cycle and use saw dust.
As we understand, it is possible to make Sawdust
  Bars - fire logs,
briquettes etc or even insulating boards if
  properly experimented. We
were also made to understand that 

RE: [Biofuel] How to choose a Biodiesel car or van???

2004-10-27 Thread aleksander . kac

Dan,

The ELSBETT engine sounds appealing, but I have no idea how hard it would 
be
to match one to my station wagon, how hard it would be to find a mechanic
comfortable with this relatively unknown engine ( in these parts), and I
really have no sense of what this thing would cost from the web page ( 
cost
of engine, shipping fees, cost of mating transmission to it, etc).

Anybody have any answers for this ? :-)

AFAIK: 
Elsbett three cyl., 1500 ccm, split piston diesel engine
These engines are years out of production. One of the reasons for the 
financial
collapse of the original Elsbett company was a production attempt in south 
America.
Elsbett also sold licensing to Russia.
You may perhaps be able to trace one (a narrow chance, though, and you 
will be 
forced to heavily auction and beat me :-)) at Ebay, they a re still 
driving
over here in Europe. They are made to replace VW engines mostly, but other
car conversions shouldn't be a problem.
The present Elsbett company is involved in one or two tank conversions for
diesel engines to run on neat veg oil. Fresh oil, not WVO. Also, the 
inventor of
the engine, Elsbett sr., died a few years ago. His son (?, I think) is a 
lot more
into solar/biomass stirling engines. A friend of mine visited him in 
november '03
and saw the stirling running on wood pellets - took pictures. Wow.

Aleks

snip



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Re: [Biofuel] Fwd: Information on Sawdust processing

2004-10-27 Thread aleksander . kac

Combine sawdust with hacked rice straw (about 2 in long) as a filler and 
mix in poor concrete or concrete milk.
Cast  porridge in wooden forms (blocks several inches or panels desired 
inches thick) and use for insulation 
between rafters. Straw panels made this way are still widely used in 
Slovenija (sandwich : cast porridge-
styrofoam-cast porridge). Blocks are held together with cement mortar, 
panels are screwed ot nailed
to the construction. Plaster on both sides and you've got a nice wall with 
some thermal mass,
or don't plaster and just paint and you get a nice rustic wall. 
Alternatively combine sawdust and hacked
rice straw with clay to make plasters, bricks, cast walls (an adobe 
variation, is it?). 
Depending on climate, outer walls made this way should be protected by 
suitable overhangs.
Sawdust by itself could make insulation in hollow spaces in walls, but 
should be treated with perborate
to fireproof (nontoxic). All this can be made by hand.

If funding kicks in, buy hydraulic press for wood bricks, doesn't need 
binder but a lot of pressure (power,
this can't be made by hand).

Aleks


Greetings all

I was sent this by an NGO in Sri Lanka. Any advice for them? They're 
not list members, but I'll forward any responses.

Thanks!

regards

Keith



From: National Development Foundation [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Subject: Information on Sawdust processing
Date: Mon, 25 Oct 2004 23:13:12 +0600

National Development Foundation

63/2, Yahampath Mawatha, Piliyandala Road, Maharagama, Sri Lanka.

Tele: +(94)-011-5526679 or +(94)-011-5522776 E-mail: 
mailto:[EMAIL PROTECTED][EMAIL PROTECTED]

Monday, October 25, 2004,

Journey to Forever Organisation.

Dear Sir/Madam,

Ours is a Non-governmental, non-profit making organisation devoted to 
development through self-help development programmes. We also 
carryout environmental protection programmes with local communities 
in Sri Lanka.

Recently we were informed of a long-standing problem in a suburban 
city, due to sawdust. There are large numbers of timber mills, 
carpentry workshops and woodwork centers in the area. They produce 
tons and tons of saw dust and dump them into the nearby lake 
polluting the area. Recently the government has no other alternative, 
but found another dumping site and the sawdust is now dumped in this 
site spending large sums of money for transportation. For a 
developing country like ours this type of spending is unaffordable.

We have been trying to find a solution to re-cycle and use saw dust. 
As we understand, it is possible to make Sawdust Bars - fire logs, 
briquettes etc or even insulating boards if properly experimented. We 
were also made to understand that there are many organisations, 
private sector companies engaged in this business.

We thought of searching for a simple technology that could be 
introduced to the low-income generation groups in the area, 
especially to the women, who could produce some type of an item to 
the market, could be a fire log, a briquette or an item that could be 
used in daily life.

If we could introduce this type of a technology then it will help the 
poor to generate income. On the other side it will arrest the 
pollution problem in the area and save public money that is spent at 
present for clearing and dumping.

Considering the above we are very much obliged if you could help us 
in finding a technological enterprise who would willing to conduct an 
investigation on this matter.

Since ours is a NGO, we are unable to fund such a programme. If the 
programme proves to be successful, we may be able to convince a 
suitable and sympathetic funding agency to support the initial stages 
of this challenging project.

I send an article as an attachment to this e-mail that describes the 
problem in the area.

We sincerely hope that you will give your sympathetic consideration 
to this request.

Thanking you and hoping to hear from you favourably,

Sincerely yours,

Upali Magedaragamage,

Executive Director,

NATIONAL DEVELOPMENT FOUNDATION.

---

Attachment:

Consuming the Bolgoda... : An eco-system in peril

by RAPTI SIRIWARDANE-de ZOYSA

Saturday, August 07, 2004 5:19:50 PM

It has already been said a countless number of times, in a 
considerable number of ways by a numerous number of people, from 
journalists and environmentalists to the local communities inhabiting 
the area. For indeed, thanks to widespread and sustained media 
attention, activists and NGOs have been able to garner support 
pushing for the conservation of the Bolgoda Lake and its surrounding 
wetlands.

The uncontrolled dumping of industrial effluent, agricultural 
pesticides and untreated sewage leading to depleting mangrove 
reserves and the immense loss of biodiversity, an ever-increasing 
population density due to its recreational value and scenic beauty, 
and now the construction of the Colombo - Matara Expressway to join 
the long catastrophic laundry list, inevitably prompts 

Re: [Biofuel] 2004 VW Jetta TDI

2004-09-22 Thread aleksander . kac

- Original Message - 
From: m gildow [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Saturday, September 18, 2004 7:43 PM
Subject: [Biofuel] 2004 VW Jetta TDI


 After having a VW Pickup and becoming interested in
 Biodiesel as a fuel I have bought a new 2004 VW Jetta
 TDI. I have read several postings from various chat
 pages that the new TDIs shouldn't run Biodiesel. Does
 anyone have any experience with the new TDIs?
What does the instruction booklet say? If the factory forbids the use of
bio, stick with it.

 I would
 like to start using Biodiesel in it either as an
 addative or straight, but don't want to cause any
 problems.
Well, Mel, ( I just had to do that) from what is my understanding ALL new
model european cars are BD friendly since the 80's. I could be a little 
off
on the actual dates but it is a sure thing for recent models, from the 
info
posted here in the past.
L.

Not true. Opel in his new DI engines forbidds use of bio in any form. New
VW models do not tolerate biodiesel also (any form, not even B5) in some 
engines.
We have had a LC Toyota (100 series) with a totally broken IP after only 
6.000
km on neat bio (costly repair, 12.000 US). 
We've been in the EU for a very short time (meaning biofuels are legal now
in Slovenija) and have had serious damage on  engines. I could go on and 
on: 
BMW - no good OBD shuts the engine down, Peugeot - will stop engine, 
beacuse antiPM 
chemical injected in the exhaust is not compatible with neat bio, 
Mercedes - OBD gets all fuzzy, can't recognize the neat bio as a fuel ... 
I
recently learned thet people in Germany, though having neat bio at quite a 
lot
of fuel stations, actually don't drive on it and strongly recommend 
against.
Except for farmers and bus fleets owned by cities, very few people drive 
on
bio. VW alone reported about 20M? spent in repairs on warranted VW cars 
in 2003
for biodiesel usage related damages.

Sooo: not all cars come biodiesel ready. Some need to be ordered biodiesel
compliant (BMW, Merc, ...) some don't even have this option. Specially 
suited are older TDIs,
most prechamber engines (modification), most new heavy machinery diesels 
(some need the obvious hoses and gasket change, CAT for example) and most 
newer 
gensets. I'm not having good experiences with my car, and I have certified
DIN compliant fuel. And, it's not only the gaskets on the pump shaft, if 
you're 
wondering. The whole rotor assembly needed to be renewed, it wasn't  very 
expensive,
but this means the fuel is not safe for my car in its neat form.


Cheers
Aleks



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[biofuel] Re: biodisel in Canada

2001-01-25 Thread aleksander . kac

Hello Adrian!
And how exactely would we do that? Biodiesel lounch
is difficult in countries without the knowledge of
biofuels existance.
Keith, please send a team over! Valium and streight jackets
and everything included. Soon to be two frustrated
people here, banging heads against concrete walls.

Cheers, Aleks

 Hi Aleks
 Probably me and you are in the same position :
 struggling for the launch of biodiesel  industry in
 our countries (Poland and Slovenia).
 
 Why don't we join forces to work out new solutions for
 CEE countries on how to start biodiesel (biofuel)
 industry here ?
 
 Best regards 
 
 Adrian 



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Re: [biofuel] Sodium hydride

2001-01-23 Thread aleksander . kac


No  way  by heating.
Sodium hydride (NaH) is made electrolitically. A  sodium bar
is sunk in saltwater and made into a cathode and put to power.
Remember the 'cold fusion? Well, this is not very far away.
There are some other ways but none of them is cheap - sodium
lye for one is cheap, but when heated it just melts (very high melting
point, though).

Aleks


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Re: [biofuel] Dale's machine

2001-01-22 Thread aleksander . kac


WOW!

Boys and girls, 't looks like R2D2 (in a cage)! Terrific!

A bit complicated for me of course, but it makes a nice portable reactor.

Cheers, Aleks


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[biofuel] Rapeseed emissions - no more,please

2001-01-19 Thread aleksander . kac


There is another strong reason to consider: a scientist, who's
funds are running out and is not as popular in the science com-
munity decides to take sides. He makes enemies, gains some
funds (it doesn't really matter where they come from, if his dept
is just so little far away from being closed) and last, but not least
he makes some new friends.
Analysis results can be interpreted in different ways, that's always so.

Cheers. Aleks


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Re: [biofuel] Rapeseed emissions more polluting than diesel - study

2001-01-18 Thread aleksander . kac


Burning oil in an open combustion chamber is not the same as
pressure burning in the engine (yes, in a diesel engine the fuel
burns, it does not explode). But it is not far from the truth when you
say diesel exhausts cause cancer. Dinod exhaust contains different
cancerogene substancies as biod's, though.
Our main adversaries in the battle against cancer are nitrouos oxides.
Both dino and bio produce them. Infact you can see them : its a very
bright blue colored gas (provided the engine does not burn its motor
oil, which you can smell), but nevertheless these gasses are the
uglyest thing comming out a diesel engine; soot is not as dangerous
and with biod you almost can't produce sulphur oxides or aromatic
substances.

Aleks


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Re: [biofuel] Digest Number 252

2001-01-15 Thread aleksander . kac






You are absolutely right. But a molecule of water weights just 18 g/mol.
Another possibility to drain water may be osmosys which requires a
membrane.

*i don't know why it works, but old pilots like myself used to filter our
aircraft gas through a 'chamoix', that is a wool-less sheepskin. the gas
would go through ok, but the water would not. did it for safety when flying
in the hinterlands.

A chamoix is is actually deerskin. It's terribly waterloving, if dry it can
suck up tremendouos amounts of water. When completely saturated it won't do
any good anymore though.

Cheers, Aleks





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Re: [biofuel] Re: screens

2001-01-12 Thread aleksander . kac



Keith Addison   

[EMAIL PROTECTED]To: biofuel@egroups.com   

rever.orgcc:   

  Subject: [biofuel] Re: 
screens
11.01.2001 20:19

Please respond to   

biofuel 













Someone mentioned a micron screen for diesel fuel that would not pass
water (so to speak!). Any ideas?

Nope. It would rather let pass water than diesel (water is a MUCH
smaller molecule). There are some membranes available, which are
now used more and more in solvent recovery after solventogenic
fermentation of scrap organic matter in the production of biofuels.

Cheers, Aleks





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Re: [biofuel] Re: screens

2001-01-12 Thread aleksander . kac


   
DAVID REID
   
[EMAIL PROTECTED]To: biofuel@egroups.com 

.nz cc: DAVID REID [EMAIL 
PROTECTED]
 Subject: Re: [biofuel] Re: screens 
   
12.01.2001  
   
06:45   
   
Please  
   
respond to  
   
biofuel 
   

   

   








Keith,
I doubt if thats possible. Believe a diesel molecule would be bigger than a
water molecule. One molecule of water as H20 is after all only three atoms
although the molecular weight is something like 33 (1 x 1 plus 2 x 16
offhand). Out of my depth unfortunately and I quickly get lost. Someone
correct me if I am wrong.
Aleks with your vastly superior knowledge of chemistry please enlighten us
if possible.  Believe it may be possible to pass water rather than diesel
on
this basis if  I am correct about molecule size.
B.r.,  David

You are absolutely right. But a molecule of water weights just 18 g/mol.
Another possibility to drain water may be osmosys which requires a
membrane.

Cheers, Aleks





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Re: [biofuel] Re:Dale's machine

2001-01-12 Thread aleksander . kac






The trap works very much like the oil traps in air compressors.  I
used the pressure pot from a paint spraying system.  It holds about
ten liters.
Uhm, don't quite get it. (not so good in engineering).

I plan to borrow a camera and post pictures this weekend.  Steal all
you want!  I plan to steal your two-stage process for my next batch.
Way cool!

Aleks







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[biofuel] Re:Dale's machine

2001-01-11 Thread aleksander . kac




And, of course, those switches.
Any special kind?

I first evacuate the tank, then suck in the oil through a filter
setup
that I'm a little too proud of.  I mix the methoxide separately,
using
a drill press with a paint mixer installed, then suck it into the
tank.  Then flip the pump switch.  Watch through the clear hoses and
marvel.  Later, flip off the pump switch, check for separation, flip
on the vacuum pump (which is connected to a liquid trap which is
connected to the condenser which is connected to the tank)and watch
the excess methanol collect in the trap.  When no more collects, I
open the tank to the atmosphere and drain off the glycerine.  Then
suck in water and begin the wash.

Okay, okay, maybe I was bragging a little.
Uhm, that was really OK. This is nice, I_mean_really_nice! Do you
mind if I steal the vacuum-trap-condenser idea? What kind of liquid
trap is it? Like oil traps in air compressors? This is a little more
complete than Josh's Grease Machine.

Cheers, Aleks






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Re: [biofuel] Re: Biodiesel - no catalyst

2001-01-10 Thread aleksander . kac




  But I'm not sure a biochemist would
even
drive a diesel, much less make his/her own fuel.
They make cheese, mostly. :o).

Isn't the acid catalyzed reaction slw?  Suslick and his followers
claim chemical reactions can be sped up considerably if US is used
during the processing.  I haven't used acid yet, since my oil has
little FFA and I don't relish mixing for eight hours, even
intermittently.  But if that time could be shortened to 45 minutes...
and I could shine UV light on the stuff too.
I don't know, Dale. It's not quite convincing me. What if it is 8 h mixing?
You don't have to do it by hand. And it's not quite 8 hours. It's just
5 times as much as lye TE and you should know how quick that is.


I shouldn't even be thinking about new methods.  I just finished and
tested a new processor.  I've got fuel running out my ears.
Brag, brag.;o)Let's see some pictures! Tell us, if you made something
special!


Cheers, Aleks




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[biofuel] Re: Biodiesel - no catalyst

2001-01-08 Thread Aleksander Kac

  It 
 would be interesting to apply such power to a small sample of 
 vegetable oil and methanol (or ethanol), without catalyst, and 
examine 
 the results.  Even if this produced no reaction, introduction of an 
 acid catalyst should.  Any biochemists out there?
Well, you need organic chemists, bios won't do. And why bother with
US, if you plan to catalyze? Just mix instead, it's easyer.
(an ester bond is not as easyly breakable as you generally might 
think; consider the strong alkalinity which is used in a lye based TE 
process)


Cheers, Aleks



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[biofuel] Martin Steele

2001-01-03 Thread aleksander . kac


Hey Keith!

How are you? Have you made it through New year's eve? In Slovenija
it was biting cold.
A question.
I don't seem to understand Martin's lingo AT ALL. Did you communicate
with him? What's his problem? To tell you the truth, I'm quite lost without
punctuation. I don't get much from his letters, despite the fact that he is
quite nice and always answers my mail.
So, what's the story behind this man? I got that he's 41, works with esters
for three years and fights the government. No recipe, no advice, no
nothing.
Do you know more? Am I too dumb to get his english?

Cheers, Aleks


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Re: [biofuel] KOH and saving methanol

2000-12-13 Thread aleksander . kac


A word of warning :
saving on methanol is a cheap way to make fuel. You'll get good
so-called yield and poor conversion. In other words :
Cheating on meth means drivng on glycerids.

Are there any other chemists in our group?

To help me explain that there is no perpetuum mobile?

To help me explain about equlibrium?

Aleks


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Re: [biofuel] Re: FFA@home

2000-12-12 Thread aleksander . kac


Hello Kevin!
Let's clear some things for you here!

Are you suggesting that the Methanol/Acid ratio is more important
than the Acid/Fat ratio.
Yes. Sulph acid/Meth should be 1-2ml/100ml. And for complete base
tranz your sodium methoxide should be 0.5 M (stands for molar, meaning
mols of NaOH per litre of solution). This is a bit low for our
standards, but added lots of it you reach our lye consumption.

Since we only what to change the FFA in the fat, say a titration of
6-7ml or approx 10gm of NaOH for a base reaction. For the previous
the FFA percentage  6% (I cant remember the conversion for FFA
percentage) what amount of acid will react with the FFA.
You have to determine the amount of METHANOL not acid. Gotten your
methanol volume, just pop in 1-2 vol.% of H2SO4. Acid is a true
catalyst in this reaction, so it does take part in actual products,
hence the non important exact value.

Michael indicated that the acid is not consumed during the reaction
but would be removed with the Base reaction. So no concerns with acid
in engines.
Michael suggested that 0.1% acid to the fat would cause a titration
of approx 1.4ml
Why the estimate? This one can be calculated exactly:
for every mol of H2SO4 Two mols of NaOH get neutralized.

So smaller amounts of acid will produce lower quantities of water.
Hence higher yield.
Nope. H2SO4 actually eats water, hence it's use in final stages
of alcohol dehydration.

Our best results have been with 4ml H2SO4 to 400ml Methanol. Greater
than 85% yield.
Intuitively got the right figure! Congrats!

The 2ml H2SO4 to 400 methanol has not been Base reacted, we are
letting it stand to see long term acid reaction.
That's the maximum of useful concentration. One can go higher but
with no better results. I read this from a cromatography sample prep
guide. I believe this guys.

Know since Methanol is the highest cost per litre, minimising its use
is of prime concern.
Wrong going here. Use as much meth as you can afford. Complete conversion
is directly connected to methanol input.

At present we don't have a reflux reactor for processing or a still
for methanol recovery.
Reflux is not necessary. Get a flash distillation to recover unreacted
methanol.
Stage One
1. How much H2SO4 to convert the FFA below a titration of 2.0ml
You need to know the meth amount. For every mol of FFA you need
one mol of MetOH. than just add 1-2% v/v acid.

2. How much Methanol to carry the Acid.
We already have this one. I myself am a chemist, but never bother to
calculate. I use meth in large excess. (10% with oil at this stage v/v)

Stage Two ( I know this can be split into two stages
3. NaOH amount calculated by titration method, seems to work.
With no more FFAs now you need 3.5 g/litre of oil+neutralyzation amount.

4. How much Methanol to carry the Base.
At least 15% to oil v/v.

5. What happens if KOH is used instead of NaOH
Recalculate amounts to KOH. I never use it because it's far too expensive.


Now really Cheers,
Aleks





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Re: [biofuel] FFA@home-not a chance!

2000-12-06 Thread aleksander . kac



Keith Addison   

[EMAIL PROTECTED]To: biofuel@egroups.com   

rever.orgcc:   

  Subject: [biofuel] FFA

05.12.2000 20:47

Please respond to   

biofuel 













FFA can probably be acid catalysed. I've not tried this, but the basic
recipe
has been looked at by an analytical chemist who thinks it should work.
Again : this is called the Fisher esterification process. Please don't try
this @ home if non-chemists. Sulph acid heats up nasty while diluting and
is the
cause for many_a_plastic_surgery. Fumes of that acid are highly corrosive
and toxic
(SO3).
Acid catalysis is a water tolerant process. Use 10% methanol mixed
with 2% to 3%
concentrated sulphuric acid (or double that of 50% acid). Mix with the oil
and
stir regularly for at least 24 hours.
That is time and material lost. In oreder to get any result at all, the
Methanol
overdose has to be 5 to 7 fold the stoichiometric value. That one is tryed
out.
And to finnish, washing is a real bitch.
Then leave to settle. Conversion rate is
often poor (like 50%), but it is using a material that otherwise can't be
made
into biodiesel. Ester should rise to the top of tank. It may work with less
nasty acids, but we have to begin somewhere. Acetic and citric may be too
weak.
Phosphoric may be OK.
Does not work with any other acids than H2SO4.


Cheers, Aleks





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Re: [biofuel] Glycerin and Glucose

2000-11-15 Thread aleksander . kac


Well, first things first:
glyc can't be broken down to glucose since it has fewer C atoms.
Second:
glyc is a flat chain of three C atoms, glucose is a ring compound of five
C atoms and one O.
So glucose is a heterogeneous ring compound. There is a process
called glycerolysys in bio-reactions - apparently it happens in our bodies
too, but I'm not quite sure what exactly is happening. A simple way to
convert glyc to sugar - that one I don't know.

Cheers, Aleks


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Re: [biofuel] Re: getting rid of water was Catalysts in transesterification

2000-11-03 Thread aleksander kac

 Hi Aleks
 I thought YOU where supposed to be telling US ! 
 you're the chemistry tech
 ;-)
 
Yeah right! You do not know, but you are talking to a
failed chemistry student, who is painfully picking up
the remains of his knowledge!

 Will a system something like taking water out of
 alcohol work?

Nope. Too acidic or too alkaline.

 if NaOH isn't
 the catalyst but simply an ingedient of methoxide
 and of the resulting brew
 can a catalyst be added to speed the Journey or
 isn't there one for this
 reaction?  

Not one I know of. 

and on the other side if a strong acid is
 a catalyst therefore
 isn't alterered in the reaction and can be reclaimed
 what does it matter if
 the reaction each time is only 50% IF the unbonded
 methel or ethel molecules
 can be used again. 

H2SO4 can't be easily reclaimed. Trans esterification
rate maters because K of the acidic reaction is ~1,
meaning the reaction is almost complete only in
infinite steps.

 Another thought for removing water (this one is way
 out but who knows what
 nuerons it may shift.) if we pump the reacting
 solution through  a small
 orifice can we freeze the water out like what
 happens in the fuel pump? and
 maybe get rid of a bit of wax at the same time?

Nice one, but almost HITEC and energy guzzling. If you
have the means, you should definitely check this one
out.

Cheers, Aleks


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[biofuel] Catalysts in transesterification

2000-11-02 Thread Aleksander Kac

For all of you, who care to know a little more:

There are actually two kinds of transesterification:
alkali based and acid based.
This reaction is in chemistry known as NUCLEOPHILLIC
SUBSTITUTION. It can be done in two ways :
1.using strong acids as catalysts (this way it is possible to
make FFA to alc esters too);
2.or doing a alkali based reaction. Lye IS NOT  a catalyst, since it 
enters the reaction and forms soap. Soap formation is inevitable, 
because of water formation during transesterification.

You can use a combination of both, but can never do acid based 
reactions solely, because K (konst. of equilibrium) is around 1,
which means you get aprox 50% work done. Another trick with the alkali
based reaction is to try to pull water out during the raction.
It is said, that this way conversions can get up to 98%. So please,
help me to find a cheap way to pull water molecules away from
the esters and lye.

Cheers, Aleks


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Re: [biofuel] Fwd: [Biodiesel] absolute ethanol

2000-10-23 Thread aleksander kac

Always use crystalline hydrate forming compounds:
plaster (CaSO4*2H20)
burned lymestone (CaO + H2O = Ca(OH)2
CuSO4*5H2O
soda Na2CO3*2H2O etc.


--- Ian Bennett [EMAIL PROTECTED] wrote:
 Are there any other chemicals/products that can be
 used?  would silica gel
 be effective or will it absorb alcohol as well as
 water?
 
 Thanks
 


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[biofuel] Electrode washing

2000-10-19 Thread aleksander kac

Hello folks!
You should wash vegetable oil contaminated electrodes
with DISH SOAP and WATER! Never use any solvent with
an
epoxy electrode!!
Solvent wash is needed if you sample mineral oil
products.
 both petroleum and
 vegetable oils but that the glass gets coated with
 oil and a solvent must be
 used to clean the electrode and the solvent eats at
 the seals and such which


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Re: [biofuel] Re: pH checker to use in oils

2000-10-18 Thread aleksander kac

Oy folks!
ALL REGULAR pH METERS WORK IN NATURAL OILS!
They are just slower to stabilyze. Oil pH
meter electrodes are VERY expensive, because
they have to be solvent deterioration proof, 
meaning they are designed to measure fossil
oil products.
Cheers, Aleks
--- Bryan Fullerton [EMAIL PROTECTED] wrote:
 Hmm I am doubtful. I know they make special ones
 just for oils and gas
 alcohols etc... and they are expensive. I have a
 soil pH tester and I tried
 it in oil and it didn't work. I believe it works
 decent in water..
 
 Hm I might have to play with it some more..
 
 ---Bryan
 
 
 - Original Message -
 From: aleksander kac [EMAIL PROTECTED]
 To: biofuel@egroups.com
 Sent: Monday, October 16, 2000 9:51 PM
 Subject: Re: [biofuel] Re: pH checker very cheap
 
 
  You see, pH is a measure for the concentration of
 H+
  or OH- ions in liquids (matter in general). The
 medium
  doesn't matter. Organic acids are poorly
 dissociated,
  so H+ activity is low. Measurement takes in water
 30
  sec's and in oil 2 min's. Wash electrode carefully
  after measuring oils with dish soap and rinse
  thoroughly first with tap water and at last with
 just
  a little of distilled water.
 
  Cheers, Aleks
 
  --- Bryan Fullerton [EMAIL PROTECTED] wrote:
   I looked this one over pretty carefully.. it is
   still int eh affordable
   range if you don't get any attachments. But I
 could
   not find anything that
   would indicate that it worked in oils.. Pretty
   expensive to buy if it
   doesn't work for what you want..
 
 
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Re: [biofuel] Re: pH checker very cheap

2000-10-17 Thread aleksander kac

You see, pH is a measure for the concentration of H+
or OH- ions in liquids (matter in general). The medium
doesn't matter. Organic acids are poorly dissociated,
so H+ activity is low. Measurement takes in water 30
sec's and in oil 2 min's. Wash electrode carefully
after measuring oils with dish soap and rinse
thoroughly first with tap water and at last with just
a little of distilled water.

Cheers, Aleks

--- Bryan Fullerton [EMAIL PROTECTED] wrote:
 I looked this one over pretty carefully.. it is
 still int eh affordable
 range if you don't get any attachments. But I could 
 not find anything that
 would indicate that it worked in oils.. Pretty
 expensive to buy if it
 doesn't work for what you want..


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[biofuel] Re: pH checker very cheap

2000-10-16 Thread aleksander kac


--- Bryan Fullerton [EMAIL PROTECTED] wrote:
 I did and I didn't find anything near that cheap.
 

I got this one. But it' cheaper in the store than
over the internet.
http://www.davisontheweb.com/shop/page153.html

Cheers, Aleks


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Re: [biofuel] Interesting site...biodiesel must be a good investment!

2000-10-12 Thread aleksander kac


--- Bryan Fullerton [EMAIL PROTECTED] wrote:
 Oh really and where might I find something like
 that? Remember it has to
 work in oil. Any soil ones I have tested have not
 worked in oil..
 Be interested in knowing your source...

Check with your local chemicals and lab equipment 
suplyer. Also check the Internet.

Cheers, Aleks


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Re: [biofuel] A crazy thought

2000-10-11 Thread aleksander kac


 their related water
 line scams, said to improve water quality by
 snapping a small pair of
 magnets around your lines.

Well, Steve,
wrong again, magnetic field actually improves water
qualitiy, if less limestone is your goal. Without the
maegnetic field limestone crystalyzes in calcyte
(cubes) formation, in magnetic field it's aragonyte
(needles). Needle crystals can't stick to surfaces and

get flushed away. Needs a strong mag field doe.
Cheers, Aleks


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Re: [biofuel] Interesting site...biodiesel must be a good investment!

2000-10-11 Thread aleksander kac


--- Bryan Fullerton [EMAIL PROTECTED] wrote:
 If you invest in an electronic meter you could have
 used that money to buy
 almost 400 gallons of regular diesel(G) Well at
 least the ones I looked at

 A digital pH indicator (means it has no temp
compensation) costs less than 15 US$. It looks like
a pencil on steroids.

Cheers, Aleks

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Re: [biofuel] A crazy thought

2000-10-10 Thread aleksander kac

Hi, Steve!
This is a bit untrue, as Nuclear Magnetic Resonance is
used mainly in agriculture to figure out oil content
in sunflower seeds, for example. One job back I made
this NMR monsters. Magnetic force works mainly on
protons, in our case hydrogen prtns, but working with
a permanent magnet to shift anything in the molecule
you would have to drag around giant and heavy magnets.

Cheers, Aleks
--- Steve Spence [EMAIL PROTECTED] wrote:
 it's not a valid premise. Magnets have no effect on
 liquid fuels.


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Re: [biofuel] Re: Ethanol from cellulose

2000-10-05 Thread aleksander kac

Hi there, David!

Currently I'm investigating a no waste tretment of
cellulose, namely Saccharification by microorganisms.
I have info on two types of cellulose splitting :
1. mycotic splitting by Trychodermas fungus
2. bacterial splitting by the Clostrydium strand - 
this has to be cellulose without lygnin.

Cheers, Aleks
--- DAVID REID [EMAIL PROTECTED] wrote:
 Aleks,
Thanks for your comments.  Your right
 about a myriad of
 possibilities but I was trying to simplify the
 situation and give him some
 valid starting points. I actually mention enzymes
 towards the bottom of the
 Sugar Primer which I wrote several months ago. Those
 with the greatest
 longterm potential are probably enzymes and G.M.
 yeasts. Fortunately or
 unfortunately  depending on your viewpoint G.M.Os.
 are no longer flavour of
 the year and a lot of valuable research on
 G.M.yeasts has come to a grinding
 halt. Fortunately a lot of work and research
 continues on enzymes and these
 will almost definitely provide better longterm
 solutions.
 This is an avenue I continue to research and have a
 great interest in. If
 you come across anything really interesting or
 outstanding I would most
 appreciate hearing. I believe a number of bacteria
 have possibilities but
 todate there has been nothing really outstanding.
 I believe 5 to 6 months ago there was something like
 55 Ethanol plants in
 the States although Pearce Lyons from Alltech and
 Joe ? from the Siebel
 Institute who were recently out here tell me that
 number is being reduced as
 one or two become redundant because of outmoded
 technology and a number of
 plants become concentrated in fewer hands.
 B.r., David
 
 
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[biofuel] Re: gas stripping

2000-09-19 Thread Aleksander Kac

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 I am wondering what you mean by the cold gas you
 spoke of to strip out the ferment?
 Are you talking about using gasoline? That is
 dangerous stuff to work with, as the vapours are
 poisonous and explosive. 

Well, by this gas stripping I'm talking about air stripping.
Namely, inside the air bubble you get a situation similar
to the one on the surface of the liquid mixture. As you know,
due to vapor pressure, there is allways some vapor of the liquid
above the surface. You can use this effect when you broaden your
surface - now being your air bubbles - and lead the vapors into
a cold finger duct. The result is a more concentrated liquid
mixture. This air stripping method is used in some places to clean
dangerous solvents out of drinking water or petroleum.
So rig up your aquarium pump, a hose, a large stone an a sealable
container. Vaccum the fumes into a cold finger array, but be
patient, as the thing requires days. But you don't have to do
nothing anyway, so watch the olimpics and let da bubbles do
some work.

Good luck, Aleks



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[biofuel] Ethanol drying by pressure

2000-08-03 Thread Aleksander Kac


Has anyone tryed drying eth by reverse osmosis? 
Where I worked before we used a small CHRIST unit for water 
deionification (we needed very pure water, not even ions were 
allowed). Such units are easy to operate - there are only cartridges 
to change and oil to look after in the pump. If you can get
a used one it can't be costly.

bye, Aleks


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[biofuel] strange biod smell III

2000-06-07 Thread Aleksander Kac

Hey Keith,

long time no write ( our mail server was down). The last three 
batches vent on well. The biod smells kind'a oily and nice. I
purchased a digital pH meter-money well spent (~50 USD). But I
found out a strange thing in my calculations of lye using my
measurements. With starting pH of waste oil of 6,10 one would need
very minute amounts of lye to reach neutrality. All you guys
say, when titrating your samples, you usualy get giant amounts
of lye (1g or more) per liter for this very low acidity. Is it 
possible that you are trying to get the mixture on a higher pH
value than 7? It doesn't make sense to me, because rinsing the
ester with pH higher than 10,5 takes a lot of water.
And now to the .si thing. I live in Slovenija, which is the 
northernmost ex Yugoslavia republic. We split away in 1991 and
had lots of luck - a ten day war only with very few casualtys and
not much material damage. We now border with (W)Italy, (N)Austria,
(NE)Hungary and (E)Croatia. Population is 2 milion, land is twice
the size of Ciprus, of which 55% is covered with borreal forrest.
We have a small piece of the Adriatic coast, the southern alps and
lots of small rivers and lakes.
Where do you live?

Good luck, 
Aleks



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[biofuel] strange smell II

2000-05-25 Thread Aleksander Kac

Well Keith,my friend,

seems you were right about the fatty acids. I've checked
with a friend, who works in a veg oil refinement plant and
she told me, that you can split triglycerids and fail to 
form monoesters (methanol vapours out, not enough stirring,...)
All acids don't saponificate, some are left in the mixture.
After this I've double checked my pH, and after 15 min the
paper showed slightly acidic levels. Old indicator perhaps.
Here is her advice:
Don't be cheap on the booze (add 3% extra methanol)
and, if it doesn't work if you shake it harder, then shake it
longer!
I've heard that one before.

And now to the compost smell.
Farmers in my country have a new tech for stock feeding.
Fresh grass clippings (which my mother composts, along with food 
leftovers)get wrapped in PE foil and stay that way till next
spring. The grass gets acidic (lactic acid forms, like with sour 
cabbages). Well, the same happened to my mom, the compost odor
was just not very earthy.

Thanks anyway!

Aleks



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